675120-59-9

Basic information

• Product Name: Arsorane, azidoiodotris(pentafluorophenyl)-
• CAS NO: 675120-59-9
• Molecular Formula: C18AsF15IN3
• Molecular Weight: 745.02
• Mol File: 675120-59-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Arsorane, azidoiodotris(pentafluorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Arsorane, azidoiodotris(pentafluorophenyl)-(675120-59-9)
• EPA Substance Registry System: Arsorane, azidoiodotris(pentafluorophenyl)-(675120-59-9)

Safety Data

• Hazardous Substances Data: 675120-59-9(Hazardous Substances Data)

Upstream product

• 1259-34-3 tris(pentafluorophenyl)arsine 

Downstream Products

• 675120-68-0 1-phenyl-4-[tris(pentafluorophenyl)arsenic] iodo tetrazole-5-thione 

Relevant articles and documents

Some reactions and spectroscopic studies of tris(pentafluorophenyl) arsenic and -antimony(III and V) derivatives

The reactions of tris(pentafluorophenyl)arsenic(III) with iodine monochloride, iodine monoazide, and dithiocyanogen yielded corresponding oxidative-addition products of the type (C6F5) 3As(V)XY (X=I, Y=Cl, N3; X=Y=NCS). The elemental sulphur also added oxidatively with tris(pentafluorophenyl)arsenic(III) yielding tris(pentafluorophenyl)arsine(V) sulphide. Some displacement reactions were also carried out to synthesize mixed pseudohalide derivatives of the type (C6F5)3 M(N3)NCS (M=As and Sb) and their insertion reactions were studied with phenyl isothiocyanate which yielded the corresponding 1,2-cycloaddition products, i.e. tetrazole-5-thiones. The compounds were characterized by elemental analysis, molar conductance, UV, IR and 19F NMR spectroscopic studies.