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65253-04-5

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65253-04-5 Usage

Uses

(-)-8-Phenylmenthol is used to prepare piperidine-based analogs of cocaine as monoamine reuptake inhibitors. It is also used to prepare quinuclidinyl (fluoroalkyl)benzilate as muscarinic receptor antagonist.

Check Digit Verification of cas no

The CAS Registry Mumber 65253-04-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,5,2,5 and 3 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 65253-04:
(7*6)+(6*5)+(5*2)+(4*5)+(3*3)+(2*0)+(1*4)=115
115 % 10 = 5
So 65253-04-5 is a valid CAS Registry Number.
InChI:InChI=1/C16H24O/c1-12-9-10-14(15(17)11-12)16(2,3)13-7-5-4-6-8-13/h4-8,12,14-15,17H,9-11H2,1-3H3/t12-,14-,15-/m1/s1

65253-04-5 Well-known Company Product Price

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  • TCI America

  • (P2327)  (-)-8-Phenylmenthol  >98.0%(GC)

  • 65253-04-5

  • 200mg

  • 690.00CNY

  • Detail
  • Aldrich

  • (329487)  (−)-8-Phenylmenthol  98%

  • 65253-04-5

  • 329487-250MG

  • 952.38CNY

  • Detail
  • Aldrich

  • (329487)  (−)-8-Phenylmenthol  98%

  • 65253-04-5

  • 329487-1G

  • 3,184.74CNY

  • Detail

65253-04-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name (-)-8-Phenylmenthol

1.2 Other means of identification

Product number -
Other names (1R,2S,5R)-5-methyl-2-(2-phenylpropan-2-yl)cyclohexan-1-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:65253-04-5 SDS

65253-04-5Relevant articles and documents

Diastereoselective sulfa-Michael reactions controlled by a biomass-derived chiral auxiliary

Klepp, Julian,Podversnik, Harald,Puschnig, Johannes,Wallace, Andrew,Greatrex, Ben W.

supporting information, p. 3894 - 3903 (2019/06/18)

A family of chiral auxiliaries derived from the lignocellulosic biomass pyrolysis product levoglucosenone (LGO) has been screened in the sulfa-Michael reaction. When promoted by inorganic bases with potassium counterions, the auxiliary with geminal benzyl substituents showed diastereoselectivity up to 90:10 for a broad range of α,β-unsaturated esters.

Method for Highly Enantioselective Ligation of Two Chiral C(sp3) Stereocenters

Bhimireddy, Eswar,Corey

supporting information, p. 11044 - 11047 (2017/08/22)

A method is described for the joining of two α-lithiated C(sp3) stereocenters efficiently and with retention of configuration. The key step involves the effective removal of two electrons from a chiral organocuprate R2CuLi, by i-propyl 2,4-dinitrobenzoate to form a Cu(III) complex that undergoes at -90 °C accelerated reductive elimination enantioselectively and exclusively without the formation of free radicals.

Synthesis of the Privileged 8-Arylmenthol Class by Radical Arylation of Isopulegol

Crossley, Steven W. M.,Martinez, Ruben M.,Guevara-Zuluaga, Sebastián,Shenvi, Ryan A.

, p. 2620 - 2623 (2016/06/15)

Hydrogen atom transfer (HAT) circumvents a disfavored Friedel-Crafts reaction in the derivatization of the inexpensive monoterpene isopulegol. A variety of readily prepared aryl and heteroaryl sulfonates undergo a formal hydroarylation to form 8-arylmenthols, privileged scaffolds for asymmetric synthesis, as typified by 8-phenylmenthol. High stereoselectivity is observed in related systems. This use of HAT significantly extends the chiral pool from the inexpensive monoterpene isopulegol.

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