6308-98-1

Basic information

• Product Name: N,N-BIS(2-PHENYLETHYL)AMINE HYDROCHLORIDE
• Synonyms: 2-Phenyl-N-(2-phenylethyl)ethanamine; Benzeneethanamine, N- (2-phenylethyl)-; benzeneethanamine, N-(2-phenylethyl)-; Bis(2-phenylethyl)amine; Diphenethylamine; Diphenethyl-amine
• CAS NO: 6308-98-1
• Molecular Formula: C₁₆H₁₉N
• Molecular Weight: 225.33
• Mol File: 6308-98-1.mol
• Article Data: 52

Chemical Properties

• Melting Point: 29°C
• Boiling Point: 356.85°C (rough estimate)
• Flash Point: 169.5°C
• Appearance: /
• Density: 1.0256 (rough estimate)
• Vapor Pressure: 3.61E-05mmHg at 25°C
• Refractive Index: 1.5550
• PKA: 9.97±0.19(Predicted)
• CAS DataBase Reference: N,N-BIS(2-PHENYLETHYL)AMINE HYDROCHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-BIS(2-PHENYLETHYL)AMINE HYDROCHLORIDE(6308-98-1)
• EPA Substance Registry System: N,N-BIS(2-PHENYLETHYL)AMINE HYDROCHLORIDE(6308-98-1)

Safety Data

• Hazardous Substances Data: 6308-98-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H19N/c1-3-7-15(8-4-1)11-13-17-14-12-16-9-5-2-6-10-16/h1-10,17H,11-14H2

Upstream product

• 3164-46-3 1-(2-phenylethyl)aziridine 
• 71-43-2 benzene 
• 102-96-5 (2-nitroethenyl)benzene 
• 93311-16-1 N-phenethyl-2-phenylethanethioamide 
• 122-78-1 phenylacetaldehyde 
• 64-04-0 phenethylamine 
• 103-63-9 1-phenyl-2-bromoethane 
• 100-51-6 benzyl alcohol 
• 140-29-4 phenylacetonitrile 
• 85608-04-4 Diphenethyl-carbamic acid methyl ester 
• 85608-05-5 Diphenethyl-carbamic acid ethyl ester 
• 64-17-5 ethanol 
• 141-78-6 ethyl acetate 
• 7647-01-0 hydrogenchloride 

Downstream Products

• 115419-49-3 N-phenyl-N-(2-phenylethyl)aniline 
• 861786-91-6 N,N-diphenethyl-benzamide 
• 109652-40-6 allyl-diphenethyl-amine 
• 25413-78-9 nitroso-diphenethyl-amine 
• 100-41-4 ethylbenzene 
• 7664-41-7 ammonia 
• 932005-76-0 phenethyl-(1,1,3,3-tetramethyl-butyl)-amine 
• 1276664-87-9 3,4-dihydro-3-methylene-4-(2-phenylethyl)amino-2H-1-benzopyran 
• 3647-71-0 N-benzyl-2-phenylethylamine 
• 76842-47-2 N-benzyl-N-phenylethyl-2-phenylethanamine 

Relevant articles and documents

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A potassium magnesiate complex: Synthesis, structure and catalytic intermolecular hydroamination of styrenes

A new heterobimetallic potassium magnesiate complex KMg[N(SiMe3)2]2Bn (Bn = PhCH2-) was synthesized by simply mixing magnesium amide and potassium benzyl in toluene. The TMEDA-ligated potassium magnesiate comple

Rhodium-Catalyzed Anti-Markovnikov Hydroamination of Aliphatic and Aromatic Terminal Alkynes with Aliphatic Primary Amines

Anti-Markovnikov hydroamination of both aliphatic and aromatic terminal alkynes with primary amines was achieved using an 8-quinolinolato rhodium catalyst to form aldimines and enamines in high yields. This catalytic system realized high functional group tolerance including hydroxy, bromo, cyano, and thioester groups.

Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides

Direct hydrogenation of thioesters with H2 provides a facile and waste-free method to access alcohols and thiols. However, no report of this reaction is documented, possibly because of the incompatibility of the generated thiol with typical hydrogenation catalysts. Here, we report an efficient and selective hydrogenation of thioesters. The reaction is catalyzed by an acridine-based ruthenium complex without additives. Various thioesters were fully hydrogenated to the corresponding alcohols and thiols with excellent tolerance for amide, ester, and carboxylic acid groups. Thiocarbamates and thioamides also undergo hydrogenation under similar conditions, substantially extending the application of hydrogenation of organosulfur compounds.