62762-20-3

Basic information

• Product Name: Silane, trimethyl[1-(phenylthio)ethenyl]-
• Synonyms: Silane,trimethyl[1-(phenylthio)ethenyl];1-phenylthio-1-trimethylsilylethene;1-phenylthio-1-(trimethylsilyl)ethylene;1-Phenylthio-1-(trimethylsilyl)ethylen;1-(trimethylsilyl-1-phenylthio)ethylene
• CAS NO: 62762-20-3
• Molecular Formula: C11H16SSi
• Molecular Weight: 208.4
• Mol File: 62762-20-3.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[1-(phenylthio)ethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[1-(phenylthio)ethenyl]-(62762-20-3)
• EPA Substance Registry System: Silane, trimethyl[1-(phenylthio)ethenyl]-(62762-20-3)

Safety Data

• Hazardous Substances Data: 62762-20-3(Hazardous Substances Data)

Usage

Physical properties

colorless liquid; bp 130–134 °C/15 mmHg

Preparation

1-Phenylthio-1-trimethylsilylethylene is widely used by lithiation of phenyl vinyl sulfide with lithium diisopropylamide, followed by silylation, or the base-induced elimination of 2-chloro-1-trimethylsilyl-1- phenylthioethane, or the lithiation of ethyl phenyl sulfoxide with LDA followed by silylation, or the Pd-catalyzed coupling reactions of trimethylstannyl phenyl sulfide with 1-bromo-1-trimethylsilylethylene.

Upstream product

• 130083-71-5 (1-Methoxy-1-phenylsulfanyl-ethyl)-trimethyl-silane 
• 108-98-5 thiophenol 
• 1066-54-2 trimethylsilylacetylene 
• 75-77-4 chloro-trimethyl-silane 
• 1822-73-7 phenylthioethylene 
• 5535-49-9 2-Chloroethyl phenyl sulfide 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 
• 100-68-5 methyl-phenyl-thioether 
• 754-05-2 ethenyltrimethylsilane 
• 931-59-9 benzenesulfenyl chloride 
• 37891-39-7 trimethylsilane 
• 2973-86-6 lithium thiophenoxide 
• 72610-21-0 2-chloro-1-(trimethylsilyl)ethyl phenyl sulfide 
• 17988-58-8 12-<(phenylthio)ethyl>trimethylsilane 

Downstream Products

• 85969-80-8 5-phenylthio-5-trimethylsilyldecane 
• 68143-73-7 2-phenylthio-1-naphthol 
• 107014-81-3 6-phenylthioundec-5-ene 
• 85969-82-0 2,2-dimethyl-4-phenylthio-4-trimethylsilyloctane 
• 76200-39-0 1-phenylthio-1-trimethylsilylhexane 
• 85969-76-2 3-phenylthio-3-trimethylsilylheptane 
• 107014-78-8 3-phenylthio-oct-3-ene 
• 20841-46-7 2-(phenylthio)-3,4-dihydronaphthalen-1(2H)-one 
• 82494-85-7 (6aR*,3aS*)-3-phenylthio-4,5,6,6a-tetrahydro-3aH-pentalen-1-one 
• 95841-51-3 9-methyl-4-(phenylthio)cis-bicyclo<4.3.0>non-3-en-2-one 
• 76200-34-5 1-(phenylthio)-1-(trimethylsilyl)propane 
• 128881-78-7 5-methoxy-2-phenylthio-1-tetralone 
• 82494-86-8 4-(phenylthio)-7,7-dimethyl-cis-bicyclo<3.3.0>oct-3-en-2-one 
• 64806-53-7 1-phenylsulfinyl-1-(trimethylsilyl)ethylene 

Relevant articles and documents

ALDEHYDES FROM ALKYLLITHIUMS WITH 2-CARBON HOMOLOGATION

1-Phenylthio-trimethylsilylalkanes, which are readily converted to aldehydes, are prepared by the addition of alkyllithiums to phenylthioethene, trimethylsilylethene and 1-phenylthio-1-trimethylsilylethene.

Regio- and stereospecific cleavage of stannylepoxides with lithium phenylsulfide

Unsubstituted and α or β C-substituted epoxystannanes react with lithium phenylsulfide to give regio- and stereodefined α-phenylthio-β-hydroxystannanes resulting from α-opening with inversion of configuration. On the other hand, α- or β-trans-silyl epoxys

Electro-initiated oxygenation of alkenylsilanes in the presence of thiophenol

Electrolysis of alkenylsilanes in the presence of thiophenol with bubbling of molecular oxygen gave the corresponding α-phenylthio carbonyl compounds with the consumption of a catalytic amount of electricity. An electro-initiated radical chain mechanism i