64187-83-3Relevant articles and documents
Silica-supported dendrimer-palladium complex-catalyzed selective hydrogenation of dienes to monoolefins
Zweni, Pumza P.,Alper, Howard
, p. 725 - 731 (2007/10/03)
The selective hydrogenation of cyclic and acyclic dienes to monoolefins occurs under very mild conditions, in the presence of silica-supported PAMAM-Pd complexes. The activity and selectivity of this reaction is sensitive to the dendrimer structure. These dendritic complexes display excellent recycle properties, retaining activity for up to eight recycles.
A Note on Stereochemical Observation of the Deprotonation of Ethyl-2-Alkenoates
Krebs, Ernst-Peter
, p. 1023 - 1025 (2007/10/02)
Deprotonation of ethyl (E)-2-alkenoates 1, 3 and 4 yields after protonation the double bond migrated (3 Z)-isomers 5, 7 and 9 as major products.In contrast, deprotonation and reprotonation of ethyl (Z)-2-pentanoate (2) gives the (3 E)-isomer 6 exclusively