56431-03-9

Basic information

• Product Name: 2-fluoro-α-vinyl-benzhydrol
• Synonyms: 2-fluoro-α-vinyl-benzhydrol
• CAS NO: 56431-03-9
• Molecular Weight: 228.266
• Mol File: 56431-03-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-fluoro-α-vinyl-benzhydrol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-fluoro-α-vinyl-benzhydrol(56431-03-9)
• EPA Substance Registry System: 2-fluoro-α-vinyl-benzhydrol(56431-03-9)

Safety Data

• Hazardous Substances Data: 56431-03-9(Hazardous Substances Data)

Upstream product

• 362-54-9 2-fluorobenzhydrol 
• 342-24-5 o-fluorobenzophenone 
• 1826-67-1 vinyl magnesium bromide 
• 110-89-4 piperidine 
• 56431-26-6 1-(2-fluorophenyl)-1-phenylpropargyl alcohol 
• 5970-45-6 zinc(II) acetate dihydrate 
• 3536-96-7 vinylmagnesium chloride 

Downstream Products

• 1620684-41-4 3-(benzo[d][1,3]dioxol-2-yl)-1-(2-fluorophenyl)-2-phenylpropan-1-one 

Relevant articles and documents

Photo-induced phosphorus radical involved semipinacol rearrangement reaction: Highly synthesis of γ-oxo-phosphonates

Hydroxyphosphoric acids display the unique biological activities, and they have some attractive prospects as clinical drug moleculars. Herein, a new approach for the synthesis of γ-oxo-phosphonates (the precursor of hydroxyphosphoric acid) has been established through the semipinacol rearrangement tactic involved the photo-induced phosphorus radical process. Most important, this transformation is avoid of the external oxidants, and occurs very well under the sunlight irradiation, meanwhile the γ-oxo-phosphonate was easily derivatized to obtain γ-hydroxyphosphoric acid, thus highlights the synthesis value of this method.

Alpha-substituted benzhydrol derivatives

The invention relates to new α-substituted benzhydrols and pharmaceutically acceptable acid addition salts or quaternary ammonium salts thereof with enzyme promoting or inhibiting effects;