Welcome to LookChem.com Sign In|Join Free

CAS

  • or

64443-05-6

Post Buying Request

64443-05-6 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

64443-05-6 Usage

Reaction

Useful catalyst for the Ullmann synthesis. Catalytic asymmetric [2,3]-Sigmatropic rearrangement of sulfur ylides. Precatalyst for enantioselective N–H insertion reactions with diazoesters and anilines.

Uses

Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively. It can also be used as a copper precursor:For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.

Check Digit Verification of cas no

The CAS Registry Mumber 64443-05-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,4,4,4 and 3 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 64443-05:
(7*6)+(6*4)+(5*4)+(4*4)+(3*3)+(2*0)+(1*5)=116
116 % 10 = 6
So 64443-05-6 is a valid CAS Registry Number.
InChI:InChI=1/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1

64443-05-6 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • TCI America

  • (T2665)  Tetrakis(acetonitrile)copper(I) Hexafluorophosphate  >97.0%(T)

  • 64443-05-6

  • 5g

  • 590.00CNY

  • Detail
  • Aldrich

  • (346276)  Tetrakis(acetonitrile)copper(I)hexafluorophosphate  97%

  • 64443-05-6

  • 346276-5G

  • 648.18CNY

  • Detail
  • Aldrich

  • (346276)  Tetrakis(acetonitrile)copper(I)hexafluorophosphate  97%

  • 64443-05-6

  • 346276-25G

  • 2,806.83CNY

  • Detail

64443-05-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Tetrakis(acetonitrile)copper(I) hexafluorophosphate

1.2 Other means of identification

Product number -
Other names acetonitrile,copper(1+),hexafluorophosphate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:64443-05-6 SDS

64443-05-6Relevant articles and documents

Efficient one-pot green synthesis of tetrakis(acetonitrile)copper(i) complex in aqueous media

Kritchenkov, Ilya S.,Shakirova, Julia R.,Tunik, Sergey P.

, p. 15531 - 15535 (2019)

New simple, fast, effective and environmentally friendly one-pot method for the synthesis of extensively used tetrakis(acetonitrile)copper(i) complexes with BF4-, PF6- and ClO4- counterions is invented and optimized. The approach suggested allows using water as solvent and minimizes amounts of toxic organic reagents in the synthetic protocol.

Intermittent molecular shuttle as a binary switch

Jiang, Lasheng,Okano, Junji,Orita, Akihiro,Otera, Junzo

, p. 2121 - 2124 (2004)

Action stations: Treatment of rotaxanes containing a 2,2′-bipyridine moiety between two bipyridinium stations with Cu1 ions gives rise to a new type of shuttling process. The switch between static and dynamic states is achieved through complexation of the Cu1 center to the 2,2′-bipyridine unit followed by decomplexation (see picture).

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 64443-05-6