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Cas Database

590-15-8

590-15-8

Identification

  • Product Name:1-Propene, 1-bromo-,(1E)- (9CI)

  • CAS Number: 590-15-8

  • EINECS:

  • Molecular Weight:120.977

  • Molecular Formula: C3H5 Br

  • HS Code:

  • Mol File:590-15-8.mol

Synonyms:1-Propene,1-bromo-, (E)-; Propene, 1-bromo-, (E)- (8CI); Propene, 1-bromo-, trans- (6CI);(E)-1-Bromo-1-propene; (E)-1-Bromo-1-propylene; (E)-1-Bromopropene;(E)-1-Propenyl bromide; 1-Bromo-(1E)-propene; trans-1-Bromo-1-propene;trans-1-Bromopropene

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Safety information and MSDS view more

  • Pictogram(s):F,Xi

  • Hazard Codes:F,Xi

  • Signal Word:Danger

  • Hazard Statement:H225 Highly flammable liquid and vapourH315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:trans-1-Bromo-1-propene contains copper as stabilizer, 99%
  • Packaging:1g
  • Price:$ 51.8
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:trans-1-Bromo-1-propene contains copper as stabilizer, 99%
  • Packaging:5g
  • Price:$ 146
  • Delivery:In stock
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  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:trans-1-Bromo-1-propene - stablised with Copper
  • Packaging:10 g
  • Price:$ 600
  • Delivery:In stock
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  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:trans-1-Bromo-1-propene - stablised with Copper
  • Packaging:5 g
  • Price:$ 320
  • Delivery:In stock
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  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:trans-1-Bromo-1-propene - stablised with Copper
  • Packaging:2 g
  • Price:$ 200
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:trans-1-Bromo-1-propene - stablised with Copper
  • Packaging:1 g
  • Price:$ 125
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:trans-1-Bromo-1-propene - stablised with Copper
  • Packaging:25 g
  • Price:$ 1250
  • Delivery:In stock
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:TRANS-1-BROMO-1-PROPENE 95.00%
  • Packaging:5G
  • Price:$ 948.98
  • Delivery:In stock
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:TRANS-1-BROMO-1-PROPENE 95.00%
  • Packaging:1G
  • Price:$ 653.07
  • Delivery:In stock
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Relevant articles and documentsAll total 4 Articles be found

A novel system for decarboxylative bromination

Telvekar, Vikas N.,Chettiar, Somsundaram N.

, p. 4529 - 4532 (2008/02/03)

A simple and mild method for decarboxylative bromination of α,β-unsaturated carboxylic acids has been developed using diphosphorus tetraiodide in combination with tetraethylammonium bromide (TEAB) at room temperature. High yields of the corresponding bromoalkenes were obtained.

Mild and efficient method for decarboxylative bromination of α,β-unsaturated carboxylic acids with Dess-Martin periodinane

Telvekar, Vikas N.,Arote, Nitin D.,Herlekar, Omkar P.

, p. 2495 - 2497 (2007/10/03)

A simple and mild method for decarboxylative bromination of α,β-unsaturated carboxylic acids has been developed using Dess-Martin Periodinane (DMP) in combination with tetraethylammonium bromide (TEAB) at room temperature. High yields of the corresponding bromoalkenes were obtained. Georg Thieme Verlag Stuttgart.

Synthesis of the Substituted Z-1-Bromo-1-alkenes and Arylacetylenes from 2,3-Dibromocarboxylic Acids

Matveeva,Erin,Kurz

, p. 1065 - 1067 (2007/10/03)

Stereoselectivity was studied of simultaneous debromination-decarboxylation of dibrominated cinnamic and acrylic acids. The best selectivity in formation of Z-vinyl bromides was achieved with the use of organic nitrogen bases. The 1-bromo-1-alkenes were converted into the corresponding acetylenes.

ERYTHROSELECTIVITY IN ADDITION OF γ-SUBSTITUTED ALLYLSILANES TO ALDEHYDES IN THE PRESENCE OF TITANIUM CHLORIDE

Hayashi, Tamio,Kabeta, Keiji,Hamachi,Itaru,Kumada, Makoto

, p. 2865 - 2868 (2007/10/02)

(E)-Crotyltrimethylsilane and (E)-cinnamyltrimethylsilane were allowed to react with aldehydes (RCHO: t-Bu, i-Pr, Et, Me) in the presence of titanium chloride to give erythro homoallyl alcohols with over 93percent selectivity.Lower erythroselectivity was observed in the reaction of (Z)-allylsilanes.

