627-54-3Relevant articles and documents
Reactions of 1,1-Dichloroethene with elemental chalcogens in the system hydrazine hydrate–alkali
Levanova,Nikonova,Grabel’nykh,Russavskaya,Albanov,Rozentsveig,Korchevin
, p. 1070 - 1071 (2016/09/04)
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Reaction of 1,1-dichloroethane with tellurium in the system hydrazine hydrate-potassium hydroxide
Levanova,Grabel'nykh,Kolesnikov,Klyba,Zhanchipova,Albanov,Russavskaya,Korchevin
experimental part, p. 988 - 992 (2011/02/26)
The reaction of 1,1-dichloroethane with tellurium in the system hydrazine hydrate-potassium hydroxide gave ethyltellanyl derivatives as a result of replacement of one chlorine atom in the substrate by tellurium, and of the other, by hydrogen. Probable mechanisms of reduction of the C-Cl bond and mass spectra of the products were considered. The mass spectra of ditelluroacetals revealed unusual rearrangement of the molecular ion, leading to the formation of Te-Te and new C-C bond.
Process for the preparation of group IVA and group VIA compounds
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Page 12, (2008/06/13)
Methods of preparing Group IVA and Group VIA organometallic compounds, particularly Group IVA organometallic compounds, are provided. Such manufacturing methods employ an amine and/or phosphine catalyst in a transalkylation step and may be performed in a batch, semi-continuous or continuous manner.