63593-23-7

Basic information

• Product Name: 2,5-Pyrrolidinedione, 1-(phenylmethoxy)-
• CAS NO: 63593-23-7
• Molecular Formula: C11H11NO3
• Molecular Weight: 205.213
• Mol File: 63593-23-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2,5-Pyrrolidinedione, 1-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Pyrrolidinedione, 1-(phenylmethoxy)-(63593-23-7)
• EPA Substance Registry System: 2,5-Pyrrolidinedione, 1-(phenylmethoxy)-(63593-23-7)

Safety Data

• Hazardous Substances Data: 63593-23-7(Hazardous Substances Data)

Upstream product

• 108-30-5 succinic acid anhydride 
• 622-33-3 N-benzyloxyamine 
• 6066-82-6 1-hydroxy-pyrrolidine-2,5-dione 
• 100-44-7 benzyl chloride 
• 108-88-3 toluene 

Downstream Products

• 6066-82-6 1-hydroxy-pyrrolidine-2,5-dione 
• 2687-43-6 O-benzylhydoxylamine hydrochloride 

Relevant articles and documents

Ultrasound accelerated synthesis of: O-alkylated hydroximides under solvent- A nd metal-free conditions

A novel, sustainable, environmentally friendly, high substrate scope, efficient, solvent-free and metal catalyst-free method for the cross-dehydrogenative coupling (CDC) reaction between N-hydroxyphthalimide (NHPI) and benzyl/ether compounds is described. This coupling reaction proceeds through ultrasound acceleration. Compared to conventional heating conditions, the use of ultrasound techniques not only improves the reaction efficiency and enhances the reaction rate but also minimizes the side reactions.

Photoinduced electron-transfer-promoted redox fragmentation of N-alkoxyphthalimides

A new photoinduced electron-transfer-promoted redox fragmentation of N-alkoxyphthalimides has been developed. Mechanistic experiments have established that this reaction proceeds through a unique concerted intramolecular fragmentation process. This distinctive mechanism imparts many synthetic advantages, which are highlighted in the redox fragmentation of various heterocyclic substrates.

Development of n new class of rate-accelerating additives for nitroxide- mediated 'living' free radical polymerization

Acylating agents have been identified as a new class of rate accelerating additives for nitroxide-mediated 'living' free radical polymerization. It is found that addition of 1 weight percent of acetic anhydride results in a significant decrease in the reaction time, 48 to 4 hours. This decrease in reaction time leads to greater control over the polymerization process with low polydispersity materials being obtained up to 150 000 a.m.u. A possible explanation for this effect is acylation of the alkoxyamine nitrogen leading to an increase in the lability of the C-ON bond.