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64788-85-8

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64788-85-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 64788-85-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,4,7,8 and 8 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 64788-85:
(7*6)+(6*4)+(5*7)+(4*8)+(3*8)+(2*8)+(1*5)=178
178 % 10 = 8
So 64788-85-8 is a valid CAS Registry Number.

64788-85-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (E)-1-[dimethyl(phenyl)silyl]-2-phenylethylene

1.2 Other means of identification

Product number -
Other names (E)-1-phenyl-2-(dimethylphenylsilyl)ethylene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:64788-85-8 SDS

64788-85-8Relevant articles and documents

Silsesquioxyl rhodium(i) complexes - Synthesis, structure and catalytic activity

Marciniec, Bogdan,Kownacki, Ireneusz,Franczyk, Adrian,Kubicki, MacIej

, p. 5073 - 5077 (2011)

The first bi- and mononuclear rhodium(i) complexes [{Rh(μ-OSi 8O12(i-Bu)7)(cod)}2] (5), [Rh(cod)(PCy3)(OSi8O12(i-Bu)7)] (6) with a hindered hepta(iso-butyl)silsesquiox

Caged Iridium Catalyst for Hydrosilylation of Alkynes with High Site Selectivity

Gu, Defa,Li, Qiaosheng,Liu, Yuzhou,Yu, Dongdong

, (2022/02/02)

The proximity and orientation of the reacting groups can be different in organic cages from in free solution, thus affecting the selectivity of the reaction. Herein, we reported a synthetic strategy to encapsulate iridium nanoparticles (Ir-NP@COP1-T) within organic cages in the homogeneous solution. Ir-NP@COP1-T showed good selectivity in the hydrosilylation reaction of alkynes. Our work provides a new perspective to the catalysis field by using soluble microporous cages as support for inorganic nano particles.

Manganese-Catalyzed Dehydrogenative Silylation of Alkenes following Two Parallel Inner-Sphere Pathways

Weber, Stefan,Glavic, Manuel,St?ger, Berthold,Pittenauer, Ernst,Podewitz, Maren,Veiros, Luis F.,Kirchner, Karl

supporting information, p. 17825 - 17832 (2021/11/04)

We report on an additive-free Mn(I)-catalyzed dehydrogenative silylation of terminal alkenes. The most active precatalyst is the bench-stable alkyl bisphosphine Mn(I) complex fac-[Mn(dippe)(CO)3(CH2CH2CH3)]. The catalytic process is initiated by migratory insertion of a CO ligand into the Mn-alkyl bond to yield an acyl intermediate which undergoes rapid Si-H bond cleavage of the silane HSiR3 forming the active 16e- Mn(I) silyl catalyst [Mn(dippe)(CO)2(SiR3)] together with liberated butanal. A broad variety of aromatic and aliphatic alkenes was efficiently and selectively converted into E-vinylsilanes and allylsilanes, respectively, at room temperature. Mechanistic insights are provided based on experimental data and DFT calculations revealing that two parallel reaction pathways are operative: an acceptorless reaction pathway involving dihydrogen release and a pathway requiring an alkene as sacrificial hydrogen acceptor.

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