Welcome to LookChem.com Sign In|Join Free

Cas Database

614-14-2

614-14-2

Identification

  • Product Name:Benzenemethanol, a-propyl-

  • CAS Number: 614-14-2

  • EINECS:

  • Molecular Weight:150.221

  • Molecular Formula: C10H14 O

  • HS Code:

  • Mol File:614-14-2.mol

Synonyms:Benzylalcohol, a-propyl- (6CI,7CI,8CI); (?à)-1-Phenyl-1-butanol; (?à)-1-Phenylbutanol; (?à)-a-Propylbenzenemethanol; (?à)-a-Propylbenzyl alcohol; 1-Butanol, 1-phenyl-; 1-Phenyl-1-butanol;1-Phenylbutanol; NSC 406592; NSC 4887; a-Propylbenzenemethanol; a-Propylbenzyl alcohol

Post Buying Request Now
Entrust LookChem procurement to find high-quality suppliers faster

Safety information and MSDS view more

  • Signal Word:no data available

  • Hazard Statement:no data available

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:Usbiological
  • Product Description:1-Phenyl-1-butanol
  • Packaging:1g
  • Price:$ 312
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:TCI Chemical
  • Product Description:1-Phenyl-1-butanol >98.0%(GC)
  • Packaging:25g
  • Price:$ 220
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:TCI Chemical
  • Product Description:1-Phenyl-1-butanol >98.0%(GC)
  • Packaging:5g
  • Price:$ 74
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Ambeed
  • Product Description:1-Phenyl-1-butanol 96%
  • Packaging:25g
  • Price:$ 240
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Ambeed
  • Product Description:1-Phenyl-1-butanol 96%
  • Packaging:10g
  • Price:$ 122
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Ambeed
  • Product Description:1-Phenyl-1-butanol 96%
  • Packaging:5g
  • Price:$ 73
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Ambeed
  • Product Description:1-Phenyl-1-butanol 96%
  • Packaging:1g
  • Price:$ 21
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:AK Scientific
  • Product Description:1-Phenyl-1-butanol
  • Packaging:500mg
  • Price:$ 166
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:AK Scientific
  • Product Description:1-Phenyl-1-butanol
  • Packaging:250mg
  • Price:$ 163
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:AHH
  • Product Description:1-Phenyl-1-butanol 98%
  • Packaging:10g
  • Price:$ 608
  • Delivery:In stock
  • Buy Now

Relevant articles and documentsAll total 167 Articles be found

Zirconium-catalyzed cyclopropanation of α-olefins mediated by R′CO2R″ and ClnAlEt3-n

Khafizova, Leila O.,Gubaidullin, Rinat R.,Dzhemilev, Usein M.

, p. 9142 - 9147 (2011)

A Cp2ZrCl2-catalyzed one-pot cyclopropanation method has been developed to afford alkoxycyclopropanes and cyclopropanols from α-olefins involving esters of carboxylic acids and ClnAlEt 3-n.

The Comparative Effect of Particle Size and Support Acidity on Hydrogenation of Aromatic Ketones

Kim, Kyung Duk,Wang, Zichun,Tao, Yongwen,Ling, Huajuan,Yuan, Yuan,Zhou, Cuifeng,Liu, Zongwen,Gaborieau, Marianne,Huang, Jun,Yu, Aibing

, p. 4810 - 4817 (2019)

A comparative study was reported for both the effects of shape-confined cubic Pd particle size (8, 13, and 21 nm) and surface property of most commonly used supports (SiO2, Al2O3, and silica-alumina) on catalytic performance in the chemoselective hydrogenation of three model bio-oil chemicals (benzaldehyde, acetophenone, and butyrophenone). The results showed that the size of Pd particles could be more associated with the hydrogenation reaction than acidities of the supports. Smaller size of Pd particles, regardless of the type of the support, provided the higher catalytic performance. XPS data showed that the electronic properties of Pd particles were similar, therefore, the possible reasons were the higher fraction of Pd atoms on corner in smaller particles, the lower accessibility of hydrogen atom to reactant on bigger particles, and the more low-coordinated sites in the small-size particles due to the short-range ordering. In addition, Pd/SA catalysts (Br?nsted acid sites on the support) showed the highest conversion and TOF compared to Pd/Al2O3 and Pd/SiO2 catalysts. This might be due to the enhanced the diffusion rates of the chemicals on the surface of the catalysts although they could not induce the ionic effect from the metal surface. Pd/SiO2 catalysts performed better than Pd/Al2O3 catalysts (Lewis acid sites on the support). The flexible SiOH groups on surface made the easy interaction with the metal particles and promote the reaction.

