611168-46-8

Basic information

• Product Name: 5-Bromo-2-(tributylstannyl)pyridine
• Synonyms: 5-Bromo-2-(tributylstannyl)pyridine;5-BroMo-2-(tributylstannyl)pyridine 97% (H-NMR)
• CAS NO: 611168-46-8
• Molecular Formula: C₁₇H₃₀BrNSn
• Molecular Weight: 447
• Product Categories: Building Blocks;C13 to C40;C7 to C18;Chemical Synthesis;Halogenated Heterocycles;Heterocyclic Building Blocks;Organometallic Reagents;Organotin;Organotins;Pyridines
• Mol File: 611168-46-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 140-145℃
• Appearance: /
• Density: 1.317g/mLat 25℃
• Refractive Index: n20/D 1.535
• PKA: 2.84±0.29(Predicted)
• CAS DataBase Reference: 5-Bromo-2-(tributylstannyl)pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Bromo-2-(tributylstannyl)pyridine(611168-46-8)
• EPA Substance Registry System: 5-Bromo-2-(tributylstannyl)pyridine(611168-46-8)

Safety Data

• Hazard Codes: T,N
• Statements: 21-25-36/38-48/23/25-50/53
• Safety Statements: 35-36/37/39-45-60-61
• RIDADR: UN 2788 6.1/PG 2
• WGK Germany: 3
• Hazardous Substances Data: 611168-46-8(Hazardous Substances Data)

Usage

Uses

5-Bromo-2-(tributylstannyl)pyridine can be used in the synthesis of:1,10-Phenanthroline based ditopic ligand, which is used to prepare bistable metallic rotaxanes.Donor-acceptor type isomeric platinum(II) complexes exhibiting excellent optoelectronic properties for OLED applications.Pt(II) polymetallayne derived orange phosphorescent polymers applicable in phosphorescent OLEDs (PHOLEDs).

Upstream product

• 624-28-2 2,5-dibromopyridine 
• 1461-22-9 tributyltin chloride 

Downstream Products

• 15862-18-7 5,5'-dibromo-2,2'-dipyridyl 
• 1042150-70-8 C₁₀H₆Br₂N₂ 
• 223463-10-3 5,5''-dibromo-2,2',6',2''-terpyridine 
• 1042150-68-4 C₁₀H₆BrIN₂ 
• 1361215-97-5 5-bromo-2-(4-(phenylsulfonyl)phenyl)pyridine 
• 890936-07-9 5-(8-(4-methoxyphenyl)-1,10-phenanthrolin-3-yl)-5''-methyl-2,2':6',2''-terpyridine 

Relevant articles and documents

Platinum coordination compound, organic light emitting diode, and apparatus capable of emitting visible light or near infrared light

The present invention provides a platinum coordination compound, an organic light emitting diode, and an apparatus capable of emitting visible light or near infrared light. The platinum coordination compound has a structure represented by the following general formula (I), wherein A1-A4 are respectively and independently an unsaturated 5-membered ring or an unsaturated 6-membered ring, X is carbonor nitrogen, the formal charge number of the first chelating ligand having A1 and A4 is negative univalence, and the formal charge number of the second chelating ligand having A2 and A3 is negative univalence. According to the present invention, the platinum coordination compound has advantages of stable structure, excellent luminous efficiency and simple synthesis steps. The general formula (I)is defined in the specification.

Synthesis of a novel ditopic ligand incorporating directly bonded 1,10-phenanthroline and 2,2′:6′,2″-terpyridine units

The synthesis of a rigid ditopic ligand incorporating a 1,10-phenanthroline directly connected through its 3-position to the 5-position of a 2,2′:6′,2″-terpyridine is described. The synthesis is based on a series of palladium(0)-catalyzed cross-coupling reactions (Stille and Suzuki couplings) starting from 1,10-phenanthroline and bromo-substituted pyridines.