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Bis[2-(2-benzothiazoly)phenolato]zinc(II), also known as Zn(BTZ)2, is a high-efficiency electroluminescent material that has been extensively studied and widely used as an excellent electron transporting material in OLEDs (Organic Light-Emitting Diodes). It is a light yellow to light yellow-green solid and exhibits an unusual broad electroluminescent (EL) emission, making it a potential single-emitting component for white light-emitting diodes.

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  • 58280-31-2 Structure
  • Basic information

    1. Product Name: Bis[2-(2-benzothiazoly)phenolato]zinc(II)
    2. Synonyms: BIS[2-(2-BENZOTHIAZOLY)PHENOLATO]ZINC(II);Bis(2-(2-hydroxyphenyl)-benz-1,3-oxadiazoleato)zinc complex;Zn(BTZ)2;Bis[2-(2-hydroxyphenyl)benzothiazolato]zinc(II);Bis(2-(2-hydroxyphenyl)benzothiazolate)zinc;bis(2-(benzo[d]thiazol-2-yl)phenylbenzo[d]thiazol-2-yl)phenoxy)zinc;Bis[2-(2-benzothiazo;Bis[2-(2-benzothiazolyl)phenolato]zinc(Ⅱ)
    3. CAS NO:58280-31-2
    4. Molecular Formula: C26H16N2O2S2Zn
    5. Molecular Weight: 517.94
    6. EINECS: N/A
    7. Product Categories: Classes of Metal Compounds;Electroluminescence;Functional Materials;Transition Metal Compounds;Zn (Zinc) Compounds;oled materials
    8. Mol File: 58280-31-2.mol
  • Chemical Properties

    1. Melting Point: 305-310°C
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Bis[2-(2-benzothiazoly)phenolato]zinc(II)(CAS DataBase Reference)
    10. NIST Chemistry Reference: Bis[2-(2-benzothiazoly)phenolato]zinc(II)(58280-31-2)
    11. EPA Substance Registry System: Bis[2-(2-benzothiazoly)phenolato]zinc(II)(58280-31-2)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: 45-60-23/24/25-36/37/38-42/43
    3. Safety Statements: 53-26-36/37-45
    4. RIDADR: UN 2811 6.1 / PGIII
    5. WGK Germany: 3
    6. RTECS:
    7. HazardClass: N/A
    8. PackingGroup: N/A
    9. Hazardous Substances Data: 58280-31-2(Hazardous Substances Data)

58280-31-2 Usage

Uses

Used in Organic and Printed Electronics:
Bis[2-(2-benzothiazoly)phenolato]zinc(II) is used as a green light emitter and dopant for its high efficiency in electroluminescence, making it suitable for applications in organic and printed electronics.
Used in OLED and PLED Materials:
Zn(BTZ)2 is used as an electron transporting material in OLEDs (Organic Light-Emitting Diodes) and PLEDs (Polymer Light-Emitting Diodes) due to its excellent electron transport properties.
Used in Photoluminescent Materials:
Bis[2-(2-benzothiazoly)phenolato]zinc(II) is used as a metal complex dopant and dye in photoluminescent materials, taking advantage of its broad electroluminescent emission.
Used in Photonic and Optical Materials:
Zn(BTZ)2 is used in the development of photonic and optical materials, where its unique electroluminescent properties can be utilized for various applications in the photonics industry.

Check Digit Verification of cas no

The CAS Registry Mumber 58280-31-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,8,2,8 and 0 respectively; the second part has 2 digits, 3 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 58280-31:
(7*5)+(6*8)+(5*2)+(4*8)+(3*0)+(2*3)+(1*1)=132
132 % 10 = 2
So 58280-31-2 is a valid CAS Registry Number.
InChI:InChI=1/2C13H9NOS.Zn/c2*15-11-7-3-1-5-9(11)13-14-10-6-2-4-8-12(10)16-13;/h2*1-8,15H;/q;;+2/p-2

58280-31-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Bis[2-(2-benzothiazolyl)phenolato]zinc(II)

1.2 Other means of identification

Product number -
Other names bis(2-(benzo[d]thiazol-2-yl)phenylbenzo[d]thiazol-2-yl)phenoxy)zinc

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:58280-31-2 SDS

58280-31-2Downstream Products

58280-31-2Relevant articles and documents

White organic light-emitting diodes based on spectral broadening electroluminescence due to formation of interfacial exciplexes

Singh, Samarendra P.,Mohapatra,Qureshi,Manoharan, S. Sundar

, p. 1 - 3 (2005)

We demonstrate white organic light-emitting diodes (OLEDs) having spectral width of approximately 260 nm in electroluminescence (EL) in a simple bilayer structure, consisting of TPD and zinc benzothiazole, without taking recourse to complex strategies such as blending and doping. The EL is broader than the corresponding photoluminescence (PL) of both component materials and their structures. A deconvolution of PL and EL spectra shows that as large as 60% of the broad EL emission originates from multiple exciplexes formed at the interface during electrical excitation.

Direct Oxygenation of C-H Bonds through Photoredox and Palladium Catalysis

Paul, Amrita,Shah, Sk. Sheriff,Shee, Maniklal,Singh, Amit Kumar,Singh, N. D. Pradeep

supporting information, p. 3426 - 3439 (2020/03/23)

This report presents the oxygenation of C-H bonds via the merger of photocatalysis and Pd catalysis. Herein, we describe the utilization of a photocatalyst to oxidize an organopalladium(II) intermediate to high-valent PdIII or PdIV intermediates, which promotes the formation of C-O bonds. The demonstrated method works efficiently with various directing groups, such as oxime ether and benzothiazole. The applicability of this direct C-O bond formation method is shown by synthesizing several metal complexes of 2-(benzo[d]thiazol-2-yl)phenol that can be used in organic light-emitting diodes and pharmaceuticals.

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