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Cas Database

622-79-7

622-79-7

Identification

  • Product Name:Benzene, (azidomethyl)-

  • CAS Number: 622-79-7

  • EINECS:

  • Molecular Weight:133.153

  • Molecular Formula: C7H7 N3

  • HS Code:2929909090

  • Mol File:622-79-7.mol

Synonyms:Toluene, a-azido- (6CI,7CI,8CI);(Azidomethyl)benzene; Benzyl azide; NSC 26304; a-Azidotoluene

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Safety information and MSDS view more

  • Pictogram(s):Xi,Xn

  • Hazard Codes:Xi,Xn

  • Signal Word:Danger

  • Hazard Statement:H226 Flammable liquid and vapourH241 Heating may cause a fire or explosion H315 Causes skin irritation H319 Causes serious eye irritation H372 Causes damage to organs through prolonged or repeated exposure

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

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  • Manufacture/Brand:Usbiological
  • Product Description:Benzyl azide
  • Packaging:25g
  • Price:$ 665
  • Delivery:In stock
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  • Manufacture/Brand:TRC
  • Product Description:α-Azidotoluene
  • Packaging:25g
  • Price:$ 1055
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  • Manufacture/Brand:TRC
  • Product Description:α-Azidotoluene
  • Packaging:2.5g
  • Price:$ 130
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Benzyl azide solution ~0.5 M in dichloromethane, ≥95.0% (HPLC)
  • Packaging:50ml
  • Price:$ 295
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Benzyl azide solution ~0.5 M in dichloromethane, ≥95.0% (HPLC)
  • Packaging:10ml
  • Price:$ 115
  • Delivery:In stock
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  • Manufacture/Brand:Oakwood
  • Product Description:Benzyl Azide, Pract.
  • Packaging:1g
  • Price:$ 19
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  • Manufacture/Brand:Oakwood
  • Product Description:Benzyl Azide, Pract.
  • Packaging:250mg
  • Price:$ 15
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  • Manufacture/Brand:Oakwood
  • Product Description:Benzyl Azide, Pract.
  • Packaging:5g
  • Price:$ 70
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  • Manufacture/Brand:Oakwood
  • Product Description:Benzyl Azide, Pract.
  • Packaging:25g
  • Price:$ 280
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:(Azidomethyl)benzene 95%+
  • Packaging:5g
  • Price:$ 323
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Relevant articles and documentsAll total 287 Articles be found

Mutagenicity of alkyl azides

Matsumura,Shiozawa,Matsushita,Terao

, p. 1805 - 1807 (1995)

Alkyl azides showed mutagenicity for S. typhimurium TA100 strain with S9 mix. However, no significant activity was observed for TA98 either with or without S9 mix or for TA100 without S9 mix. On the other hand, 3-azido-1,2- propanediol showed the enantios

Measurement and correlation of the solubility of (1-benzyl-1H-1,2,3-triazole-4-yl)methanol in water and alcohols at temperatures from 292.15 K to 310.15 K

Li, Huiping,Liang, Shuqin,Li, Huiying,Shen, Le,Li, Huanxin,Mao, Zhendong

, p. 1 - 10 (2016)

The solubilities of (1-benzyl-1H-1,2,3-triazole-4-yl)methanol (BTZM) in water, methanol, ethanol, n-propanol, isopropanol, and n-butanol were measured at temperatures ranging from 292.15 K to 310.15 K by a dynamic method under normal atmospheric pressure. The results showed that it increased with the increasing temperature and the order of solvents was: Order: Methanol > ethanol > n-propanol > n-butanol > isopropanol > water except three points. The solubility data were correlated with the Van't Hoff equation, modified Apelblat equation, and λh equation. The average relative deviations (ARD) were 1.87%, 1.53%, and 1.71%, and the root-mean-square-deviations (RMSD) were 2.37 × 10-2, 1.51 × 10-2, and 2.12 × 10-2, respectively. It was found that the modified Apelblat equation gave the best correlation results. Furthermore, the dissolution enthalpy of BTZM was calculated by the modified Apelblat equation.

