61888-16-2Relevant articles and documents
Stereoselective reduction of enaminones to syn γ-aminoalcohols
Bartoli, Giuseppe,Cupone, Giovanna,Dalpozzo, Renato,De Nino, Antonio,Maiuolo, Loredana,Procopio, Antonio,Tagarelli, Antonio
, p. 7441 - 7444 (2007/10/03)
One-pot reduction of enaminones to syn γ-aminoalcohols can be efficiently performed by lithium borohydride in the presence of cerium chloride as Lewis acid. Selectivities are very good with respect to classical reduction method of these products.
Syntheses d'aminoalcools-1,3 ou d'aminophenols-1,3 par reduction d'enaminones ou d'iminophenols par les hydrures metalliques. Etude structurale par infrarouge et RMN des aminoalcools-1,3 bisecondaires diastereomeres
Maroni, Pierre,Cazaux, Louis,Tisnes, Pierre,Zambeti,Marianthie
, p. 179 - 186 (2007/10/02)
Enaminones, obtained by reaction of a primary amine with a β-diketone, can take three tautomeric forms: keto-enamine Ia, keto-imine Ib and imino-enol Ic.In general the keto-enamine form Ia is the most stable.Thi