66894-04-0Relevant articles and documents
A convenient halogenation of α,β-unsaturated carbonyl compounds with OXONE and hydrohalic acid (HBr,HCl)
Kim, Kyoung-Mahn,Park, In-Hwan
, p. 2641 - 2644 (2007/10/03)
Mixtures of OXONE and hydrobromic acid or hydrochloric acid afford solutions of bromine or chlorine, respectively, α-Bromo- or α-chloro-α,β-unsaturated carbonyl compounds were prepared by addition of hydrobromic acid or hydrochloric acid to the mixture of
Selective regeneration of carbonyl compounds from oximes with N-bromosuccinimide under neutral and mild conditions
Bandgar, Babasaheb P.,Kale, Ramesh R.,Kunde, Lalita B.
, p. 1057 - 1060 (2007/10/03)
N-Bromosuccinimide has been found to be an efficient and selective reagent for the mild oxidative cleavage of oximes to yield their corresponding carbonyl compounds in good to excellent yields.
α-Keto Dianion Precursors via Conjugate Additions to Cyclic α-Bromo Enones
Kowalski, Conrad J.,Weber, Ann E.,Fields, Kevin W.
, p. 5088 - 5093 (2007/10/02)
Successful conjugate to 2-bromocyclohexenone and 2-bromocyclopentenone have been achieved with a variety of lithium homocuprates, mixed cyanocuprates, and lithium tri-sec-butylborohydride as well.In all cases the resulting α-bromo enolate anions could be