Process route upstream and downstream products

Process route

(E)-but-2-enoic acid
107-93-7

(E)-but-2-enoic acid

trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

Conditions
Conditions Yield
With diphosphorus tetraiodide; tetraethylammonium bromide; In carbon disulfide; at 20 ℃; for 12h;
86%
With tetraethylammonium bromide; Dess-Martin periodane; In dichloromethane; at 20 ℃; for 0.5h;
78%
(Z)-but-2-enoic acid
503-64-0

(Z)-but-2-enoic acid

trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

Conditions
Conditions Yield
With diphosphorus tetraiodide; tetraethylammonium bromide; In carbon disulfide; at 20 ℃; for 12h;
90%
2,3-dibromobutanoic acid
600-30-6

2,3-dibromobutanoic acid

(Z)-1-propenyl bromide
590-13-6

(Z)-1-propenyl bromide

trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

Conditions
Conditions Yield
With sodium hydrogencarbonate; N,N-dimethyl-formamide; at 70 ℃;
With pyridine; auf Siedetemperatur;
With potassium cyanide; acetone;
With triethylamine; In N,N-dimethyl-formamide; Yield given. Yields of byproduct given; Heating;
1-bromo-1-propene
590-14-7

1-bromo-1-propene

trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

Conditions
Conditions Yield
With sodium hydroxide; In butan-1-ol; for 40h; Heating;
63%
1,2-Dibromopropane
78-75-1

1,2-Dibromopropane

trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

Conditions
Conditions Yield
With ethanol; sodium phenoxide;
1,2-Dibromopropane
78-75-1

1,2-Dibromopropane

trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

Conditions
Conditions Yield
With sodium ethanolate; Trennung vom cis-Isomeren durch fraktionierte Destillation;
hydrogen bromide
10035-10-6,12258-64-9

hydrogen bromide

prop-1-yne
74-99-7

prop-1-yne

(Z)-1-propenyl bromide
590-13-6

(Z)-1-propenyl bromide

trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

Conditions
Conditions Yield
Addition bei UV-Licht in fluessiger Phase und in der Gasphase bei Raumtemperatur.Irradiation;
at 25 ℃; under 150 - 200 Torr; zeitl.Verlauf (0-60 min) der Reakt. bei UV-Licht in in der Gasphase; Einfluss von Zusaetzen (Sauerstoff,Aceton) und Einfl.der Lichtintensitaet.Irradiation;
(Z)-1-propenyl bromide
590-13-6

(Z)-1-propenyl bromide

trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

Conditions
Conditions Yield
at 0 - 100 ℃; Kinetics; Isomerisierung unter Belichtung;
at 0 - 100 ℃; Kinetics; Isomerisierung unter Lichtausschluss;
ethanol
64-17-5

ethanol

1,2-Dibromopropane
78-75-1

1,2-Dibromopropane

sodium phenoxide
139-02-6

sodium phenoxide

(Z)-1-propenyl bromide
590-13-6

(Z)-1-propenyl bromide

trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

2-bromoprop-1-ene
557-93-7

2-bromoprop-1-ene

Conditions
Conditions Yield
erythro-2,3-dibromobutanoic acid
600-30-6,26697-68-7,90429-42-8,125810-56-2

erythro-2,3-dibromobutanoic acid

N,N-dimethyl-formamide
68-12-2,33513-42-7

N,N-dimethyl-formamide

(Z)-1-propenyl bromide
590-13-6

(Z)-1-propenyl bromide

trans-2-propenyl bromide
590-15-8

trans-2-propenyl bromide

Conditions
Conditions Yield

Global suppliers and manufacturers

Global( 12) Suppliers
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  • Chemwill Asia Co., Ltd.
  • Business Type:Manufacturers
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  • Country:China (Mainland)
  • Antimex Chemical Limied
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  • Emails:anthony@antimex.com
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  • LEAP CHEM Co., Ltd.
  • Business Type:Trading Company
  • Contact Tel:0571-87317139
  • Emails:market15@leapchem.com
  • Main Products:89
  • Country:China (Mainland)
  • Sigma-Aldrich Chemie GmbH
  • Business Type:Trading Company
  • Contact Tel:800 558-9160
  • Emails:romesh.collins@milliporesigma.com
  • Main Products:1
  • Country:Germany
  • NovaChemistry
  • Business Type:Trading Company
  • Contact Tel:+44 (0)208 191 7890
  • Emails:info@novachemistry.com
  • Main Products:1
  • Country:United Kingdom
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