Combinatorial synthesis of new fluorescent scaffolds using click chemistry

Cleemann, Felix,Karuso, Peter,Kum-Cheung, Wendy Loa

supporting information, (2021/12/08)

Azides and acetylenes are bio-orthogonal functional groups that can be readily coupled using copper(I)- or ruthenium(II)- catalyzed 1,3-dipolar cycloaddition reactions. Using non-fluorescent aromatic azides and aromatic acetylenes, covering a range of electron rich and poor building blocks, the Huisgen cycloaddition afford 1,4-disubstituted or 1,5-disubstituted 1,2,3-triazoles. Using a combinatorial approach by running reaction in parallel in polypropylene 96-well plates we discovered several new fluorescent 1,2,3-triazoles scaffolds. These compounds show diverse interactions with biomolecules that could find applications in biology in, for example, fluorescence microscopy or biomolecule quantification.

Click generated o-Cresolphthalein linked 1,2,3-triazole derivative for selective Pb(II) ion recognition

Saini, Parveen,Singh, Gurjaspreet,Kaur, Gurpreet,Singh, Jandeep,Singh, Harminder

, (2021/12/09)

Present report describes the “turn-on” absorbance response of a molecular assembly o-Cresolphthalein appended 1,4-disubstituted 1,2,3-triazole (o-CPT) on complexation with Pb(II) ions. Copper (I) catalyzed alkyne-azide cycloaddition reaction, a highly versatile and stereoselective approach to stitch diverse structural units has been employed to generate the designed receptor that has been successfully characterized through IR, NMR (1H, 13C) and mass spectroscopic techniques. UV-Visible absorption spectral behavior of o-CPT was examined with a series of metal ions (Mn (II), Ce (III), Hg (II), Ni (II), Pb (II), Zn (II), Fe (II), Cr (III), Co (II) and Na (I)) in acetonitrile-water (4:1, v/v) solution and the results obtained have marked out the sensitivity of the designed probe exclusively towards Pb(II) ions with a measured detection limit of 13 μM at 2:1 stoichiometry of o-CPT:Pb(II) complex.

Alkylphosphinites as Synthons for Stabilized Carbocations

Ochmann, Lukas,Kessler, Mika L.,Schreiner, Peter R.

supporting information, p. 1460 - 1464 (2022/03/01)

We present a new acid-free method for the generation of carbocations based on a redox condensation reaction that enables SN1 reactions with a variety of nucleophiles. We utilize readily synthesized phosphinites that are activated by diisopropyl azodicarboxylate to form betaine structures that collapse upon adding a pronucleophile, thereby yielding reactive carbocation intermediates. We also employ this approach for the alkylation of some bioactive molecules.

Synthesis, Docking, and Biological activities of novel Metacetamol embedded [1,2,3]-triazole derivatives

Battu, Satyanarayana,Joolakanti, Hima Bindhu,Kamepalli, Ramanjaneyulu,Miryala, Jeevanreddy

, (2021/06/18)

ERα controls the breast tissue development and progression of breast cancer. In our search for novel compounds to target Estrogen Receptor Alpha Ligand-Binding Domain, we identified “N-(3-((1H-1,2,3-triazol-4-yl)methoxy)phenyl)acetamide” derivatives as lead compounds. The Docking studies indicated good docking score for Metacetamol derivatives when docked into the 1XP6. A series of metacetamol derivatives have been synthesized, characterized and evaluated for cytotoxicity, anti bacterial and anti oxidant activities. Among the tested twelve hybrid compounds, “7a, 7g, 7h and 7i” derivatives showed promising cytotoxicity with IC50 value of 50 value of 30 μM, whereas Compounds “7a, 7b, 7c, 7d, 7g, 7j, 7k and 7l” showed moderate anti bacterial activity with the MIC value of 300 μM.

Concise synthesis of: N -phosphorylated amides through three-component reactions

Yang, Shang-Dong,Zhang, Tao,Zhou, Linlin,Zhu, Yuan-Yuan

supporting information, p. 9417 - 9421 (2021/12/09)

N-Phosphorylated amides continue to be an unparalleled asset for the development of pharmaceutical molecules, and the importance of this framework has inspired researchers to look for concise and efficient methods for the synthesis of this unit. In this work, a new strategy was developed in which a one-pot synthesis of N-phosphorylated amides was achieved by a three-component reaction with carboxylic acids, phosphorus chlorides and azides under mild reaction conditions. To our knowledge, this is the first study in which this framework was constructed through a multicomponent reaction, which is innovative, efficient and economical. This journal is

