66128-99-2

Basic information

• Product Name: 1-methyl-3-(2-methylallyloxy)benzene
• CAS NO: 66128-99-2
• Molecular Weight: 162.232
• Mol File: 66128-99-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-methyl-3-(2-methylallyloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-3-(2-methylallyloxy)benzene(66128-99-2)
• EPA Substance Registry System: 1-methyl-3-(2-methylallyloxy)benzene(66128-99-2)

Safety Data

• Hazardous Substances Data: 66128-99-2(Hazardous Substances Data)

Upstream product

• 1458-98-6 2-methyl-3-bromo-1-propene 
• 108-39-4 3-methyl-phenol 
• 563-47-3 3-Chloro-2-methylpropene 

Downstream Products

• 63991-96-8 2-methyl-3-m-tolyloxy-propane-1,2-diol 
• 19956-97-9 2,2,6-trimethyl-2,3-dihydro-benzofuran 
• 859822-17-6 3-Hydroxy-1-methyl-4-methallyl-benzol 

Relevant articles and documents

Palladium-Catalyzed Tandem Oxidative Arylation/Olefination of Aromatic Tethered Alkenes/Alkynes

We describe herein a palladium-catalyzed tandem oxidative arylation/olefination reaction of aromatic tethered alkenes/alkynes for the synthesis of dihydrobenzofurans and 2 H-chromene derivatives. This reaction features a 1,2-difunctionalization of C?C π-bond with two C?H bonds using O2as terminal oxidant at room temperature. The products obtained are valuable synthons and important scaffolds in biological agents and natural products.