627-19-0Relevant articles and documents
Unexpected conformational behavior of gaseous 1-pentyne
Traetteberg,Bakken,Hopf
, p. 213 - 220 (1999)
The molecular structure and conformations of 1-pentyne have been studied experimentally by the gas electron diffraction method. A conformational mixture of 68.6% gauche and 31.4% anti, with standard deviation equal to 4.5%, was observed. Results from ab initio MP2/6-31G* optimization calculations are in excellent agreement with those observed.
TiO2 Assisted Photocatalytic Decomposition of 2-Chloronaphthalene on Iron Nanoparticles in Aqueous Systems: Synergistic Effect and Intermediate Products
Jipeng Qi,Wang, Chen,Sun, Jing,Li, Shuping
, p. 1620 - 1626 (2019/08/15)
Abstract: 2-Chloronaphthalene (2-CN), used as an intermediate for organic synthesis, is a new type of persistent organic pollutant. In this work, the decomposition efficiency and decomposition mechanism of 2-CN by zero-valent iron (ZVI) assisted TiO2
An Additive-Free, Base-Catalyzed Protodesilylation of Organosilanes
Yao, Wubing,Li, Rongrong,Jiang, Huajiang,Han, Deman
, p. 2250 - 2255 (2018/02/23)
We report an additive-free, base-catalyzed C-, N-, O-, and S-Si bond cleavage of various organosilanes in mild conditions. The novel catalyst system exhibits high efficiency and good functional group compatibility, providing the corresponding products in good to excellent yields with low catalyst loadings. Overall, this transition-metal-free process may offer a convenient and general alternative to current employing excess bases, strong acids, or metal-catalyzed systems for the protodesilylation of organosilanes.