Welcome to LookChem.com Sign In|Join Free

CAS

  • or

625-58-1

Post Buying Request

625-58-1 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

625-58-1 Usage

Description

Ethyl nitrate has formula C2H5NO3. It is used in organic synthesis and as an intermediate in the preparation of some drugs, dyes, and perfumes. Ethyl nitrate is found in the atmosphere, where it can react with other gases to form smog. Originally thought to be a pollutant, formed mainly by the combustion of fossil fuels, recent analysis of ocean water samples reveal that in places where cool water rises from the deep, the water is saturated with alkyl nitrates, likely formed by natural processes.

Chemical Properties

Different sources of media describe the Chemical Properties of 625-58-1 differently. You can refer to the following data:
1. Ethyl nitrate is capable of explosive decomposition when exposed to heat.
2. Colorless liquid; pleasant odor; sweet taste.Soluble in alcohol and ether; insoluble in water.

Uses

Organic synthesis, drugs, perfumes, dyes, rocket propellant.

Production Methods

The alkyl nitrates are produced from the corresponding alcohols by esterification with nitric acid in the presence of urea or urea nitrate.

Preparation

Ethyl nitrate has been prepared by bubbling gaseous nitryl fluoride through ethanol at ?10 °C . The reaction was subsequently studied in detail.

General Description

A clear colorless liquid with a pleasant odor. Flash point 50°F. Prolonged exposure to fire or heat may cause vigorous decomposition and rupturing of the container. Denser than water and insoluble in water. Vapors are heavier than air. Produces toxic oxides of nitrogen during combustion.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Organonitrates, such as Ethyl nitrate, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive.

Hazard

Flammable, dangerous, fire and explosion risk.

Health Hazard

Different sources of media describe the Health Hazard of 625-58-1 differently. You can refer to the following data:
1. Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
2. In humans ethyl nitrate can cause headache, narcosis and vomiting, but no cases of industrial intoxication have been reported .

Industrial uses

Ethyl nitrate is used in the synthesis of certain drugs, perfumes and dyes. It has also found some use as a rocket fuel.

Safety Profile

A poison by intraperitoneal route. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxibzing materials. A moderate explosion hazard when exposed to heat (explodes @ 185'F). To fight fire, use foam, CO2, dry chemical, water to blanket fire. Incompatible with Lewis acids. When heated to decomposition it emits toxic fumes of NOx. See also NITRATES and ESTERS.

Metabolism

There is no information concerning the in vivo metabolism of ethyl nitrate, but it seems likely that one route for biotransformation is hydrolysis to yield an alcohol and nitrate. Such a pathway is common to other alkyl nitrates such as nitroglycerin and amyl nitrate.

Check Digit Verification of cas no

The CAS Registry Mumber 625-58-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,2 and 5 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 625-58:
(5*6)+(4*2)+(3*5)+(2*5)+(1*8)=71
71 % 10 = 1
So 625-58-1 is a valid CAS Registry Number.
InChI:InChI=1/C2H5NO3/c1-2-6-3(4)5/h2H2,1H3

625-58-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name ethyl nitrate

1.2 Other means of identification

Product number -
Other names nitrooxy-ethane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:625-58-1 SDS

625-58-1Synthetic route

phosphonic acid diethyl ester
762-04-9

phosphonic acid diethyl ester

A

ethyl nitrate
625-58-1

ethyl nitrate

B

C2H6O3P(1-)*Ca(2+)*NO3(1-)

C2H6O3P(1-)*Ca(2+)*NO3(1-)

Conditions
ConditionsYield
With calcium(II) nitrate at 115℃; for 1h; Product distribution; oter time;A n/a
B 91%
With calcium(II) nitrate at 115℃;A n/a
B 91%
ethanol
64-17-5

ethanol

ethyl nitrate
625-58-1

ethyl nitrate

Conditions
ConditionsYield
With potassium fluoride; nitrylfluoride In acetonitrile at -30 - -20℃;89.4%
With nitronium tetrafluoborate
With nitric acid
1,1,1-Trimethylolethane dinitrate
84051-79-6

