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6320-02-1

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6320-02-1 Usage

Chemical Properties

clear yellow liquid

General Description

2-Bromothiophenol (2-Bromobenzenethiol) reacts with 4-(4-bromo-3-nitro-phenyl)morpholine to form nitro-sulphide.

Check Digit Verification of cas no

The CAS Registry Mumber 6320-02-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,3,2 and 0 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 6320-02:
(6*6)+(5*3)+(4*2)+(3*0)+(2*0)+(1*2)=61
61 % 10 = 1
So 6320-02-1 is a valid CAS Registry Number.
InChI:InChI=1/C6H5BrS/c7-5-3-1-2-4-6(5)8/h1-4,8H/p-1

6320-02-1 Well-known Company Product Price

  • Brand
  • (Code)Product description
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  • Alfa Aesar

  • (B25537)  2-Bromothiophenol, 97%   

  • 6320-02-1

  • 5g

  • 498.0CNY

  • Detail
  • Alfa Aesar

  • (B25537)  2-Bromothiophenol, 97%   

  • 6320-02-1

  • 25g

  • 1894.0CNY

  • Detail
  • Aldrich

  • (242659)  2-Bromothiophenol  97%

  • 6320-02-1

  • 242659-10G

  • 1,490.58CNY

  • Detail
  • Aldrich

  • (242659)  2-Bromothiophenol  97%

  • 6320-02-1

  • 242659-50G

  • 5,800.86CNY

  • Detail

6320-02-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-BROMOTHIOPHENOL

1.2 Other means of identification

Product number -
Other names 2-bromobenzenethiol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6320-02-1 SDS

6320-02-1Relevant articles and documents

SINGLE-STEP SYNTHESIS METHOD OF ARYL THIOL AND APPLICATION THEREOF

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Paragraph 0032; 0033; 0063; 0067; 0069; 0070, (2017/09/02)

The present invention relates to a single-step synthesis method of aryl thiol, and more specifically, to a method of synthesizing aryl thiol in a single-step by making aryl halide react with alkane dithiol in the presence of a transition metal catalyst. According to the present invention, a single-step synthesis method using the transition metal catalyst, the synthesis method which is capable of synthesizing aryl thiol from aryl halide at a high yield, can be provided. Various aryl halides may be applied to the synthesis method. Further, the synthesis method has advantages that an easily usable reagent may be used, operations are simple, and reactions can be performed under mild conditions. In addition, the synthesized aryl thiol may be used in the synthesis of advanced molecules such as diaryl sulfides and benzothiophenes.COPYRIGHT KIPO 2017

Oxidative cleavage of S-Arylmercaptoacetic acids by pyridinium chlorochromate: Kinetic and correlation analysis

Kabilan,Girija,Rajagopal

, p. 683 - 688 (2007/10/03)

Kinetics of oxidation of 24 S-Arylmercaptoacetic acids (SAMA) by pyridinium chlorochromate (PCC) have been studied in acid medium. The product of oxidation is the corresponding thiophenol. The rate data of meta- and para-substituted acids have been correlated well with σI, σ°R values and the meta-compounds correlate well with F,R values. The reaction constants are negative and of smaller magnitudes. Further, the ortho-substituted acids show a good correlation with triparametric equation involving Taft's σI and σ°R and charton's steric parameter v. There is no considerable steric contribution to the total orthosubstituent effect. Based on these observations, the mechanism involving the formation of protonated arylsulfinylacetic acid intermediate, followed by an intramolecular rearrangement leading to the product thiophenol has been proposed.

Peroxide Salts as Reagents in Oxidative Halogenation of Aromatic Compounds

Rudakova, N. I.,Erykalov, Yu. G.,Zharikova, S. M.,Dmitrieva, E. V.,Mataradze, M. S.

, p. 271 - 272 (2007/10/03)

Chloromesitylene, chloro-p-xylene, and 1-bromonaphthalene are formed in 78, 79, and 86percent yield, respectively, under the action of the halogenating system hydrogen peroxide-hydrohalic acid-AcOH.The following aryl halides are also formed in high yields in this halogenating system: 2-bromothiophene (89 - 92percent) upon bromonation of thiophene; chlorobenzene (77 - 79percent) and iodobenzene (79 - 81percent) upon chlorination and iodination of benzene.

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