6705-50-6

Basic information

• Product Name: 7-oxabicyclo[2.2.1]hept-2-ene
• Synonyms: 7-oxabicyclo[2.2.1]hept-2-ene
• CAS NO: 6705-50-6
• Molecular Formula: C₆H₈O
• Molecular Weight: 96.13
• Mol File: 6705-50-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 127.8°C at 760 mmHg
• Flash Point: 19.2°C
• Appearance: /
• Density: 1.073g/cm³
• Vapor Pressure: 13.3mmHg at 25°C
• Refractive Index: 1.513
• CAS DataBase Reference: 7-oxabicyclo[2.2.1]hept-2-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 7-oxabicyclo[2.2.1]hept-2-ene(6705-50-6)
• EPA Substance Registry System: 7-oxabicyclo[2.2.1]hept-2-ene(6705-50-6)

Safety Data

• Hazardous Substances Data: 6705-50-6(Hazardous Substances Data)

Usage

Uses

7-Oxanorbornene can be used as reactant/reagent in preparation of cyclometalated arylpyridine, arylquinoline and arylphenanthridine iridium and platinum complexes as phosphorescent emitters for organic electroluminescent devices.

InChI:InChI=1/C6H8O/c1-2-6-4-3-5(1)7-6/h1-2,5-6H,3-4H2

Upstream product

• 110-00-9 furan 
• 74-85-1 ethene 
• 6118-51-0 exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride 
• 925-90-6 ethylmagnesium bromide 
• 21987-33-7 7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylic acid,methyl ester 
• 74-88-4 methyl iodide 
• 87057-40-7 (+/-)-trans-2,3-bis(phenylsulfonyl)-7-oxabicyclo[2.2.1]hept-5-ene 
• 98304-32-6 2-(phenylsulfonyl)-7-oxabicyclo<2.2.1>hept-2-ene 

Downstream Products

• 110-00-9 furan 
• 74-85-1 ethene 
• 98892-41-2 {3-[(1R,2S,3S,4S)-3-((S)-3-Hydroxy-oct-1-ynyl)-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl]-phenoxy}-acetic acid 
• 98892-38-7 {3-[(1R,2S,3S,4S)-3-((S)-3-Hydroxy-oct-1-ynyl)-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl]-phenoxy}-acetic acid methyl ester 
• 30182-12-8 4-hydroxy-2-cyclohexenone 
• 279-49-2 7-oxabicyclo(2.2.1)heptane 
• 98892-38-7 {3-[(1R,2S,3S,4S)-3-((R)-3-Hydroxy-oct-1-ynyl)-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl]-phenoxy}-acetic acid methyl ester 
• 98892-38-7 {3-[(1S,2R,3R,4R)-3-((R)-3-Hydroxy-oct-1-ynyl)-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl]-phenoxy}-acetic acid methyl ester 
• 113332-13-1 {3-[(1S,2S,3S,4R,1'S,3'R,4'R)-3'-((S)-3-Hydroxy-oct-1-ynyl)-[2,2']bi[7-oxa-bicyclo[2.2.1]heptyl]-3-ylmethyl]-phenoxy}-acetic acid methyl ester 
• 113332-13-1 {3-[(1S,3S,4R,1'S,2'R,3'R,4'R)-3'-((R)-3-Hydroxy-oct-1-ynyl)-[2,2']bi[7-oxa-bicyclo[2.2.1]heptyl]-3-ylmethyl]-phenoxy}-acetic acid methyl ester 
• 98892-41-2 {3-[(1S,2R,3R,4R)-3-((R)-3-Hydroxy-oct-1-ynyl)-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl]-phenoxy}-acetic acid 
• 98892-41-2 {3-[(1R,2S,3S,4S)-3-((R)-3-Hydroxy-oct-1-ynyl)-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl]-phenoxy}-acetic acid 

Relevant articles and documents

Herbicidal oxabicyclo ethers

The present invention relates to novel oxabicyclo ether derivative compounds, compositions containing these ether derivative compounds, and methods of using these compounds or compositions to control the growth of undesired vegetation. More particularly, the present invention relates to a variety of compounds, compositions, and methods of using them which are herbicidally active on a wide variety of weed species and exhibit safety to rice, cereals or broadleaf crops.

1,2-Thiazines and Related Heterocycles. Part 1. An Investigation of the Cycloadditions of N-Sulphinylanilines with 1,4-Epoxy-1,4-dihydronaphthalene and Other Alkenes

Evidence is adduced from the character of the alkenes which cycloadd to N-sulphinylanilines and from a kinetic investigation of the reactions of N-sulphinylanilines with 1,4-epoxy-1,4-dihydronaphthalene, examining the effects upon reaction rate of solvent polarity, temperature, and substitution in the N-sulphinylanilines, that the cycloadditions are pericyclic reactions of Diels-Alder type with inverse electron demand.A degree of charge separation in the transition state is indicated but this is small and confined essentially to the sulphinylaniline moiety.