61204-01-1

Basic information

• Product Name: trans-4-(4-Pentylcyclohexyl)benzonitrile
• Synonyms: 4-(4-pentylcyclohexyl)-,trans-Benzonitrile;4-(4-pentyl-cyclohexyl)-benzonitrile;4-(trans-pentylcyclohexyl)benzonitrile;1α-(4-Cyanophenyl)-4β-pentylcyclohexane;4-[(1α)-4β-Pentylcyclohexyl]benzonitrile;4-[(1α,4β)-4-Pentylcyclohexyl]benzonitrile;4-[(1β)-4α-Pentylcyclohexyl]benzonitrile;5-[4-(4-cyanophenyl)cyclohexyl]pentylidyne
• CAS NO: 61204-01-1
• Molecular Formula: C₁₈H₂₅N
• Molecular Weight: 255.4
• EINECS: 262-656-6
• Product Categories: Cyanobiphenyls & Analogs (Liquid Crystals);Functional Materials;Liquid Crystals & Related Compounds;Liquid Crystals;Nematic;Organic Electronics and Photonics;cyclohexyl phenyl compounds
• Mol File: 61204-01-1.mol

Chemical Properties

• Melting Point: 30-55 °C(lit.)
• Boiling Point: 381 °C at 760 mmHg
• Flash Point: >230 °F
• Appearance: /liquid crystal (nematic)
• Density: 0.97 g/cm₃
• Vapor Pressure: 5.22E-06mmHg at 25°C
• Refractive Index: 1.522
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility: soluble in Methanol
• CAS DataBase Reference: trans-4-(4-Pentylcyclohexyl)benzonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: trans-4-(4-Pentylcyclohexyl)benzonitrile(61204-01-1)
• EPA Substance Registry System: trans-4-(4-Pentylcyclohexyl)benzonitrile(61204-01-1)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• TSCA: Yes
• Hazardous Substances Data: 61204-01-1(Hazardous Substances Data)

Usage

Chemical Properties

White crystalline powder

Uses

Intermediates of Liquid Crystals

InChI:InChI=1/C18H25N/c1-2-3-4-5-15-6-10-17(11-7-15)18-12-8-16(14-19)9-13-18/h8-9,12-13,15,17H,2-7,10-11H2,1H3/t15-,17-

Upstream product

• 73011-80-0 4-(4-Pentyl-cyclohexyl)-benzamide 
• 61203-83-6 4-n-pentylcyclohexanone 
• 78531-59-6 4-(4'-pentyl-cyclohexyl)-acetophenone 
• 78531-55-2 (4-Pentylidene-cyclohexyl)-benzene 
• 88069-97-0 (4-n-pentylcyclohexen-1-yl)-benzene 
• 61203-96-1 trans-4-pentyl-1-phenylcyclohexane 
• 88069-95-8 4-Pentyl-1-phenyl-cyclohexanol 
• 88070-00-2 1-(4-Phenyl-cyclohexyl)-pentan-1-ol 
• 73011-79-7 4-(trans-4'-n-Pentylcyclohexyl)benzoic acid chloride 
• 65355-30-8 4-(Trans-4'-pentylcyclohexyl)-benzoic acid 
• 73011-78-6 trans-1-(4-fenilcicloesil)-1-pentanone 
• 82241-68-7 cis-4-pentanoyl-1-phenylcyclohexane 
• 344308-23-2 1-(4-Chloro-cyclohexyl)-hexan-1-one 
• 113035-74-8 trans-1-(4-Phenylcyclohexyl)-1-hexanon 

Downstream Products

• 95149-38-5 trans-1-(4-pentanoylphenyl)-4-pentylcyclohexane 
• 78531-59-6 4-(4'-pentyl-cyclohexyl)-acetophenone 
• 95149-36-3 1-[4-(4-Pentyl-cyclohexyl)-phenyl]-propan-1-one 
• 101160-88-7 α-(4-bromophenyl)-4-(trans-4-pentylcyclohexyl)acetophenone 
• 101160-86-5 α-(4-chloro-2-fluorophenyl)-4-(trans-4-pentylcyclohexyl)acetophenone 
• 65355-30-8 4-(Trans-4'-pentylcyclohexyl)-benzoic acid 
• 937725-66-1 N-(2,3,5-trifluoro-4-hexyloxy-6-(propylsulfanyl)phenyl)-4-(4E-pentylcyclohexyl)benzamidine 
• 937725-55-8 5,6,8-trifluoro-7-hexyloxy-3-(4-(E-4-pentylcyclohexyl)phenyl)-4H-benzo[1,2,4]thiadiazine 
• 101161-07-3 1-(4-bromophenyl)-2-<4-(trans-4-pentylcyclohexyl)phenyl>ethane 
• 101160-87-6 1-(4-chloro-2-fluorophenyl)-2-<4-(trans-4-pentylcyclohexyl)phenyl>ethane 

Relevant articles and documents

Process for preparing 2,3-dihydro-1,3-dialkyl-2,3-dialkyl perimidines and N,N-'-dialkyl-1,8-naphthalene diamines

Processes for preparing 2,3-dihydro-1,3-dialkyl-2,2-dialkyl perimidines and N,N'-dialkyl-1,8-naphthalene diamines are disclosed. The 2,3-dihydro-1,3-dialkyl-2,2-dialkyl perimidines are prepared by alkylating 2,3-dihydro-2,2-dialkyl perimidines with an alkylating agent in a water miscible organic solvent at room temperature to 80° C. in the presence of water and an inorganic base. N,N'-dialkyl-1,8-naphthalene diamines are prepared by hydrolyzing the 2,3-dihydro-1,3-dialkyl-2,2-dialkyl perimidines with strong aqueous acid in an aqueous organic solvent and removing a ketone by-product and the aqueous organic solvent by codistillation.

SYNTHESIS OF TRANS-4-ALKYL-1-PHENYLCYCLOHEXANES AND THEIR DERIVATIVES

The alkylation of benzene by 1-alkanoyl-2-chlorocyclohexanes and 1-alkanoyl-1-cyclohexenes leads to the formation of cis- and trans-4-alkanoyl-1-phenylcyclohexanes, the yields of which increase with increase in the reaction temperature. trans-4-Alkyl-1-phenylcyclohexanes were obtained from 4-alkanoyl-1-phenylcyclohexanes and also from the products from the reaction of 4-alkylcyclohexanones with phenylmagnesium bromide.Some mesomorphous derivatives of these hydrocarbons were synthesized.

CONVENIENT SYNTHESIS OF 4-(TRANS-4 prime -N-ALKYLCYCLOHEXYL) BENZOIC ACIDS.

A convenient method of obtaining 4-(trans-4 prime -n-alkylcyclohexyl) benzoic acids from alkanoyl chlorides, cyclohexane and benzene is described. Homologous series of above mentioned acids and their nitriles with alkyl tail 2 to 10 carbon atoms were prepared and temperatures of their phase transitions were determined.