60512-57-4

Basic information

• Product Name: Benzene, 1-(2,2-dibromoethenyl)-4-methoxy-
• Synonyms: 2,2-dibromo-1-(4'-methoxyphenyl)ethene;Benzene,1-(2,2-dibromoethenyl)-4-methoxy;1,1-dibromo-2-(4-methoxyphenyl)ethylene;(4-methoxyphenyl)vinylidene dibromide;1-(4-methoxyphenyl)-2,2-dibromoethylene
• CAS NO: 60512-57-4
• Molecular Formula: C9H8Br2O
• Molecular Weight: 291.97
• Mol File: 60512-57-4.mol
• Article Data: 89

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(2,2-dibromoethenyl)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(2,2-dibromoethenyl)-4-methoxy-(60512-57-4)
• EPA Substance Registry System: Benzene, 1-(2,2-dibromoethenyl)-4-methoxy-(60512-57-4)

Safety Data

• Hazardous Substances Data: 60512-57-4(Hazardous Substances Data)

Upstream product

• 558-13-4 carbon tetrabromide 
• 5953-85-5 p-anisaldehyde hydrazone 
• 56506-90-2 (dibromomethyl)(triphenyl)phosphonium bromide 
• 105-13-5 4-Methoxybenzyl alcohol 
• 2746-25-0 p-Methoxybenzyl bromide 
• 123-11-5 4-methoxy-benzaldehyde 
• 1111758-14-5 (Z)-1-iodo-2-(4-methoxyphenyl)-1-trimethylsilylethene 
• 874918-25-9 1-(4-methoxyphenyl)-2,2-bis(trimethylsilyl)ethylene 
• 603-35-0 triphenylphosphine 
• 81559-61-7 1-methoxy-4-(2,2,2-tribromoethyl)benzene 

Downstream Products

• 877-99-6 1-methoxy-4-(2-methyl-1-propenyl)benzene 
• 104-01-8 4-Methoxyphenylacetic acid 
• 33675-41-1 1-bromo-2-(4-methoxyphenyl)acetylene 
• 144256-13-3 1,1-dibromo-2-(4-hydroxyphenyl)ethylene 
• 768-60-5 4-methoxyphenylacetylen 
• 77295-86-4 (E)-4-(4-Methoxyphenyl)-1-(4-nitrophenyl)-1-buten-3-in 
• 157019-54-0 isopropyl 3-(4-methoxyphenyl)propiolate 
• 7515-17-5 methyl 3-(4-methoxyphenyl)propynoate 
• 7577-08-4 1-(cyclohexylidenemethyl)-4-methoxy-benzene 
• 22779-05-1 1,4-bis(4-methoxyphenyl)-1,3-butadiyne 
• 398-23-2 4,4'-difluorobiphenyl 
• 64583-16-0 1-fluoro-4-[2-(4-methoxyphenyl)ethynyl]benzene 
• 92-52-4 biphenyl 
• 7380-78-1 4-(phenylethynyl)anisole 

Relevant articles and documents

Molecular Solar Thermal Batteries through Combination of Magnetic Nanoparticle Catalysts and Tailored Norbornadiene Photoswitches

Cobalt catalysts are immobilized on the surface of iron oxide nanoparticles for the preparation of highly active quasi-homogeneous catalysts toward an efficient release of photochemically stored energy in norbornadiene-based photoswitches. The facile sepa

Synthesis of 3,4-bis(Butylselanyl)selenophenes and 4-alkoxyselenophenes promoted by oxone

We describe herein an alternative transition-metal-free procedure to access 3,4-bis(butylsela nyl)selenophenes and the so far unprecedented 3-(butylselanyl)-4-alkoxyselenophenes. The protocol involves the 5-endo-dig electrophilic cyclization of 1,3-diynes promoted by electrophilic organosele-nium species, generated in situ through the oxidative cleavage of the Se-Se bond of dibutyl diselenide using Oxone as a green oxidant. The selective formation of the title products was achieved by controlling the solvent identity and the amount of dibutyl diselenide. By using 4.0 equiv of dibutyl diselenide and acetonitrile as solvent at 80?C, four examples of 3,4-bis(butylselanyl)selenophenes were obtained in moderate to good yields (40–78%). When 3.0 equiv of dibutyl diselenide were used, in the presence of aliphatic alcohols as solvent/nucleophiles under reflux, 10 3-(butylselanyl)-4-alkoxyselenophenes were selectively obtained in low to good yields (15–80%).

Pd-Catalyzed Indole Synthesis via C-H Activation and Bisamination Sequence with Diaziridinone

This work describes an efficient Pd-catalyzed indole synthesis. A wide variety of indoles can be obtained in good yields from readily available vinyl bromides. The reaction likely proceeds through a sequential aryl C-H activation and bisamination of a resulting pallada(II)cycle with diaziridinone.