66605-19-4

Basic information

• Product Name: methyl 2,3-di-O-p-tolylsulfonyl-α-D-glucopyranoside
• Synonyms: methyl 2,3-di-O-p-tolylsulfonyl-α-D-glucopyranoside
• CAS NO: 66605-19-4
• Molecular Weight: 502.563
• Mol File: 66605-19-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 2,3-di-O-p-tolylsulfonyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-di-O-p-tolylsulfonyl-α-D-glucopyranoside(66605-19-4)
• EPA Substance Registry System: methyl 2,3-di-O-p-tolylsulfonyl-α-D-glucopyranoside(66605-19-4)

Safety Data

• Hazardous Substances Data: 66605-19-4(Hazardous Substances Data)

Upstream product

• 65556-00-5 methyl 4,6-di-O-benzylidene-2,3-di-O-tosyl-α-D-glucopyranoside 
• 6884-01-1 methyl 4,6-O-benzylidene-2,3-di-O-p-toluenesulphonyl-α-D-glucopyranoside 

Downstream Products

• 908576-44-3 methyl-[O⁴-acetyl-O²,O³-bis-(toluene-4-sulfonyl)-O⁶-trityl-α-D-glucopyranoside] 
• 96038-68-5 methyl-[O⁴,O⁶-dimethyl-O²,O³-bis-(toluene-4-sulfonyl)-α-D-glucopyranoside] 
• 122147-75-5 methyl O⁴,O⁶-phenylboranediyl-O²,O³-bis-(toluene-4-sulfonyl)-α-D-glucopyranoside 
• 146195-50-8 methyl 2,3-anhydro-4,6-di-O-p-bromobenzyl-α-D-allopyranoside 
• 131566-60-4 C₂₂H₂₇IO₉S₂ 
• 146195-48-4 methyl 4,6-di-O-p-bromobenzyl-2,3-di-O-p-tolylsulfonyl-α-D-glucopyranoside 

Relevant articles and documents

Cleavage of 4,6- O -benzylidene acetal using sodium hydrogen sulfate monohydrate

The use of protecting groups is an important protocol in carbohydrate synthesis. Among protecting groups, benzylidene acetals are generally more stable than other acetals; therefore, strong conditions are often required for deprotection. We report the deprotection of 4,6-O-benzylidene derivatives using sodium hydrogen sulfate monohydrate under mild conditions. Georg Thieme Verlag Stuttgart New York.

Tetrafluoroboric acid, an efficient catalyst in carbohydrate protection and deprotection reactions

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