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59483-84-0

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59483-84-0 Usage

Chemical Properties

White crystalline powder and chunks

Uses

Different sources of media describe the Uses of 59483-84-0 differently. You can refer to the following data:
1. Bis(pentafluorophenyl) carbonate is a reagent used as a carbonyl equivalent and for various coupling reactions, especially for azapeptides.
2. Bis(pentafluorophenyl) carbonate can be used in the preparation of:A cyclic carbonate named 6,6′-(ethane-1,2-diyl)bis(1,3,6-dioxazocan-2-one), which is a key intermediate for the synthesis of non-isocyanate polyurethanes.A coumarin based aliphatic polycarbonate named 5-(4-methylumbelliferyloxycarbonyl)-5-methyl-1,3-dioxan-2-one (MUC).

General Description

Bis(pentafluorophenyl) carbonate is the equivalent of carbonyl compound generally used in coupling reactions. It is used as a reagent in the preparation of azapeptides.

Check Digit Verification of cas no

The CAS Registry Mumber 59483-84-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,4,8 and 3 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 59483-84:
(7*5)+(6*9)+(5*4)+(4*8)+(3*3)+(2*8)+(1*4)=170
170 % 10 = 0
So 59483-84-0 is a valid CAS Registry Number.
InChI:InChI=1/C13F10O3/c14-1-3(16)7(20)11(8(21)4(1)17)25-13(24)26-12-9(22)5(18)2(15)6(19)10(12)23

59483-84-0 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • TCI America

  • (B3604)  Bis(pentafluorophenyl) Carbonate  >98.0%(GC)

  • 59483-84-0

  • 5g

  • 1,250.00CNY

  • Detail
  • Alfa Aesar

  • (H54880)  Bis(pentafluorophenyl) carbonate, 98+%   

  • 59483-84-0

  • 1g

  • 509.0CNY

  • Detail
  • Alfa Aesar

  • (H54880)  Bis(pentafluorophenyl) carbonate, 98+%   

  • 59483-84-0

  • 5g

  • 2037.0CNY

  • Detail
  • Alfa Aesar

  • (H54880)  Bis(pentafluorophenyl) carbonate, 98+%   

  • 59483-84-0

  • 25g

  • 8489.0CNY

  • Detail
  • Aldrich

  • (539899)  Bis(pentafluorophenyl)carbonate  97%

  • 59483-84-0

  • 539899-5G

  • 1,470.69CNY

  • Detail

59483-84-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name BIS(PENTAFLUOROPHENYL)CARBONATE

1.2 Other means of identification

Product number -
Other names bis(2,3,4,5,6-pentafluorophenyl) carbonate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:59483-84-0 SDS

59483-84-0Relevant articles and documents

Photo-on-Demand Base-Catalyzed Phosgenation Reactions with Chloroform: Synthesis of Arylcarbonate and Halocarbonate Esters

Dai, Namin,Eda, Kazuo,Harada, Hidefumi,Hashimoto, Yuka,Hosokawa, Sasuga,Kakiuchi, Toshifumi,Liang, Fengying,Okazoe, Takashi,Suzuki, Yuto,Tana, Gegen,Tsuda, Akihiko

, p. 9811 - 9819 (2021/07/20)

Carbonate esters are utilized as solvents and reagents for C1 building blocks in organic synthesis. This study reports a novel photo-on-demand in situ synthesis of carbonate esters with CHCl3 solutions containing a mixture of an aromatic or haloalkyl alcohol having relatively high acidity, and an organic base. We found that the acid-base interaction of the alcohol and base in the CHCl3 solution plays a key role in enabling the photochemical reaction. This reaction allows practical syntheses of diphenyl carbonate derivatives, haloalkyl carbonates, and polycarbonates, which are important chemicals and materials in industry.

REACTIONS OF PENTAFLUOROPHENOL AND POLYFLUORINATED ALCOHOLS WITH CARBON TETRACHLORIDE IN THE PRESENCE OF ALUMINUM CHLORIDE

Petrova, T. D.,Ryabichev, A. G.,Savchenko, T. I.,Kolesnikova I. V.,Platonov, V. E.

, p. 1362 - 1366 (2007/10/02)

The reaction of pentafluorophenol, 2,2,3,3-tetrafluoropropyl alcohol, and 2,2,3,3,4,4,5,5-octafluoropentyl alcohol with carbon tetrachloride in the presence of aluminum chloride were investigated.The main products from the reaction of pentafluorophenol with these reagents are pentafluorophenoxytrichloromethane, di(pentafluorophenol) carbonate, and tri(pentafluorophenoxy)chloromethane.The ratios of the products depend on the reaction conditions.The use of a large excess of carbon tetrachloride leads to the preferential formation of pentafluorophenoxytrichloromethane.The addition of water promotes the formation di(pentafluorophenyl) carbonate.When heated with carbon tetrachloride and aluminum chloride and subsequently treated with water, 2,2,3,3-tetrafluoropropyl and 2,2,3,3,4,4,5,5-octafluoropentyl alcohols are converted into di(2,2,3,3-tetrafluoropropyl) carbonate and di(2,2,3,3,4,4,5,5-octafluoropentyl) carbonate respectively.

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