Process route upstream and downstream products

Process route

benzyl chloride
100-44-7

benzyl chloride

benzonitrile
100-47-0

benzonitrile

benzyl azide
622-79-7

benzyl azide

Conditions
Conditions Yield
With tetrabutylammoniun azide; In toluene; at 80 ℃; for 10h; under 760.051 Torr;
83 %Chromat.
8 %Chromat.
benzyl bromide
100-39-0

benzyl bromide

benzyl azide
622-79-7

benzyl azide

benzyl alcohol
100-51-6,185532-71-2

benzyl alcohol

Conditions
Conditions Yield
With sodium azide; water; Solvolysis;
90%
10%
1-Benzyl-4,5-diphenyl-4,5-dihydro-1H-tetrazole
97325-74-1

1-Benzyl-4,5-diphenyl-4,5-dihydro-1H-tetrazole

benzylidene phenylamine
538-51-2

benzylidene phenylamine

N-benzylidene benzylamine
780-25-6

N-benzylidene benzylamine

benzyl azide
622-79-7

benzyl azide

Phenyl azide
622-37-7

Phenyl azide

Conditions
Conditions Yield
In (2)H8-toluene; at 100 ℃; for 2h; Yield given. Yields of byproduct given;
1-Benzyl-4-methyl-5-phenyl-4,5-dihydro-1H-tetrazole
97325-73-0

1-Benzyl-4-methyl-5-phenyl-4,5-dihydro-1H-tetrazole

methyl azide
624-90-8

methyl azide

N-benzylidene benzylamine
780-25-6

N-benzylidene benzylamine

N-Benzylidenemethylamine
622-29-7

N-Benzylidenemethylamine

benzyl azide
622-79-7

benzyl azide

Conditions
Conditions Yield
In (2)H8-toluene; at 100 ℃; for 18h; Yield given. Yields of byproduct given;
In (2)H8-toluene; at 100 ℃; for 18h; Product distribution; thermolysis study; other alkyl, aryl tetrazolines, other times, other products;
trimethylsilylazide
4648-54-8

trimethylsilylazide

benzyl bromide
100-39-0

benzyl bromide

trimethylsilyl bromide
2857-97-8

trimethylsilyl bromide

benzyl azide
622-79-7

benzyl azide

Conditions
Conditions Yield
In N,N,N,N,N,N-hexamethylphosphoric triamide; at 60 ℃; for 24h;
87%
C<sub>17</sub>H<sub>17</sub>N<sub>3</sub>O<sub>3</sub>
112157-95-6

C17H17N3O3

phenylacetic acid
103-82-2

phenylacetic acid

acetic acid
64-19-7,77671-22-8

acetic acid

benzyl azide
622-79-7

benzyl azide

Conditions
Conditions Yield
With ammonium hydroxide; other reagents and conditions;
75%
benzyl chloride
100-44-7

benzyl chloride

benzyl azide
622-79-7

benzyl azide

Conditions
Conditions Yield
With azide ion; highly branchedpolyacrylamide-APTMAI; In water; toluene; at 20 - 70 ℃; for 0.5h;
100%
With sodium azide; In N,N-dimethyl-formamide; acetonitrile; for 24h; Reflux;
99%
With sodium azide; In water; at 80 ℃; for 2h; Reagent/catalyst; Temperature; Time;
98%
With sodium azide; ammonium chloride; In water; at 70 ℃; for 48h;
97%
With sodium azide; In water; acetone; at 120 ℃; for 0.333333h; Microwave irradiation;
96%
With sodium azide; tetra(n-butyl)ammonium hydrogensulfate; In dichloromethane; water; at 20 ℃; for 25h; Inert atmosphere;
96%
With sodium azide; In chloroform; water; ethyl acetate; N,N-dimethyl-formamide;
96.4%
With sodium azide; In ethyl acetate;
96%
With sodium azide; In water; at 80 ℃; for 5h;
95.4%
With sodium azide; In ethanol; water; at 95 ℃; for 20h;
95%
With sodium azide; ammonium chloride; In water; at 70 ℃; for 48h;
94%
With anion exchange resin(N3- form); In methanol; acetonitrile; at 40 ℃; for 2.5h;
93%
With azide(1-);

-(CH2)3-+PBu3; In water; at 110 ℃; for 1h;

