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58688-35-0

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58688-35-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 58688-35-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,8,6,8 and 8 respectively; the second part has 2 digits, 3 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 58688-35:
(7*5)+(6*8)+(5*6)+(4*8)+(3*8)+(2*3)+(1*5)=180
180 % 10 = 0
So 58688-35-0 is a valid CAS Registry Number.

58688-35-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name cyclohexyl(cyclopropyl)methanone

1.2 Other means of identification

Product number -
Other names cyclopropyl cyclohexyl ketone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:58688-35-0 SDS

58688-35-0Relevant articles and documents

B(C6F5)3-Catalyzed Hydrosilylation of Vinylcyclopropanes

He, Tao,Long, Peng-Wei,Oestreich, Martin

supporting information, p. 7383 - 7386 (2020/10/12)

A hydrosilylation of vinylcyclopropanes (VCPs) catalyzed by the strong boron Lewis acid B(C6F5)3 is reported. For the majority of VCPs, little or no ring opening of the cyclopropyl unit is observed. Conversely, for VCPs with bulky R groups, such as ortho-substituted aryl rings or branched alkyl residues, ring opening is the exclusive reaction pathway. This finding is explained by the thwarted hydride delivery to a sterically shielded, β-silicon-stabilized cyclopropylcarbinyl cation intermediate.

Another Role of Copper in the SimmonsSmith Reaction: Copper-catalyzed Nucleophilic Michael-type Cyclopropanation of a,β-Unsaturated Ketones

Fujii, Kanami,Misaki, Tomonori,Sugimura, Takashi

, p. 634 - 636 (2014/05/20)

Cyclopropanation was performed using the Furukawa procedure with CH2I2/Et2Zn and a,β-unsaturated ketones. The reaction was performed in the presence of a copper salt. The reactivity was highly dependent on the substrate structure, and cyclopropanated products were obtained in better yields than those achieved using the original SimmonsSmith conditions with a ZnCu couple in some cases. Stereospecificity was observed in a certain case; however, the synthesis of an asymmetric version with a chiral ligand was not successful.

Synthesis of Some Substituted Pyrrolidines from Cyclopropyl Carbonyl Compounds

Blake, Keith W.,Gillies, Iain,Denney, Ronald C.

, p. 700 - 702 (2007/10/02)

A series of alkyl and aryl cyclopropyl carbonyl compounds, when refluxed in N-methylformamide in the presence of magnesium chloride, gave variously substituted pyrrolidines.

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