1,1,1-Trimethylolethane dinitrate

A

3-hydroxymethyl-3-methyloxethane
3143-02-0

3-hydroxymethyl-3-methyloxethane

B

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

C

ethyl nitrate
625-58-1

ethyl nitrate

D

1,1,1-Trimethylolethane mononitrate
84051-80-9

1,1,1-Trimethylolethane mononitrate

E

3-methyl-3-(nitroxymethyl)oxetane
84051-81-0

3-methyl-3-(nitroxymethyl)oxetane

F

NO2- (5.2percent), NO3-

NO2- (5.2percent), NO3-

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water at 55℃; for 3.10833h; Product distribution; Rate constant; var. NaOH conc.;A 13%
B 0.7%
C n/a
D 24%
E 66%
F n/a
methanol
67-56-1

methanol

2-ethoxy-1-phenylazo-naphthalene; dinitrate

2-ethoxy-1-phenylazo-naphthalene; dinitrate

A

ethyl nitrate
625-58-1

ethyl nitrate

B

Sudan I
842-07-9

Sudan I

ethyl nitrite
109-95-5

ethyl nitrite

ethyl hydroperoxide
3031-74-1

ethyl hydroperoxide

ethyl nitrate
625-58-1

ethyl nitrate

ethanol
64-17-5

ethanol

benzoyl nitrate
6786-32-9

benzoyl nitrate

A

ethyl nitrate
625-58-1

ethyl nitrate

B

benzoic acid
65-85-0

benzoic acid

ethyl hydroperoxide
3031-74-1

ethyl hydroperoxide

ethyl nitrate
625-58-1

ethyl nitrate

Conditions
ConditionsYield
With cis-nitrous acid
ethyl iodide
75-03-6

ethyl iodide

ethyl nitrate
625-58-1

ethyl nitrate

Conditions
ConditionsYield
With silver nitrate In ethanol at 20℃; Product distribution; Mechanism; var. salt conc.;
With silver nitrate
ethyl hydroperoxide
3031-74-1

ethyl hydroperoxide

isopentyl nitrite
110-46-3

isopentyl nitrite

A

ethyl nitrate
625-58-1

ethyl nitrate

B

i-Amyl alcohol
123-51-3

i-Amyl alcohol

ethyl hydroperoxide
3031-74-1

ethyl hydroperoxide

isopentyl nitrite
110-46-3

isopentyl nitrite

A

ethyl nitrate
625-58-1

ethyl nitrate

B

pentan-1-ol
71-41-0

pentan-1-ol

ethyl-nitro-amine; ammonium salt
69153-14-6

ethyl-nitro-amine; ammonium salt

ethyl nitrate
625-58-1

ethyl nitrate

Conditions
ConditionsYield
With nitrylfluoride In acetonitrile
ethoxy radical
2154-50-9

ethoxy radical

ethyl nitrate
625-58-1

ethyl nitrate

Conditions
ConditionsYield
With Nitrogen dioxide at 21.9℃; Rate constant; Kinetics; different pressure; different diluent gases;
trimethylolethane trinitrate
3032-55-1

trimethylolethane trinitrate

A

ethyl nitrate
625-58-1

ethyl nitrate

B

1,1,1-Trimethylolethane mononitrate
84051-80-9

1,1,1-Trimethylolethane mononitrate

C

1,1,1-Trimethylolethane dinitrate
84051-79-6

1,1,1-Trimethylolethane dinitrate

D

3-methyl-3-(nitroxymethyl)oxetane
84051-81-0

3-methyl-3-(nitroxymethyl)oxetane

Conditions
ConditionsYield
With sodium hydroxide In ethanol Heating;A n/a
B 15.7 % Chromat.
C 2.5 % Chromat.
D 42 % Chromat.
ethane
74-84-0

ethane

A

Nitroethane
79-24-3

Nitroethane

B

ethyl nitrite
109-95-5

ethyl nitrite

C

ethyl nitrate
625-58-1

ethyl nitrate

Conditions
ConditionsYield
With dihydrogen peroxide; boric acid; Nitrogen dioxide under 300.02 Torr; Yield given. Yields of byproduct given;
With dihydrogen peroxide; Nitrogen dioxide at 24.9℃; under 300.02 Torr; Kinetics; Product distribution; Mechanism; boric-acid-coated surface; various temp.;
With dihydrogen peroxide; Nitrogen dioxide at 24.9℃; under 300.02 Torr; Rate constant; Product distribution; Mechanism; boric-acid-coated surface; various pressure and carrier-gas composition;A 50 % Chromat.
B 3 % Chromat.
C 45 % Chromat.
With dihydrogen peroxide; boric acid; Nitrogen dioxide under 300.02 Torr; Product distribution; Mechanism;
ethane
74-84-0

