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Cas Database

60256-44-2

60256-44-2

Identification

  • Product Name:Benzenamine, N-(2-bromo-2-propenyl)-N-methyl-

  • CAS Number: 60256-44-2

  • EINECS:

  • Molecular Weight:226.116

  • Molecular Formula: C10H12BrN

  • HS Code:

  • Mol File:60256-44-2.mol

Synonyms:

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Safety information and MSDS view more

  • Signal Word:no data available

  • Hazard Statement:no data available

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

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Relevant articles and documentsAll total 2 Articles be found

Enantioselective Palladium(II)-Catalyzed Intramolecular Aminoarylation of Alkenes by Dual N?H and Aryl C?H Bond Cleavage

Zhang, Wen,Chen, Pinhong,Liu, Guosheng

supporting information, p. 5336 - 5340 (2017/04/27)

An asymmetric palladium-catalyzed intramolecular oxidative aminoarylation of alkenes has been developed with quinoline–oxazoline chiral ligands and Ag2CO3 as the oxidant. Various indolines containing a quaternary stereogenic center were synthesized in high yield with excellent enantioselectivity. Preliminary mechanistic studies suggest that the addition of a catalytic amount of phenylglyoxylic acid significantly accelerates the reaction and slightly enhances the enantioselectivity.

Direct Coupling between β-Functionalized Organolithium Compounds and Aryl and Vinyl Halides

Barluenga, Jose,Montserrat, Javier M.,Florez, Josefa

, p. 6183 - 6186 (2007/10/02)

Treatment of N-lithio-N-(2-lithioethyl)benzamide with different aromatic and vinylic halides affords directly the corresponding substitution products: functionalized benzamides 3-10.

Process route upstream and downstream products

Process route

N-methylaniline
100-61-8

N-methylaniline

2-bromoallyl bromide
513-31-5

2-bromoallyl bromide

N-Methyl-N-phenyl-2-bromo-2-propenylamine
60256-44-2

N-Methyl-N-phenyl-2-bromo-2-propenylamine

Conditions
Conditions Yield
With n-butyllithium; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 8h;
52%
With n-butyllithium; In tetrahydrofuran;
N-Methyl-N-phenyl-2-bromo-2-propenylamine
60256-44-2

N-Methyl-N-phenyl-2-bromo-2-propenylamine

Conditions
Conditions Yield
entspr.Amin, entspr.Halohydrin;
N-Methyl-N-phenyl-2-bromo-2-propenylamine
60256-44-2

N-Methyl-N-phenyl-2-bromo-2-propenylamine

N-methylaniline
100-61-8

N-methylaniline

C<sub>10</sub>H<sub>12</sub><sup>(2)</sup>HN

C10H12(2)HN

Conditions
Conditions Yield
N-Methyl-N-phenyl-2-bromo-2-propenylamine; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃;
With N,N,N,N,-tetramethylethylenediamine; In diethyl ether; pentane;
With water-d2; In diethyl ether; pentane; Further stages.;
N-Methyl-N-phenyl-2-bromo-2-propenylamine
60256-44-2

N-Methyl-N-phenyl-2-bromo-2-propenylamine

methyl(2-morpholin-4-ylallyl)phenylamine

methyl(2-morpholin-4-ylallyl)phenylamine

Conditions
Conditions Yield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; palladium diacetate; In toluene; at 80 ℃; for 1h;
96%
N-Methyl-N-phenyl-2-bromo-2-propenylamine
60256-44-2

N-Methyl-N-phenyl-2-bromo-2-propenylamine

4-methoxy-aniline
104-94-9

4-methoxy-aniline

(4-methoxyphenyl)[1-methyl-2-(methylphenylamino)ethylidene]amine

(4-methoxyphenyl)[1-methyl-2-(methylphenylamino)ethylidene]amine

Conditions
Conditions Yield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); In toluene; at 90 ℃; for 0.333333h;
92%
N-Methyl-N-phenyl-2-bromo-2-propenylamine
60256-44-2

N-Methyl-N-phenyl-2-bromo-2-propenylamine

N-methylaniline
100-61-8

N-methylaniline

N,N'-dimethyl-1-methylene-N,N'-diphenyl-1,2-ethanediamine

N,N'-dimethyl-1-methylene-N,N'-diphenyl-1,2-ethanediamine

Conditions
Conditions Yield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; palladium diacetate; In toluene; at 80 ℃; for 1.5h;
95%
N-Methyl-N-phenyl-2-bromo-2-propenylamine
60256-44-2

N-Methyl-N-phenyl-2-bromo-2-propenylamine

4-methoxy-benzylamine
2393-23-9

4-methoxy-benzylamine

[2-(4-methoxybenzylimino)propyl]methylphenylamine

[2-(4-methoxybenzylimino)propyl]methylphenylamine

Conditions
Conditions Yield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); In toluene; at 90 ℃; for 0.75h;
93%
N-Methyl-N-phenyl-2-bromo-2-propenylamine
60256-44-2

N-Methyl-N-phenyl-2-bromo-2-propenylamine

(E)-2-Deuterio-4-deuteriomethyl-N,N'-dimethyl-2-penten-1,5-diamine

(E)-2-Deuterio-4-deuteriomethyl-N,N'-dimethyl-2-penten-1,5-diamine

Conditions
Conditions Yield
N-Methyl-N-phenyl-2-bromo-2-propenylamine; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃;
With zirconocene dichloride; In tetrahydrofuran; diethyl ether; pentane; at -78 - 20 ℃; for 5h;
With water-d2; In tetrahydrofuran; diethyl ether; pentane; at 20 ℃; Further stages.;
91%
N-Methyl-N-phenyl-2-bromo-2-propenylamine
60256-44-2

N-Methyl-N-phenyl-2-bromo-2-propenylamine

N,N'-Dimethyl-2,3-dimethylene-N,N'-diphenyl-1,4-butanediamine

N,N'-Dimethyl-2,3-dimethylene-N,N'-diphenyl-1,4-butanediamine

Conditions
Conditions Yield
N-Methyl-N-phenyl-2-bromo-2-propenylamine; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃;
In diethyl ether; pentane; at 20 ℃; for 8h; Further stages.;
81%
N-Methyl-N-phenyl-2-bromo-2-propenylamine
60256-44-2

N-Methyl-N-phenyl-2-bromo-2-propenylamine

(Z)-2,5-Diiodo-N,N'-dimethyl-N,N'-diphenyl-2-penten-1,5-diamine

(Z)-2,5-Diiodo-N,N'-dimethyl-N,N'-diphenyl-2-penten-1,5-diamine

Conditions
Conditions Yield
N-Methyl-N-phenyl-2-bromo-2-propenylamine; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃;
With zirconocene dichloride; In tetrahydrofuran; diethyl ether; pentane; at -78 - 20 ℃; for 5h;
With iodine; In tetrahydrofuran; diethyl ether; pentane; at 20 ℃; Further stages.;
79%

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