64418-88-8

Basic information

• Product Name: Benzaldehyde, 5-(acetyloxy)-2-hydroxy-
• CAS NO: 64418-88-8
• Molecular Formula: C9H8O4
• Molecular Weight: 180.16
• Mol File: 64418-88-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 5-(acetyloxy)-2-hydroxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 5-(acetyloxy)-2-hydroxy-(64418-88-8)
• EPA Substance Registry System: Benzaldehyde, 5-(acetyloxy)-2-hydroxy-(64418-88-8)

Safety Data

• Hazardous Substances Data: 64418-88-8(Hazardous Substances Data)

Upstream product

• 3524-69-4 2-formyl-1,4-phenylene diacetate 
• 1194-98-5 2,5-Dihydroxybenzaldehyde 
• 108-24-7 acetic anhydride 
• 108-05-4 vinyl acetate 
• 3233-32-7 hydroquinone monoacetate 
• 100-97-0 hexamethylenetetramine 
• 123-31-9 hydroquinone 
• 23001-29-8 6-hydroxy spiropyran 
• 287398-52-1 C₂₁H₂₁NO₃ 

Downstream Products

• 1415680-12-4 2-(2,3,4,6-tetra-О-acetyl-β-D-glucopyranozyloxy)-5-acetyloxybenzyl alcohol 
• 18265-35-5 2-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyloxy)-5-acetoxybenzyl(3-methoxy-4-acetoxy)benzoate 
• 1415680-15-7 2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)-5-acetyloxybenzyl-(4-acetoxy) cinnamate 
• 16955-55-8 2-benzoyloxymethyl-4-hydroxyphenyl β-D-glucopyranoside 
• 1415680-10-2 2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)-5-acetyloxybenzaldehyde 
• 1194-98-5 2,5-Dihydroxybenzaldehyde 
• 6468-46-8 6-acetoxy-3-phenylcoumarin 

Relevant articles and documents

Total Synthesis of Divergolides E and H

This manuscript describes the first total syntheses of divergolides E and H. The route employs a telescoped hetero-Diels–Alder and oxidative carbon–hydrogen bond cleavage as an entry into the central bridged bicyclic acetal unit. Additional key steps of the highly convergent route include a desymmetrizing epoxidation, a chelation-controlled alkenylzinc addition, an amide formation between a hindered aniline and an acylating agent that is prone to ketene formation, and a challenging macrolactonization.

Fischer's base as a protecting group: Protection and deprotection of 2- hydroxybenzaldehydes

The hydroxyl and aldehyde groups of 2-hydroxybenzaldehydes were protected by the reaction with Fischer's base and deprotected by the ozonolysis in methanol at -78°C to give the corresponding 2- hydroxybenzaldehydes in good to high yields. (C) 2000 Elsevier Science Ltd.