ethane

ethyl nitrate
625-58-1

ethyl nitrate

Conditions
ConditionsYield
With nitrate radical Thermodynamic data; Mechanism; calculated (BEBO and equibonding method) activation energies for hydrogen atom transfer reaction, anodic nitrooxylation;
With methyl nitrite; ultra-zero air; nitrogen(II) oxide at 25.9℃; for 0.333333h; Product distribution; Rate constant; Irradiation; other alkylperoxy radical generator (Cl2);
ethane
74-84-0

ethane

A

Nitroethane
79-24-3

Nitroethane

B

ethyl nitrate
625-58-1

ethyl nitrate

C

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
With dihydrogen peroxide; oxygen; Nitrogen dioxide at 24.9℃; under 300.02 Torr; Rate constant; Product distribution; Mechanism; boric-acid-coated surface; various O2 concn.;
triethyloxonium hexaflourophosphate
17950-40-2

triethyloxonium hexaflourophosphate

ethyl nitrate
625-58-1

ethyl nitrate

Conditions
ConditionsYield
With silver nitrate In ethanol at 0℃; Product distribution; Mechanism; var. of reagent, its conc.;
isovaleraldehyde
590-86-3

isovaleraldehyde

A

ethyl nitrate
625-58-1

ethyl nitrate

B

isobutyl nitrate
543-29-3

isobutyl nitrate

C

peroxyacetyl nitrate
2278-22-0

peroxyacetyl nitrate

D

3-methylbutyryl peroxynitrate
154292-38-3

3-methylbutyryl peroxynitrate

Conditions
ConditionsYield
With air; nitrogen(II) oxide Nitration; sunlight; Title compound not separated from byproducts;
silver nitrate

silver nitrate

ethyl iodide
75-03-6

ethyl iodide

ethyl nitrate
625-58-1

ethyl nitrate

nitric acid
7697-37-2

nitric acid

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

A

formic acid
64-18-6

formic acid

B

ethyl nitrate
625-58-1

ethyl nitrate

ethanol
64-17-5

ethanol

silver nitrate

silver nitrate

ethyl iodide
75-03-6

ethyl iodide

A

diethyl ether
60-29-7

diethyl ether

B

ethyl nitrate
625-58-1

ethyl nitrate

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

nitrous acid anhydride

nitrous acid anhydride

A

ethyl nitrate
625-58-1

ethyl nitrate

B

formic acid ethyl ester
109-94-4

formic acid ethyl ester

chloroform
67-66-3

chloroform

dinitrogen tetraoxide
10544-72-6

dinitrogen tetraoxide

ethyl isocyanate
109-90-0

ethyl isocyanate

A

ethyl nitrate
625-58-1

ethyl nitrate

B

ethene
74-85-1

ethene

C

methylammonium carbonate
15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

D

nitrogen

nitrogen

n-butane
106-97-8

n-butane

A

ethyl nitrate
625-58-1

ethyl nitrate

B

butyl nitrate
928-45-0

butyl nitrate

C

2-butyl nitrate
924-52-7

2-butyl nitrate

D

peroxyacetyl nitrate
2278-22-0

peroxyacetyl nitrate

E

peroxy-n-butyryl nitrate

peroxy-n-butyryl nitrate

F

butanone
78-93-3

butanone

G

C2H5C(O)OONO2

C2H5C(O)OONO2

Conditions
ConditionsYield
With air; Nitrogen dioxide at 25℃; for 6h; Product distribution; Mechanism; Kinetics; Irradiation; also addition of NO;A 1.3 % Chromat.
B 1.3 % Chromat.
C 16 % Chromat.
D 23 % Chromat.
E 1.3 % Chromat.
F 37 % Chromat.
G n/a
diethyl ether
60-29-7

