6110-37-8Relevant articles and documents
Dimeric orsellinic acid derivatives: Valuable intermediates for natural product synthesis
Drochner, Daniel,Huettel, Wolfgang,Bode, Silke E.,Mueller, Michael,Karl, Ulrich,Nieger, Martin,Steglich, Wolfgang
, p. 1749 - 1758 (2007)
Herein we report on the synthesis of dimeric orsellinates by the Ullmann reaction as well as by biomimetic oxidative phenolic coupling. The Ullmann reaction gives the 5,5′- and 3,3′-coupled dimeric orsellinates 9 and 10 regioselectively. Oxidative phenoli
Enantioselective total synthesis of β-zearalenol from (s)-propylene oxide
Kotla, Ravindar,Murugulla, Adharvana Chari,Ruddarraju, Radhakrishnamraju,Aparna,Donthabakthuni, Shobha,Sridhar, Gattu
supporting information, p. 747 - 752 (2018/03/29)
The total synthesis of 14-membered resorcylic acid macrolide, β-zearalenol, was accomplished starting from commercially available enantiomerically pure propylene oxide and methyl 2,4-dihydroxy-6-methylbenzoate using Grignard reaction, asymmetric dihydroxy
Synthesis of (3R,5S)-5-hydroxy-de-O-methyllasiodiplodin: A facile and stereoselective approach
Bujaranipalli, Sheshurao,Das, Saibal
supporting information, p. 3747 - 3749 (2015/06/08)
A concise and facile synthesis of (3R,5S)-5-hydroxy-de-O-methyllasiodiplodin has been demonstrated in 12 steps starting from methylacetoacetate and (±)propylene oxide. The key reactions involved are Jacobsen's hydrolytic kinetic resolution, Sharpless asymmetric epoxidation, Mitsunobu, and ring closing metathesis reaction for the construction of macrolactone with two chiral substitutions on it.