92%
With sodium azide; In ethanol; water; for 8h; Reflux;
92.1%
With sodium azide; In N,N-dimethyl-formamide; at 50 ℃; for 24h;
92%
With polymeric ammonium azide; In dichloromethane; at 20 ℃; for 2h;
91%
With sodium azide; In dimethyl sulfoxide; at 20 ℃; for 2h;
90%
With sodium azide; water; In ethanol; for 24h; Inert atmosphere; Reflux;
89%
With sodium azide; In water; at 90 ℃; for 0.25h; Green chemistry;
88%
With sodium azide; In N,N-dimethyl-formamide; at 90 ℃; for 5h;
88%
With sodium azide; In ethanol; water; at 20 ℃; Green chemistry;
87%
With sodium azide; In water; at 80 ℃; for 0.25h; Green chemistry;
85%
With sodium azide; In N,N-dimethyl-formamide; for 4h; Reflux;
85%
With sodium azide; Aliquat 336; at 20 ℃; for 16h;
84%
With sodium azide; In N,N-dimethyl-formamide; at 100 ℃; for 0.166667h; Microwave irradiation; Sealed vial;
84%
With sodium azide; In water; for 0.916667h; Reflux; Green chemistry;
84%
With sodium azide; 2Cl4Fe(1-)*C11H18N4(2+); In water; for 0.916667h; Reflux; Green chemistry;
84%
With sodium azide; In water; for 0.833333h; Reflux; Inert atmosphere;
83%
With sodium azide; In ethanol; water; at 95 ℃;
82%
With sodium azide; In N,N-dimethyl-formamide; at 75 ℃; Reflux;
80%
With sodium azide; In N,N-dimethyl-formamide; at 75 ℃; Reflux;
80%
With sodium azide; In dimethyl sulfoxide; at 20 ℃;
79%
With sodium azide; In water; at 90 ℃; for 0.25h;
78%
With sodium azide; In acetonitrile; for 2h; Heating;
75%
With sodium azide; In acetonitrile; at 80 ℃; for 20h;
75%
With sodium azide; In water; acetone; for 2h; Ambient temperature;
73%
With sodium azide; In dimethyl sulfoxide;
71.4%
With sodium azide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; In water; at 75 ℃; for 1.5h;
69%
With sodium azide; zinc(II) chloride; In pyridine; benzene; for 6h; Heating;
60%
With sodium azide; In N,N-dimethyl-formamide; at 85 - 90 ℃; for 5h;
60%
With sodium azide; ethanol;
With N,N,N',N'-tetramethylguanidinium azide;
With sodium azide; In methanol;
With sodium azide;
With sodium azide; In acetonitrile; at 20 ℃; for 5.5h;
With Merrifield resin supported tetra-alkyl ammonium azide; In dimethyl amine; at 25 ℃; for 72h;
With sodium azide; In N,N-dimethyl-formamide; at 80 ℃;
With sodium azide; In ethanol; for 10h; Heating;
With sodium azide; In ethanol; at 60 ℃;
With tributylhexadecylphosphonium azide; In benzene-d6; at 60 ℃; Kinetics;
With cesium azide; In dimethyl sulfoxide; at 40 ℃; Further Variations:; Solvents; Kinetics;
With sodium azide;
With sodium azide; 18-crown-6 ether; In acetonitrile; at 125 ℃; for 0.166667h; under 12929 Torr; Microwave irradiation;
With sodium azide; In acetonitrile; at 60 ℃; for 10h;
> 99 %Chromat.
With sodium azide; 1,3-bis[2,4,4,5,7,7,8,8,9,9,9-undecafluoro-2,5-bis(trifluoromethyl)-3,6-dioxanonyl]imidazolium trifluoromethanesulfonate; at 40 ℃; for 96h;
With sodium azide; In ammonia; at 25 ℃; Kinetics; liquid NH3;
With sodium azide; In 2,4-dichlorophenoxyacetic acid dimethylamine; at 100 ℃; for 0.166667h; Microwave irradiation;
With sodium azide; In tetrahydrofuran; water; Reflux;
With sodium azide; triethylamine; In water; tert-butyl alcohol; at 20 ℃; for 0.5h;
With sodium azide; In water; at 90 ℃; for 0.5h;
With sodium azide; N-ethyl-N,N-diisopropylamine; In dimethyl sulfoxide; at 25 ℃; for 4h;
With sodium azide; N-ethyl-N,N-diisopropylamine; In dimethyl sulfoxide; at 25 ℃; for 4h;
With sodium azide; In dimethyl sulfoxide;
With sodium azide; In N,N-dimethyl-formamide; at 20 ℃;
With sodium azide; potassium iodide; In water; acetone; Reflux;
With sodium azide; In N,N-dimethyl-formamide; at 70 ℃;
With sodium azide; sodium iodide; In ethanol; water; at 20 ℃; for 24h;
With sodium azide; In N,N-dimethyl-formamide; at 60 ℃; for 2h; Inert atmosphere;
With sodium azide; N-benzyl-N,N,N-triethylammonium chloride; triethylamine hydrochloride; at 50 - 55 ℃; Large scale;
With sodium azide; In water; dimethyl sulfoxide; at 40 ℃; for 1h;
With sodium azide; ammonium chloride; In water; at 70 ℃; for 48h;
1.15 g
With sodium azide; In ethanol; water; at 20 ℃; for 1h; Green chemistry;
With sodium azide; triethylamine; In water; tert-butyl alcohol; at 20 ℃; for 0.5h;
With sodium azide; triethylamine; In water; tert-butyl alcohol; at 20 ℃; for 1h;
With sodium azide; triethylamine; In water; tert-butyl alcohol; at 20 ℃; for 0.5h;
With sodium azide; In dimethyl sulfoxide; at 20 ℃;
benzyl chloride; With sodium azide; In water; at 20 ℃; for 0.0833333h;
at 80 ℃;
With sodium azide; In ethanol; water; at 85 ℃; for 48h;
With sodium azide; In acetone; Reflux;
With sodium azide; at 20 ℃;
With sodium azide; In dimethyl sulfoxide; at 20 ℃;
With sodium azide; sodium tosylate; In water; at 20 ℃; for 0.166667h; Reagent/catalyst;
93 %Chromat.
With sodium azide; In acetone; at 65 ℃; for 7h;
With sodium azide; In water; N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere;
With sodium azide; In methanol; at 20 ℃; Green chemistry;
With sodium azide; In water; at 100 ℃; Temperature; Solvent; Green chemistry;
With sodium azide; In water; N,N-dimethyl-formamide; at 50 ℃; for 5h; Inert atmosphere;
With sodium azide; In methanol; water; at 80 ℃; for 10h;
With sodium azide; In ethanol; water; Reflux;
With sodium azide; In ethanol; Reflux;
With sodium azide; In N,N-dimethyl-formamide; at 20 ℃; for 24h;
With sodium azide;
With sodium azide; In N,N-dimethyl-formamide; for 4h; Reflux;
With sodium azide; In N,N-dimethyl-formamide; acetonitrile;
benzylamine
100-46-9