diethyl ether

nitric acid
7697-37-2

nitric acid

ethyl nitrate
625-58-1

ethyl nitrate

Conditions
ConditionsYield
at -15 - -5℃;
ethyl hydroperoxide
3031-74-1

ethyl hydroperoxide

cis-nitrous acid
7782-77-6

cis-nitrous acid

ethyl nitrate
625-58-1

ethyl nitrate

ethyl hydroperoxide
3031-74-1

ethyl hydroperoxide

alkyl nitrites

alkyl nitrites

ethyl nitrate
625-58-1

ethyl nitrate

ethanol
64-17-5

ethanol

benzoyl nitrate

benzoyl nitrate

ethyl nitrate
625-58-1

ethyl nitrate

diethyl ether
60-29-7

diethyl ether

N2O5

N2O5

ethyl nitrate
625-58-1

ethyl nitrate

ethyl nitrate
625-58-1

ethyl nitrate

tin(ll) chloride

tin(ll) chloride

A

hydroxylamine hydrochloride
5470-11-1

hydroxylamine hydrochloride

B

ammonia
7664-41-7

ammonia

C

tin(IV) chloride
7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
With hydrogenchloride In hydrogenchloride byproducts: C2H5OH, H2O; in concd. HCl soln.; evapn. of the alcohol,diluting with water,pptg. of the Sn with H2S,evapn. and crystn. from alcohol;A 90%
B <1
C n/a
rubidium hydroxide

rubidium hydroxide

ethyl nitrate
625-58-1

ethyl nitrate

hydroxylamine hydrochloride
5470-11-1

hydroxylamine hydrochloride

sodium
7440-23-5

sodium

rubidium hyponitrate

rubidium hyponitrate

Conditions
ConditionsYield
In ethanol byproducts: NaCl; stepwise addn. of EtONa (prepd. from Na in EtOH) to NH2OH*HCl (0°C, soln. just alcaline towards phenolphtalein, stirring), filtration offof NaCl, addn. of 1 equiv. RbOH, addn. of 0.5 equiv. EtONO2 (pptn.), st anding for 2 days at 3-5°C; purity 92%; elem. anal.; can be repptd. from aq. soln. by EtOH or THF ordioxan;85%
ethyl nitrate
625-58-1

ethyl nitrate

hydroxylamine hydrochloride
5470-11-1

hydroxylamine hydrochloride

sodium
7440-23-5

sodium

sodium trioxodinitrate

sodium trioxodinitrate

Conditions
ConditionsYield
In ethanol byproducts: NaCl; stepwise addn. of EtONa (prepd. from Na in EtOH) to NH2OH*HCl (0°C, soln. just alcaline towards phenolphtalein, stirring), filtration offof NaCl, slow addn. of 0.5 equiv. EtONO2 (pptn.), standing for 4 days a t 3-5°C; filtration, washing (EtOH, ether), drying (vac., 1 h); contg. NaNO2 and NaNO3 as impurities;76%
In ethanol byproducts: NaCl; stepwise addn. of EtONa (prepd. from Na in EtOH) to NH2OH*HCl (0°C, soln. just alcaline towards phenolphtalein, stirring), filtration offof NaCl, slow addn. of 0.5 equiv. EtONO2 (pptn.), standing for 3 days a t 3-5°C; filtration, washing (EtOH, ether), drying (vac., 1 h); contg. NaNO2 and NaNO3 as impurities;75%
In ethanol byproducts: NaCl; stepwise addn. of EtONa (prepd. from Na in EtOH) to NH2OH*HCl (0°C, soln. just alcaline towards phenolphtalein, stirring), filtration offof NaCl, slow addn. of 0.5 equiv. EtONO2 (pptn.), standing for 2 days a t 3-5°C; filtration, washing (EtOH, ether), drying (vac., 1 h); contg. NaNO2 and NaNO3 as impurities;68%
ethyl nitrate
625-58-1

ethyl nitrate

hydroxylamine hydrochloride
5470-11-1

hydroxylamine hydrochloride

sodium
7440-23-5

sodium

sodium hydroxide
1310-73-2

sodium hydroxide

sodium trioxodinitrate

sodium trioxodinitrate

Conditions
ConditionsYield
In ethanol byproducts: NaCl; stepwise addn. of EtONa (prepd. from Na in EtOH) to NH2OH*HCl (0°C, soln. just alcaline towards phenolphtalein, stirring), filtration offof NaCl, addn. of 1 equiv. NaOH, then dropwise addn. of 0.5 equiv. EtON O2 (0°C); standing (3-5°C, 3 days), filtration, washing (EtOH, ether), drying (vac., 120°C, 1 h), repeated dissoln. in H2O and pptn. on EtOHaddn. (0°C); purity 85%; can be repptd. also with dioxan or THF;57%
ethyl nitrate
625-58-1

ethyl nitrate

quadricyclo[2.2.1.0.0]heptane
278-06-8

quadricyclo[2.2.1.0.0]heptane

Sulfuric acid ethyl ester (1S,2S,4R,7R)-7-nitro-bicyclo[2.2.1]hept-5-en-2-yl ester

