66169-65-1

Basic information

• Product Name: Carbamic acid, (benzoyloxy)(trimethylsilyl)-, ethyl ester
• CAS NO: 66169-65-1
• Molecular Formula: C13H19NO4Si
• Molecular Weight: 281.384
• Mol File: 66169-65-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbamic acid, (benzoyloxy)(trimethylsilyl)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (benzoyloxy)(trimethylsilyl)-, ethyl ester(66169-65-1)
• EPA Substance Registry System: Carbamic acid, (benzoyloxy)(trimethylsilyl)-, ethyl ester(66169-65-1)

Safety Data

• Hazardous Substances Data: 66169-65-1(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 64596-18-5 O-Benzoyl-N-carbethoxyhydroxylamine 

Downstream Products

• 1825-62-3 ethyl trimethylsilyl ether 
• 2078-12-8 trimethylsilyl benzoate 
• 75732-26-2 Ethyl N-<silyl>carbamate 

Relevant articles and documents

Investigation of Thermally Induced α-Deoxysilylation of Organosilylated Hydroxylamine Derivatives as a General Method for Nitrene Production

A variety of organosilylated hydroxylamine derivatives have been synthesized and studied as possible nitrene generators by thermally induced α-deoxysilylation: GN(OR')SiR3 GN + R'OSiR3, where G = EtO2C, ArCO, ArSO2, Me, H, and Ph2PO.The methods used to assess nitrene formation include trapping product characterization, substitutent variation, kinetic activation parameter measurements, Hammett studies, and solvent effects.While the latter two types of precursors were only briefly investigated because of their marked resistance to fragmentation, the combined data for the remaining compounds are consistent with the intermediacy of a nitrene.The existence of alternative deoxysilylation pathways is discussed in some cases, and for comparison with the nitrogen systems reported herein, kinetic activation parameters for α-deoxysilylation about carbon and silicon have been determined.