benzylamine

benzyl azide
622-79-7

benzyl azide

Conditions
Conditions Yield
With copper(ll) sulfate pentahydrate; sodium hydrogencarbonate; perfluorobutanesulfonyl azide; In methanol; diethyl ether; water; at 20 ℃; for 6h;
91%
With hydrogenchloride; copper(ll) sulfate pentahydrate; 1H-imidazole-1-sulfonyl azide hydrochloride; potassium carbonate; In methanol; at 20 ℃; for 2.5h;
61%
Multistep reaction; (i) MeMgI, Et2O, (ii) TsN3, THF;
With triflic azide; sodium hydrogencarbonate; copper(II) sulfate; In methanol; dichloromethane; water; at 20 ℃; for 0.5h;
With sodium azide; trifluoromethylsulfonic anhydride; copper in charcoal; barium(II) hydroxide; In dichloromethane; at 20 ℃; for 3h;
With imidazole-1-sulfonyl azide hydrochloride; N-ethyl-N,N-diisopropylamine; In methanol; water; Combinatorial reaction / High throughput screening (HTS);
With triflic azide; sodium hydrogencarbonate; copper(II) sulfate; In methanol; dichloromethane; water; at 20 ℃; for 2h;
benzylamine; With hydrogenchloride; sodium nitrite; In water; at 0 - 5 ℃; for 0.05h;
With sodium azide; In water; for 0.0833333h;
With tert.-butylnitrite; trimethylsilylazide; In acetonitrile; at 0 - 20 ℃; for 2h; Inert atmosphere;
benzylamine; With hydrogenchloride; sodium nitrite;
With sodium azide; sodium acetate;
benzylamine; With hydrogenchloride; sodium nitrite; In water; at 0 - 5 ℃; for 0.05h;
With sodium azide; In water; for 0.0833333h;
With 3-azidosulfonyl-3H-imidazole-1-ium hydrogen sulfate; copper; N-ethyl-N,N-diisopropylamine; In methanol; dichloromethane; water; at 0 - 20 ℃; for 0.0833333h; Flow reactor;
benzylamine; With sulfuric acid; sodium nitrite; In 1,4-dioxane; water; at -15 ℃;
With sodium azide; In 1,4-dioxane; water; at -15 - 20 ℃;
benzylamine; With hydrogenchloride; In water; at 0 - 5 ℃; for 0.0833333h;
With sodium nitrite; In water; at 0 - 5 ℃; for 0.0833333h;
With sodium azide; In water; for 0.166667h;
benzylamine; With hydrogenchloride; sodium nitrite; In water; at 0 ℃; for 0.666667h;
With sodium azide; sodium acetate; In water; at 0 - 20 ℃; for 1h;
benzylamine; With sulfuric acid; In 1,4-dioxane; at -15 ℃; for 0.0833333h;
With sodium nitrite; In 1,4-dioxane; at -15 ℃; for 0.5h;
With sodium azide; In 1,4-dioxane; at -15 ℃;
With hydrogenchloride; sodium azide; In water; at 0 - 20 ℃; for 0.5h;
With sodium azide; In N,N-dimethyl-formamide; at 20 ℃;
With hydrogenchloride; sodium azide; sodium nitrite; at 20 ℃;
With hydrazine hydrate; sodium nitrite; at 20 ℃;
With tert.-butylnitrite; trimethylsilylazide; In ethyl acetate; at 0 - 20 ℃; for 0.0833333h; Sealed tube;
With imidazole-1-sulfonyl azide hydrochloride; copper(ll) sulfate pentahydrate; potassium carbonate; In methanol; at 20 ℃;
benzylamine; With hydrogenchloride; sodium nitrite; Inert atmosphere;
With sodium azide; Inert atmosphere;
benzylamine; With hydrogenchloride; sodium nitrite; In water; at 0 - 5 ℃;
With sodium azide; In water; for 2h;
trimethylsilylazide
4648-54-8

