58687-89-1

Basic information

• Product Name: 1-phenyl-1-butylhydroperoxide
• Synonyms: 1-phenyl-1-butylhydroperoxide
• CAS NO: 58687-89-1
• Molecular Weight: 166.22
• Mol File: 58687-89-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-phenyl-1-butylhydroperoxide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-1-butylhydroperoxide(58687-89-1)
• EPA Substance Registry System: 1-phenyl-1-butylhydroperoxide(58687-89-1)

Safety Data

• Hazardous Substances Data: 58687-89-1(Hazardous Substances Data)

Upstream product

• 104-51-8 1-butylbenzene 
• 22135-49-5 (S)-1-phenylbutan-1-ol 
• 22144-60-1 (R)-1-butylphenylethanol 
• 614-14-2 1-Phenyl-1-butanol 

Downstream Products

• 102560-30-5 (1-phenyl-butyl)-xanthen-9-yl peroxide 
• 103166-80-9 ((-)-1-phenyl-butyl)-trityl peroxide 
• 103166-80-9 (+/-)-(1-phenyl-butyl)-trityl peroxide 
• 614-14-2 1-Phenyl-1-butanol 

Relevant articles and documents

A novel copper(II)-lanthanum(IIi) metal organic framework as a selective catalyst for the aerobic oxidation of benzylic hydrocarbons and cycloalkenes

The synthesis and structure of a novel heteronuclear CuII and LaIII metal organic framework (MOF) having pyridinedicarboxylic acid (CuLa-MOF) is reported. The obtained MOF with the formula {[Cu0.5La2(HPDC)(PDC)2(SO4)(H2O)2]H2O}n (PDC: 3,5-pyridinedicarboxylate) has a 3D non-porous lattice with a single type of octahedrally coordinated CuII and two distinct nonacoordinated LaIII ions, with sulphate being a linker between the CuII and LaIII centers. CuLa-MOF exhibits catalytic activity to promote the aerobic autooxidation of benzylic hydrocarbons and the aerobic oxidation of cycloalkenes. Compared with a homogenous catalyst, Cu(OAc)2, CuLa-MOF, as a heterogeneous catalyst, exhibits similar activity, but the solid is recyclable with some minor decrease in activity from the first to the second catalytic cycle; after which, a steady activity is observed, as determined by the coincidence of temporal evolution of the reaction upon reuse.