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59920-85-3

59920-85-3

Identification

Synonyms:a,a,a-Trifluoro-4-(methylthio)-o-toluidine;

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Safety information and MSDS view more

  • Pictogram(s):IrritantXi

  • Hazard Codes:Xi

  • Signal Word:no data available

  • Hazard Statement:no data available

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price view more

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:2-AMINO-5-(METHYLTHIO)BENZOTRIFLUORIDE 95.00%
  • Packaging:10G
  • Price:$ 1334.03
  • Delivery:In stock
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:2-AMINO-5-(METHYLTHIO)BENZOTRIFLUORIDE 95.00%
  • Packaging:5G
  • Price:$ 909.56
  • Delivery:In stock
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:2-AMINO-5-(METHYLTHIO)BENZOTRIFLUORIDE 95.00%
  • Packaging:50MG
  • Price:$ 119.7
  • Delivery:In stock
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Relevant articles and documentsAll total 3 Articles be found

Ruthenium-Catalyzed Site-Selective Trifluoromethylations and (Per)Fluoroalkylations of Anilines and Indoles

Li, Yang,Neumann, Helfried,Beller, Matthias

supporting information, p. 6784 - 6788 (2020/05/18)

Introducing (per)fluoroalkyl groups into arenes continues to be an interesting, but challenging area in organofluorine chemistry. We herein report an ortho-selective C?H perfluoroalkylation including trifluoromethylations of anilines and indoles without the need of protecting groups using RfI and RfBr as commercially available reagents. The availability and price of the starting materials and the inherent selectivity make this novel methodology attractive for the synthesis of diverse (per)fluoroalkylated building blocks, for example, for bioactive compounds and materials.

4-Methylthio-2-trifluoromethylmethanesulfonanilide and derivatives thereof

-

, (2008/06/13)

2-(Trifluoromethyl)methanesulfonanilides substituted in the para position by methylthio, methylsulfinyl or methylsulfonyl groups and horticulturally acceptable salts thereof and composition containing these compounds are useful herbicides.

Process route upstream and downstream products

Process route

4-amino-3-(trifluoromethyl)phenyl thiocyanate
68672-37-7

4-amino-3-(trifluoromethyl)phenyl thiocyanate

4-Methylthio-2-trifluoromethylaniline
59920-85-3

4-Methylthio-2-trifluoromethylaniline

Conditions
Conditions Yield
In methanol; dichloromethane;
91%
methyl(4-nitro-3-(trifluoromethyl)phenyl)sulfane
54998-75-3

methyl(4-nitro-3-(trifluoromethyl)phenyl)sulfane

4-Methylthio-2-trifluoromethylaniline
59920-85-3

4-Methylthio-2-trifluoromethylaniline

Conditions
Conditions Yield
With hydrogen; In ethanol;
Bromotrifluoromethane
75-63-8

Bromotrifluoromethane

4-methylsulfanylaniline
104-96-1

4-methylsulfanylaniline

4-Methylthio-2-trifluoromethylaniline
59920-85-3

4-Methylthio-2-trifluoromethylaniline

Conditions
Conditions Yield
With tricyclohexylphosphine[4,5-dimethyl-1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene][2-thienylmethylene]ruthenium(II) dichloride; potassium carbonate; In 1,4-dioxane; at 100 ℃; for 12h; regioselective reaction; Inert atmosphere; Schlenk technique;
42%
4-Methylthio-2-trifluoromethylaniline
59920-85-3

4-Methylthio-2-trifluoromethylaniline

Conditions
Conditions Yield
aus 2-Nitro-5-methylthio-trifluormethylbennzol mit Ra/Ni-H2;

Global suppliers and manufacturers

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