Pincerlike molybdenum complex and preparation method thereof, catalytic composition and application thereof, and alcohol preparation method

-

Paragraph 0125-0130, (2021/08/11)

The invention discloses a clamp-type molybdenum complex, a preparation method, a corresponding catalyst composition and application. The method comprises the steps: obtaining 9 molybdenum complexes with different structures through coordination reaction of 2-(substituent ethyl)-(5, 6, 7, 8-tetrahydroquinolyl) amine and a corresponding carbonyl molybdenum metal precursor; and catalyzing a ketone compound transfer hydrogenation reaction through a molybdenum complex to generate 40 alcohol compounds. The preparation method of the molybdenum complex is simple, high in yield and good in stability. For a transfer hydrogenation reaction of ketone, the molybdenum-based catalytic system has high catalytic activity and small molybdenum loading capacity, is used for production of aromatic and aliphatic alcohols, and has the advantages of simple method, small environmental pollution and high yield.

Ambient-pressure highly active hydrogenation of ketones and aldehydes catalyzed by a metal-ligand bifunctional iridium catalyst under base-free conditions in water

Wang, Rongzhou,Yue, Yuancheng,Qi, Jipeng,Liu, Shiyuan,Song, Ao,Zhuo, Shuping,Xing, Ling-Bao

, p. 1 - 7 (2021/05/17)

A green, efficient, and high active catalytic system for the hydrogenation of ketones and aldehydes to produce corresponding alcohols under atmospheric-pressure H2 gas and ambient temperature conditions was developed by a water-soluble metal–ligand bifunctional catalyst [Cp*Ir(2,2′-bpyO)(OH)][Na] in water without addition of a base. The catalyst exhibited high activity for the hydrogenation of ketones and aldehydes. Furthermore, it was worth noting that many readily reducible or labile functional groups in the same molecule, such as cyan, nitro, and ester groups, remained unchanged. Interestingly, the unsaturated aldehydes can be also selectively hydrogenated to give corresponding unsaturated alcohols with remaining C=C bond in good yields. In addition, this reaction could be extended to gram levels and has a large potential of wide application in future industrial.

Method for synthesizing secondary alcohol in water phase

-

Paragraph 0038-0039, (2021/07/14)

The invention discloses a method for synthesizing secondary alcohol in a water phase. The method comprises the following steps: taking ketone as a raw material, selecting water as a solvent, and carrying out catalytic hydrogenation reaction on the ketone in the presence of a water-soluble catalyst to obtain the secondary alcohol, wherein the catalyst is a metal iridium complex [Cp * Ir (2, 2'-bpyO)(OH)][Na]. Water is used as the solvent, so that the use of an organic solvent is avoided, and the method is more environment-friendly; the reaction is carried out at relatively low temperature and normal pressure, and the reaction conditions are mild; alkali is not needed in the reaction, so that generation of byproducts is avoided; and the conversion rate of the raw materials is high, and the yield of the obtained product is high. The method not only has academic research value, but also has a certain industrialization prospect.

Ruthenium-p-cymene Complex Side-Wall Covalently Bonded to Carbon Nanotubes as Efficient Hybrid Transfer Hydrogenation Catalyst

Blanco, Matías,Cembellín, Sara,Agnoli, Stefano,Alemán, José

, p. 5156 - 5165 (2021/11/05)

A half-sandwich ruthenium-p-cymene organometallic complex has been immobilized at Single Walled Carbon Nanotubes (SWNT) sidewalls through a stepwise covalent chemistry protocol. The introduction of amino groups by means of diazonium-chemistry protocols leads the grafting at the outer walls of the nanotubes. This hybrid material is active in the transfer hydrogenation of ketones to yield alcohols, using as hydrogen source 2-propanol. SWNT?NH2?Ru presents a broad scope, performing the reaction under aerobic conditions and can be recycled over 9 consecutive reaction runs without losing activity or leaching ruthenium out. Comparison of the activity with related homogeneous catalysts reveals an improved performance due to the covalent bond between the metal and the material, achieving turnover frequencies as high as 192774 h?1.

