59969-93-6

Basic information

• Product Name: Cyclohexanone, 3-(1-nitroethyl)-
• CAS NO: 59969-93-6
• Molecular Formula: C8H13NO3
• Molecular Weight: 171.196
• Mol File: 59969-93-6.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 3-(1-nitroethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 3-(1-nitroethyl)-(59969-93-6)
• EPA Substance Registry System: Cyclohexanone, 3-(1-nitroethyl)-(59969-93-6)

Safety Data

• Hazardous Substances Data: 59969-93-6(Hazardous Substances Data)

Upstream product

• 79-24-3 Nitroethane 
• 930-68-7 cyclohexenone 

Downstream Products

• 855626-04-9 1-(3-iodo-cyclohexyl)-ethanone 
• 107513-61-1 1-(3-hydroxy-cyclohexyl)-ethanone 
• 15040-97-8 3-acetylcyclohexanone 
• 212557-25-0 3-(1-nitro-ethyl)-cyclohexanol 

Relevant articles and documents

Conjugate Addition of Nitro-Derivatives to α,β-Unsaturated Carbonyl Compounds on Basic Alumina

Conjugate addition of nitroalkanes to α,β-unsaturated carbonyl compounds occurs in the presence of basic alumina without a solvent.Yields are fair to good also with substrates which are acid or base sensitive.

Highly enantioselective conjugate addition of nitroalkanes to enones catalyzed by cinchona alkaloid derived primary amine

A cinchona alkaloid derived primary amine catalyzed conjugate addition of nitroalkanes to enones is described. The process affords the Michael adducts in good yield and with up to 99% ee for both acyclic and cyclic enones.

Ionic liquids made with dimethyl carbonate: Solvents as well as boosted basic catalysts for the michael reaction

This article describes 1) a methodology for the green synthesis of a class of methylammonium and methylphosphonium ionic liquids (ILs), 2) how to tune their acid-base properties by anion exchange, 3) complete neat-phase NMR spectroscopic characterisation