Sulfuric acid ethyl ester (1S,2S,4R,7R)-7-nitro-bicyclo[2.2.1]hept-5-en-2-yl ester

Conditions
ConditionsYield
With sulfur trioxide In dichloromethane at -55℃; for 0.5h;51%
ethyl nitrate
625-58-1

ethyl nitrate

hydroxylamine hydrochloride
5470-11-1

hydroxylamine hydrochloride

sodium
7440-23-5

sodium

lithium hydroxide
1310-65-2

lithium hydroxide

lithium nitrohydroxylaminate

lithium nitrohydroxylaminate

Conditions
ConditionsYield
In ethanol byproducts: NaCl; stepwise addn. of EtONa (prepd. from Na in EtOH) to NH2OH*HCl (0°C, soln. just alcaline towards phenolphtalein, stirring), filtration offof NaCl, addn. of 1 equiv. LiOH, then addn. of 0.5 equiv. EtONO2 (pptn. ), standing at 0°C; repeated dissoln. in H2O and pptn. on EtOH addn.; elem. anal.; can be repptd. also with dioxan or THF;44.6%
ethyl nitrate
625-58-1

ethyl nitrate

3,4,5,6-Tetrafluoro-tricyclo[6.2.2.02,7]dodeca-2(7),3,5,9,11-pentaene
5162-34-5

3,4,5,6-Tetrafluoro-tricyclo[6.2.2.02,7]dodeca-2(7),3,5,9,11-pentaene

Sulfuric acid ethyl ester (5S,8S,9R,10S)-1,2,3,4-tetrafluoro-10-nitro-8,9-dihydro-5H-5,8-methano-benzocyclohepten-9-yl ester

Sulfuric acid ethyl ester (5S,8S,9R,10S)-1,2,3,4-tetrafluoro-10-nitro-8,9-dihydro-5H-5,8-methano-benzocyclohepten-9-yl ester

exo-8-nitro-3,4-tetrafluorobenzotricyclo[3.2.1.02,7]oct-3-en-endo-6-yl ethyl sulfate

exo-8-nitro-3,4-tetrafluorobenzotricyclo[3.2.1.02,7]oct-3-en-endo-6-yl ethyl sulfate

Conditions
ConditionsYield
With sulfur trioxide In dichloromethane at -55℃; for 0.5h;A 30%
B 26%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

ethyl nitrate
625-58-1

ethyl nitrate

dicarbonyldinitrosyliron

dicarbonyldinitrosyliron

Conditions
ConditionsYield
In benzene under N2, stirred overnight; filtered, evapd.; identified by IR-spectroscopy;24%
ethyl nitrate
625-58-1

ethyl nitrate

cyclopentene
142-29-0

cyclopentene

A

4-nitrocyclopentene
6925-11-7

4-nitrocyclopentene

B

2-nitrocyclopentene
7053-55-6

2-nitrocyclopentene

Sulfuric acid ethyl ester (1R,3R)-3-nitro-cyclopentyl ester

Sulfuric acid ethyl ester (1R,3R)-3-nitro-cyclopentyl ester

Sulfuric acid ethyl ester (1R,3S)-3-nitro-cyclopentyl ester

Sulfuric acid ethyl ester (1R,3S)-3-nitro-cyclopentyl ester

Conditions
ConditionsYield
With sulfur trioxide In dichloromethane at -55℃; for 0.5h; Yields of byproduct given;A n/a
B n/a
C 14%
D 15%
ferrocenylbenzene

ferrocenylbenzene

ethyl nitrate
625-58-1

ethyl nitrate

para-nitrophenylferrocene

para-nitrophenylferrocene

Conditions
ConditionsYield
With aluminium trichloride In carbon disulfide13%
With AlCl3 In carbon disulfide13%
ethyl nitrate
625-58-1

ethyl nitrate

C22H19ClF3NOS

C22H19ClF3NOS

phenyl isocyanate
103-71-9

phenyl isocyanate

C24H22ClF3N2O2S

C24H22ClF3N2O2S

Conditions
ConditionsYield
With triethylamine In benzene at 20℃; for 2h;10%
2,4-dimethyl-1H-pyrrole
625-82-1