Visible Light Induced Reduction and Pinacol Coupling of Aldehydes and Ketones Catalyzed by Core/Shell Quantum Dots

Xi, Zi-Wei,Yang, Lei,Wang, Dan-Yan,Feng, Chuan-Wei,Qin, Yufeng,Shen, Yong-Miao,Pu, Chaodan,Peng, Xiaogang

, p. 2474 - 2488 (2021/02/05)

We present an efficient and versatile visible light-driven methodology to transform aryl aldehydes and ketones chemoselectively either to alcohols or to pinacol products with CdSe/CdS core/shell quantum dots as photocatalysts. Thiophenols were used as proton and hydrogen atom donors and as hole traps for the excited quantum dots (QDs) in these reactions. The two products can be switched from one to the other simply by changing the amount of thiophenol in the reaction system. The core/shell QD catalysts are highly efficient with a turn over number (TON) larger than 4 × 104 and 4 × 105 for the reduction to alcohol and pinacol formation, respectively, and are very stable so that they can be recycled for at least 10 times in the reactions without significant loss of catalytic activity. The additional advantages of this method include good functional group tolerance, mild reaction conditions, the allowance of selectively reducing aldehydes in the presence of ketones, and easiness for large scale reactions. Reaction mechanisms were studied by quenching experiments and a radical capture experiment, and the reasons for the switchover of the reaction pathways upon the change of reaction conditions are provided.

Process route upstream and downstream products

Process route

propiophenone
495-40-9

propiophenone

1-Phenylethanol
98-85-1,13323-81-4

1-Phenylethanol

1-Phenyl-1-butanol
614-14-2

1-Phenyl-1-butanol

acetophenone
98-86-2

acetophenone

Conditions
Conditions Yield
With hydrogen selenide; In methanol; at 20 ℃; for 24h; Irradiation;
With hydrogen selenide; In methanol; at 20 ℃; for 24h; Irradiation;
82 % Chromat.
peracide phenyl-5 pentanoique
85696-63-5

peracide phenyl-5 pentanoique

tetralin
119-64-2

tetralin

4-phenyl-butan-1-ol
3360-41-6

4-phenyl-butan-1-ol

1-Phenyl-1-butanol
614-14-2

1-Phenyl-1-butanol

5-Phenylpentanoic acid
2270-20-4

5-Phenylpentanoic acid

4-Phenylbutyric acid
1821-12-1

4-Phenylbutyric acid

Conditions
Conditions Yield
In n-heptane; at 98 ℃; Mechanism; Product distribution;
75 % Chromat.
4 % Chromat.
2 % Chromat.
7 % Chromat.
ethanol
64-17-5

ethanol

acetophenone
98-86-2

acetophenone

rac-1,3-diphenyl-1-butanol
4435-52-3

rac-1,3-diphenyl-1-butanol

1-Phenylethanol
98-85-1,13323-81-4

1-Phenylethanol

1-Phenyl-1-butanol
614-14-2

1-Phenyl-1-butanol

Conditions
Conditions Yield
With sodium hydroxide; at 120 ℃; for 24h;
26 %Chromat.
15 %Chromat.
24 %Chromat.
ethanol
64-17-5

ethanol

acetophenone
98-86-2

acetophenone

1-Phenylethanol
98-85-1,13323-81-4

1-Phenylethanol

1-Phenyl-1-butanol
614-14-2

1-Phenyl-1-butanol

propiophenone
495-40-9

propiophenone

Conditions
Conditions Yield
With C25H27ClIrN4O(1+)*Cl(1-); potassium hydroxide; at 120 ℃; for 4h; Time;
45 %Spectr.
34%Spectr.
20%Spectr.
With C25H27ClIrN4O(1+)*Cl(1-); potassium hydroxide; at 120 ℃; for 4h; Time;
50 %Spectr.
10 %Spectr.
25 %Spectr.
With C25H27ClIrN4O(1+)*Cl(1-); potassium hydroxide; at 120 ℃; for 4h; Time;
61 %Spectr.
19%Spectr.
14 %Spectr.
1-phenyl-1-butyne
622-76-4,83585-27-7

1-phenyl-1-butyne

1-Phenyl-1-propanol
93-54-9

1-Phenyl-1-propanol

1-phenyl-3-butanol
2344-70-9

1-phenyl-3-butanol

ethyl (E)-1-phenylbut-1-en-3-ol
36004-04-3

ethyl (E)-1-phenylbut-1-en-3-ol

2-phenylbutan-1-ol
2035-94-1,89104-46-1

2-phenylbutan-1-ol

1-Phenyl-1-butanol
614-14-2

1-Phenyl-1-butanol

benzyl alcohol
100-51-6,185532-71-2

benzyl alcohol

Conditions
Conditions Yield
With lithium aluminium tetrahydride; oxygen; at 90 ℃; for 16h; under 759.8 Torr; Product distribution; autoxidation;
34.1 % Turnov.
5.7 % Turnov.
4.7 % Turnov.
11.5 % Turnov.
3.2 % Turnov.
39.1 % Turnov.
1-Phenyl-3-buten-1-ol
80735-94-0,936-58-3

