61066-33-9Relevant articles and documents
Facile synthesis of 1,2,3-tricarbonyls from 1,3-dicarbonyls mediated by cerium(IV) ammonium nitrate
Sivan, Akhil,Deepthi, Ani
supporting information, p. 1890 - 1893 (2014/03/21)
A mild and efficient protocol for the synthesis of vicinal tricarbonyl compounds from β-dicarbonyls in a single step using cerium(IV) ammonium nitrate as a catalytic oxidant is described. Ease of execution, wide substrate scope and the suitability for the synthesis of commercially important compounds like ninhydrin, alloxan and oxoline make this reaction particularly noteworthy.
Catalytic strategies for sustainable oxidations
Carraro, Mauro,Sartorel, Andrea,Scorrano, Gianfranco,Carofiglio, Tommaso,Bonchio, Marcella
experimental part, p. 1971 - 1978 (2009/04/07)
Several catalytic protocols for the oxidation of hydro-soluble substrates are presented that employ totally inorganic and robust polyoxometalate-based catalysts as well as porphyrin sensi-tizers, fullerenes and hybrid conjugates. Strategies for the imple-mentation of the system stability and efficiency are discussed.
Voltammetric and chronoamperometric investigations on the oxidation of 7-methylxanthine
Goyal, Rajendra N.,Singhal, Naveen K.
, p. 49 - 55 (2007/10/03)
Electrooxidation of 7-methylxanthine has been studied at pyrolytic graphite electrode in phosphate to be buffers of pH 2.0-10.9. A well defined 4e, 4H+ oxidation peak was noticed and an unstable diimine is formed whose half life has been found to be 40 ms by chronoamperometry. The reaction has been identified as EC in which charge transfer is followed by chemical reactions. The products have been characterized by m.p., 1HNMR and mass spectrum and a tentative reaction mechanism for their formation is suggested.