6136-67-0Relevant articles and documents
Geometric and solvent effects on intramolecular phenolic hydrogen abstraction by carbonyl n,π* and π,π* triplets
Lathioor, Edward C.,Leigh, William J.
, p. 1851 - 1863 (2001)
The photochemistry of a series of alkoxyacetophenone, -benzophenone, and -indanone derivatives, which contain a remote phenolic group linked to the ketone by a para,para′- or meta,meta′-oxyethyl spacer, has been studied in acetonitrile and dichloromethane
Mechanochemical Solvent-Free Suzuki–Miyaura Cross-Coupling of Amides via Highly Chemoselective N?C Cleavage
Ma, Yangmin,Shao, Lei,Szostak, Michal,Wang, Ruihong,Zhang, Jin,Zhang, Pei
supporting information, (2022/01/04)
Although cross-coupling reactions of amides by selective N?C cleavage are one of the most powerful and burgeoning areas in organic synthesis due to the ubiquity of amide bonds, the development of mechanochemical, solid-state methods remains a major challe
Acylboronates in polarity-reversed generation of acyl palladium(II) intermediates
Trofimova, Alina,Holownia, Aleksandra,Tien, Chieh-Hung,?irvinskas, Martynas J.,Yudin, Andrei K.
supporting information, p. 3294 - 3299 (2021/05/07)
We report a catalytic cross-coupling process between aryl (pseudo)halides and boron-based acyl anion equivalents. This mode of acylboronate reactivity represents polarity reversal, which is supported by the observation of tetracoordinated boronate and acyl palladium(II) species by 11B, 31P NMR, and mass spectrometry. A broad scope of aliphatic and aromatic acylboronates has been examined, as well as a variety of aryl (pseudo)halides.
