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58879-33-7

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  • High quality (R)-(-)-Dihydro-5-(P-Tolysulfonyioxymethyl)-2-(3H)-Furanone supplier in China

    Cas No: 58879-33-7

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58879-33-7 Usage

Chemical Properties

white crystalline powder

Check Digit Verification of cas no

The CAS Registry Mumber 58879-33-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,8,8,7 and 9 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 58879-33:
(7*5)+(6*8)+(5*8)+(4*7)+(3*9)+(2*3)+(1*3)=187
187 % 10 = 7
So 58879-33-7 is a valid CAS Registry Number.
InChI:InChI=1/C12H14O5S/c1-9-2-5-11(6-3-9)18(14,15)16-8-10-4-7-12(13)17-10/h2-3,5-6,10H,4,7-8H2,1H3/t10-/m1/s1

58879-33-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name (R)-(5-Oxotetrahydrofuran-2-yl)methyl 4-methylbenzenesulfonate

1.2 Other means of identification

Product number -
Other names [(2R)-5-oxooxolan-2-yl]methyl 4-methylbenzenesulfonate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:58879-33-7 SDS

58879-33-7Downstream Products

58879-33-7Relevant articles and documents

Chiral hypervalent iodine(III) catalyst promotes highly enantioselective sulfonyl-and phosphoryl-oxylactonizations

Gelis, Coralie,Dumoulin, Audrey,Bekkaye, Mathieu,Neuville, Luc,Masson, Géraldine

supporting information, p. 278 - 281 (2017/11/27)

An efficient enantioselective hypervalent iodine promoted oxylactonization of 4-pentenoic acids has been achieved using stoichiometric or a catalytic amount of chiral aryl-λ3-iodane. This reaction provides straightforward access to a wide range of sulfonyloxy-and phosphoryloxy-γ-butyrolactones in respectable yields with moderate to excellent enantioselectivities.

Synthesis of C1-C11 fragment of annonacin: A polyketide acetogenin of Annonaceae

Figadere,Franck,Cave

, p. 1637 - 1640 (2007/10/02)

(4R, 10S)-Methyl tri-isopropylsilyloxy-4-tert-butyldimethylsilyloxy-10-tert-amyloxy-11- undecanoate 1 has been synthesized from L-glutamic acid. This compound is a key intermediate in the total synthesis of annonacin, an acetogenin of Annonaceae.

Enantioenriched N-(2-Chloroalkyl)-3-acetoxypiperidines as Potential Cholinotoxic Agents. Synthesis and Preliminary Evidence for Spirocyclic Aziridinium Formation.

Huh, Nam,Thompson, Charles M.

, p. 5935 - 5950 (2007/10/02)

The syntheses of six enantioenriched analogs representing cyclic forms of acetylcholine are reported. (S)- and (R)-N-(2-chloroethyl)-3-acetoxypiperidine and (R,R)-, (R,S)-, (S,R)-, and (S,S)-N-(2-chloropropyl)-3-acetoxypiperidine have been synthesized from (R)- or (S)-3-hydroxypiperidine in five steps. (R)- and (S)-3-hydroxypiperidine were accessed via parallel stereospecific routes from d- and l-glutamic acid, and through fractional recrystallization of diastereomeric tartranilic acid salts. (S)-N-(2-Chloroethyl)-3-acetoxypiperidine was reacted with silver perchlorate to form a spirocyclic aziridinium analog of acetylcholine as evidenced by a characteristic 1H NMR shift for the aziridinium methylene groups.

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