1-Phenyl-3-buten-1-ol

(E)-1-phenyl-2-buten-1-one
35660-91-4,35845-66-0,495-41-0

(E)-1-phenyl-2-buten-1-one

(2E)-1-phenylbut-2-en-1-ol
52755-39-2

(2E)-1-phenylbut-2-en-1-ol

1-Phenyl-1-butanol
614-14-2

1-Phenyl-1-butanol

propiophenone
495-40-9

propiophenone

Conditions
Conditions Yield
With triethylamine; palladium on activated charcoal; In toluene; at 200 ℃; for 12h;
63 % Spectr.
19 % Spectr.
9 % Spectr.
With triethylamine; palladium on activated charcoal; In toluene; at 150 ℃; for 3h;
30 % Spectr.
19 % Spectr.
9 % Spectr.
1-butylbenzene
104-51-8

1-butylbenzene

1-Phenyl-1-butanol
614-14-2

1-Phenyl-1-butanol

1-phenyl-1-butylhydroperoxide
58687-89-1

1-phenyl-1-butylhydroperoxide

propiophenone
495-40-9

propiophenone

Conditions
Conditions Yield
With [(copper(II))0.5(lanthanum(III))2(monoacid 3,5-pyridinedicarboxylate)(3,5-pyridinedicarboxylate)2(sulfate)(H2O)2] monohydrate; oxygen; In neat (no solvent); at 120 ℃; under 760.051 Torr;
ethanol
64-17-5

ethanol

1-Phenylethanol
98-85-1,13323-81-4

1-Phenylethanol

1-Phenyl-1-butanol
614-14-2

1-Phenyl-1-butanol

propiophenone
495-40-9

propiophenone

Conditions
Conditions Yield
With [Ru(P(NOH)2)Cl2(PPh3)]; potassium tert-butylate; In toluene; at 150 ℃; for 24h; Schlenk technique; Inert atmosphere;
75%
10%
2-phenyl-2-propyl-1,3-dioxolane
5660-57-1

2-phenyl-2-propyl-1,3-dioxolane

1-Phenyl-1-butanol
614-14-2

1-Phenyl-1-butanol

propiophenone
495-40-9

propiophenone

Conditions
Conditions Yield
With sodium tetrahydroborate; nickel(II) chloride hexahydrate; In methanol; for 8h; chemoselective reaction; Reflux;
85%
10%
1-butylbenzene
104-51-8

1-butylbenzene

1-Phenyl-1-butanol
614-14-2

1-Phenyl-1-butanol

propiophenone
495-40-9

propiophenone

Conditions
Conditions Yield
With oxygen; for 24h; Yield given. Yields of byproduct given; Ambient temperature; Irradiation;
With cerium(IV) triflate; water; at 20 ℃; for 22.5h;
42.0 % Chromat.
37.0 % Chromat.
With MoO(O2)(3,5-dimethylpyrazole)2; dihydrogen peroxide; oxygen; In acetonitrile; for 13h; Heating; atmospheric pressure;

Global suppliers and manufacturers

Global( 16) Suppliers
  • Company Name
  • Business Type
  • Contact Tel
  • Emails
  • Main Products
  • Country
  • Amadis Chemical Co., Ltd.
  • Business Type:Lab/Research institutions
  • Contact Tel:86-571-89925085
  • Emails:sales@amadischem.com
  • Main Products:29
  • Country:China (Mainland)
  • GIHI CHEMICALS CO.,LIMITED
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-571-86217390
  • Emails:info@gihichem.com
  • Main Products:66
  • Country:China (Mainland)
  • Finetech Industry Limited
  • Business Type:Trading Company
  • Contact Tel:86-27-87465837
  • Emails:sales@finetechnology-ind.com
  • Main Products:29
  • Country:China (Mainland)
  • Antimex Chemical Limied
  • Business Type:Lab/Research institutions
  • Contact Tel:0086-21-50563169
  • Emails:anthony@antimex.com
  • Main Products:163
  • Country:China (Mainland)
  • Hangzhou Keyingchem Co.,Ltd
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-571-85378921
  • Emails:market@keyingchem.com
  • Main Products:105
  • Country:China (Mainland)
  • Debye Scientific
  • Business Type:Lab/Research institutions
  • Contact Tel:+85221376140
  • Emails:sales@debyesci.com
  • Main Products:13
  • Country:China (Mainland)
  • LEAP CHEM Co., Ltd.
  • Business Type:Trading Company
  • Contact Tel:0571-87317139
  • Emails:market15@leapchem.com
  • Main Products:89
  • Country:China (Mainland)
  • Career Henan Chemical Co
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-371-86658258
  • Emails:purchase@coreychem.com
  • Main Products:1
  • Country:China (Mainland)
close
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 614-14-2
Post Buying Request Now
close
Remarks: The blank with*must be completed