2,4-dimethyl-1H-pyrrole

ethyl nitrate
625-58-1

ethyl nitrate

2,4-dimethyl-3-nitropyrrole
33458-34-3

2,4-dimethyl-3-nitropyrrole

Conditions
ConditionsYield
With diethyl ether; sodium
2-thiazolylamine
96-50-4

2-thiazolylamine

ethyl nitrate
625-58-1

ethyl nitrate

2-amino-5-nitro-1,3-thiazole
121-66-4

2-amino-5-nitro-1,3-thiazole

Conditions
ConditionsYield
With sulfuric acid
phenyl benzyl ketone
451-40-1

phenyl benzyl ketone

ethyl nitrate
625-58-1

ethyl nitrate

sodium ethanolate
141-52-6

sodium ethanolate

A

1-nitro-1-phenylmethane
622-42-4

1-nitro-1-phenylmethane

B

benzoic acid ethyl ester
93-89-0

benzoic acid ethyl ester

indole
120-72-9

indole

diethyl ether
60-29-7

diethyl ether

ethyl nitrate
625-58-1

ethyl nitrate

sodium ethanolate
141-52-6

sodium ethanolate

3-nitro-1H-indole
4770-03-0

3-nitro-1H-indole

indole
120-72-9

indole

ethyl nitrate
625-58-1

ethyl nitrate

3-nitro-1H-indole
4770-03-0

3-nitro-1H-indole

Conditions
ConditionsYield
With diethyl ether; sodium ethanolate
4-methylthiazol-2-ylamine
1603-91-4

4-methylthiazol-2-ylamine

ethyl nitrate
625-58-1

ethyl nitrate

2-amino-4-methyl-5-nitrothiazole
56682-07-6

2-amino-4-methyl-5-nitrothiazole

Conditions
ConditionsYield
With sulfuric acid
2-methyl-1H-indole
95-20-5

2-methyl-1H-indole

ethyl nitrate
625-58-1

ethyl nitrate

2-methyl-3-aci-nitro-3H-indole

2-methyl-3-aci-nitro-3H-indole

Conditions
ConditionsYield
With diethyl ether; ethanol; sodium
3-methylbenzyl cyanide
2947-60-6

3-methylbenzyl cyanide

ethyl nitrate
625-58-1

ethyl nitrate

nitro-m-tolyl-acetonitrile

nitro-m-tolyl-acetonitrile

Conditions
ConditionsYield
With diethyl ether; sodium ethanolate durch Ansaeuern in waessr. Loesung;
(4-methylphenyl)acetonitrile
2947-61-7

(4-methylphenyl)acetonitrile

ethyl nitrate
625-58-1

ethyl nitrate

nitro-p-tolyl-acetonitrile

nitro-p-tolyl-acetonitrile

Conditions
ConditionsYield
With diethyl ether; potassium ethoxide
naphthalen-1-ylacetonitrile
132-75-2

naphthalen-1-ylacetonitrile

ethyl nitrate
625-58-1

ethyl nitrate

[1]naphthyl-nitro-acetonitrile; sodium compound

[1]naphthyl-nitro-acetonitrile; sodium compound

Conditions
ConditionsYield
With sodium ethanolate
biphenyl-4-acetaldehyde
92-91-1

biphenyl-4-acetaldehyde

ethyl nitrate
625-58-1

ethyl nitrate

4-acetyl-4'-nitrobiphenyl
135-69-3

4-acetyl-4'-nitrobiphenyl

Conditions
ConditionsYield
With sulfuric acid
2-amino-benzthiazole
136-95-8

2-amino-benzthiazole

ethyl nitrate
625-58-1

ethyl nitrate

2-amino-6-nitrobenzothiazole
6285-57-0

2-amino-6-nitrobenzothiazole

Conditions
ConditionsYield
With sulfuric acid
2-acetamidothiazole
2719-23-5

2-acetamidothiazole

ethyl nitrate
625-58-1

ethyl nitrate

Nitazole
140-40-9

Nitazole

Conditions
ConditionsYield
With sulfuric acid; potassium nitrate
2(3H)-Benzothiazolone
934-34-9