trimethylsilylazide

benzyl chloride
100-44-7

benzyl chloride

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

benzyl azide
622-79-7

benzyl azide

Conditions
Conditions Yield
In N,N,N,N,N,N-hexamethylphosphoric triamide; at 60 ℃; for 24h;
65%
benzyl mesylate
55791-06-5

benzyl mesylate

benzyl azide
622-79-7

benzyl azide

Conditions
Conditions Yield
With sodium azide; In DMF (N,N-dimethyl-formamide); for 12h;
100%
With sodium azide; In dimethyl sulfoxide; at 20 ℃; for 6h;
97%
With sodium azide; In dimethyl sulfoxide; at 20 ℃; for 15h;
85%
With sodium azide; In dimethyl sulfoxide; at 80 ℃;
65%
With sodium azide; In dimethyl sulfoxide; at 20 ℃; for 15h;
With sodium azide; In dimethyl sulfoxide; at 20 ℃;
With sodium azide; In N,N-dimethyl-formamide; at 25 ℃; for 12h;
With sodium azide; In N,N-dimethyl-formamide; at 25 ℃; for 1h;
With sodium azide; In dimethyl sulfoxide; at 20 ℃;
With sodium azide; In dimethyl sulfoxide; at 20 ℃; for 15h;

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  • Amadis Chemical Co., Ltd.
  • Business Type:Lab/Research institutions
  • Contact Tel:86-571-89925085
  • Emails:sales@amadischem.com
  • Main Products:29
  • Country:China (Mainland)
  • Shaanxi BLOOM TECH Co.,Ltd
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-29-86470566
  • Emails:sales@bloomtechz.com
  • Main Products:79
  • Country:China (Mainland)
  • Chemwill Asia Co., Ltd.
  • Business Type:Manufacturers
  • Contact Tel:021-51086038
  • Emails:sales@chemwill.com
  • Main Products:56
  • Country:China (Mainland)
  • Kono Chem Co.,Ltd
  • Business Type:Other
  • Contact Tel:86-29-86107037-8015
  • Emails:info@konochemical.com
  • Main Products:82
  • Country:China (Mainland)
  • Finetech Industry Limited
  • Business Type:Trading Company
  • Contact Tel:86-27-87465837
  • Emails:sales@finetechnology-ind.com
  • Main Products:29
  • Country:China (Mainland)
  • Antimex Chemical Limied
  • Business Type:Lab/Research institutions
  • Contact Tel:0086-21-50563169
  • Emails:anthony@antimex.com
  • Main Products:163
  • Country:China (Mainland)
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