63707-12-0

Basic information

• Product Name: Benzene, 1-methyl-4-[(phenylethynyl)thio]-
• CAS NO: 63707-12-0
• Molecular Formula: C15H12S
• Molecular Weight: 224.326
• Mol File: 63707-12-0.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-[(phenylethynyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-[(phenylethynyl)thio]-(63707-12-0)
• EPA Substance Registry System: Benzene, 1-methyl-4-[(phenylethynyl)thio]-(63707-12-0)

Safety Data

• Hazardous Substances Data: 63707-12-0(Hazardous Substances Data)

Upstream product

• 1068439-06-4 4-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]toluene 
• 536-74-3 phenylacetylene 
• 106-45-6 para-thiocresol 
• 33440-88-9 silver phenylacetylide 
• 5720-05-8 4-methylphenylboronic acid 
• 2170-06-1 1-Phenyl-2-(trimethylsilyl)acetylene 
• 2943-42-2 di(4-methyl)phenylthiosulfonate 
• 7436-90-0 2,2-dibromostyrene 
• 103-19-5 di(p-tolyl) disulfide 
• 39549-10-5 1-[(4-methylphenyl)sulfanyl]pyrrolidine-2,5-dione 
• 932-87-6 1-Bromo-2-phenylacetylene 
• 62158-92-3 (2,2,2-trifluoroethyl) (4-methylphenyl) sulfide 
• 591-51-5 phenyllithium 
• 1483-82-5 phenylethynyl chloride 

Downstream Products

• 24182-84-1 (Z)-styryl(p-tolyl)sulfane 
• 24182-83-0 (E)-styryl(p-tolyl)sulfane 
• 92357-52-3 (E)-phenyl(2-phenyl-2-tosylvinyl)sulfane 
• 1034014-67-9 (E)-2-phenyl-1-(p-tolylsulfanyl)ethenyl diphenyldithiophosphinate 
• 115843-51-1 1,2,3,3a,4,6a-hexahydro-5-<(4-methylphenyl)sulphonyl>-6-phenyl-1,2,4-methenopentalene 
• 319913-63-8 phenylacetylenic phenyl sulfoxyde 
• 92070-90-1 5-methyl-2-(phenylethynyl)thiophene 
• 13343-79-8 (E)-1,4-Diphenylbut-1-en-3-yne 
• 28995-88-2 1-methyl-4-((phenylethynyl)sulfonyl)benzene 

Relevant articles and documents

Transition Metal-Free C-H Thiolation via Sulfonium Salts Using β-Sulfinylesters as the Sulfur Source

We disclose a direct C(sp)-, C(sp2)-, and C(sp3)-H thiolation reaction using β-sulfinylesters as the versatile sulfur source. The key step of this protocol is chemoselective C-S bond cleavage of the sulfonium salts that are formed in situ from the corresponding alkenes, alkynes, and 1,3-dicarboxyl compounds with β-sulfinylesters. The successful capture of the acrylate byproduct supports a retro-Michael reaction mechanism.

Radical-mediated sulfonyl alkynylation, allylation, and cyanation of propellane

Bicyclo[1.1.1]pentane (BCP) is widely applied as the bioisostere for aryl, internal alkynes, andtert-butyl groups in medicinal chemistry. We herein disclose an efficient and practical preparation of sulfonyl alkynyl/allyl/cyano-substituted BCP derivatives

Convenient and Efficient Diastereoselective Preparation of Functionalized Z-Alkenyl Sulfides

We have developed an efficient and convenient regio- and stereoselective reduction of the alkynyl sulfides with pinacolborane in the presence of copper(I) chloride to produce (Z)-alkenyl sulfides in good and very good yields. The functionalized alkynyl sulfides are readily available based on the reaction of lithium acetylides with thiotosylates under mild conditions.