2(3H)-Benzothiazolone

ethyl nitrate
625-58-1

ethyl nitrate

6-nitro-2(3H)-benzothiazolone
28620-12-4

6-nitro-2(3H)-benzothiazolone

Conditions
ConditionsYield
With sulfuric acid
With nitric acid
methyl magnesium iodide
917-64-6

methyl magnesium iodide

diethyl ether
60-29-7

diethyl ether

ethyl nitrate
625-58-1

ethyl nitrate

A

N,N-dimethylhydroxylamine
5725-96-2

N,N-dimethylhydroxylamine

B

dimethyl amine
124-40-3

dimethyl amine

Conditions
ConditionsYield
reagiert analog mit Aethylmagnesiumbromid;

625-58-1Relevant articles and documents

Evidence Against Ion-pair Formation in the Reactions of Ethyl Halides with Silver Salts

Kevill, Dennis N.,Fujimoto, Edward K.

, p. 1149 - 1150 (1983)

Contrary to a previous report, the product ratio from the reaction of ethyl iodide with silver nitrate in ethanol varies with the salt concentration; the product ratios obtained are very similar to those for the corresponding SN2 reactions of triethyloxonium hexafluorophosphate.

Kinetics and Products of the Reactions of Ethyl and n-Propyl Nitrates with OH Radicals

Morin, Julien,Bedjanian, Yuri,Romanias, Manolis N.

, p. 822 - 829 (2016/11/02)

The kinetics of the reactions of ethyl (1) and n-propyl (2) nitrates with OH radicals has been studied using a low-pressure flow tube reactor combined with a quadrupole mass spectrometer. The rate constants of the title reactions were determined under pseudo–first-order conditions from kinetics of OH consumption in high excess of nitrates. The overall rate constants, k1 = 1.14 × 10?13 (T/298)2.45 exp(193/T) and k2 = 3.00 × 10?13 (T/298)2.50 exp(205/T) cm3 molecule?1 s?1 (with conservative 15% uncertainty), were determined at a total pressure of 1 Torr of helium over the temperature range (248–500) and (263–500) K, respectively. The yields of the carbonyl compounds, acetaldehyde and propanal, resulting from the abstraction by OH of an α-hydrogen atom in ethyl and n-propyl nitrates, followed by α-substituted alkyl radical decomposition, were determined at T = 300 K to be 0.77 ± 0.12 and 0.22 ± 0.04, respectively.

FTIR spectroscopic study of the OH-induced oxidation of two linear acetates: Ethyl and n-propyl acetates

Picquet-Varrault,Doussin,Durand-Jolibois,Carlier

, p. 2595 - 2606 (2007/10/03)

OH-induced oxidation mechanisms of ethyl and n-propyl acetates have been investigated at room temperature (298 ± 5 K) and atmospheric pressure by photolysing CH3ONO/acetate/NO mixtures with FTIR spectroscopy as analytical device. The main oxidation products and their yields were as follows: from ethyl acetate, acetic acid (0.75 ± 0.13), acetoxyacetaldehyde (0.15 ± 0.05), acetic anhydride (0.02 ± 0.01), formic acetic anhydride (0.02 ± 0.01) and peroxyacetyl nitrate (PAN); from n-propyl acetate, acetoxyacetaldehyde (0.22 ± 0.06), formic acetic anhydride (0.28 ± 0.03), acetic acid (0.15 ± 0.02), acetaldehyde (0.35 ± 0.10), peroxypropionyl nitrate (PPN) and probably acetoxypropionaldehyde (0.30 ± 0.10). From these data, oxidation schemes of these two acetates were elucidated. This study reveals in particular the specifc reactivity of acetates by confirming the novel α-ester rearrangement proposed recently by Tuazon et al. (J. Phys. Chem. A, 1998, 102, 2316) and then by showing that oxygenated alkoxyl radicals may not follow the same rules of reactivity as other alkoxyl radicals. This last observation shows the necessity for further experiments to understand the influence of the oxygenated function on alkoxyl reactivity.

Nitration of alcohols by nitryl fluoride

Fedorov,Eremenko

, p. 1022 - 1023 (2007/10/03)

A general method for the preparation of nitrates by treatment of alcohols with nitryl fluoride (FNO2) in MeCN in the presence of KF has been developed.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 625-58-1