67878-16-4

Basic information

• Product Name: (8-methoxycarbonyloctyl)triphenylphosphonium bromide
• Synonyms: (8-methoxycarbonyloctyl)triphenylphosphonium bromide
• CAS NO: 67878-16-4
• Molecular Weight: 513.455
• Mol File: 67878-16-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: (8-methoxycarbonyloctyl)triphenylphosphonium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: (8-methoxycarbonyloctyl)triphenylphosphonium bromide(67878-16-4)
• EPA Substance Registry System: (8-methoxycarbonyloctyl)triphenylphosphonium bromide(67878-16-4)

Safety Data

• Hazardous Substances Data: 67878-16-4(Hazardous Substances Data)

Upstream product

• 112-62-9 Methyl oleate 
• 2104-19-0 azelaic monomethyl ester 
• 1732-10-1 Dimethyl azelate 
• 123-99-9 azelaic acid 
• 41059-02-3 9-bromononanoic acid 
• 55362-80-6 9-bromononan-1-ol 
• 1931-63-1 methyl ester of azelaic acid aldehyde 
• 34957-73-8 methyl 9-hydroxynonanoate 
• 67878-15-3 methyl 9-bromononanoate 
• 603-35-0 triphenylphosphine 

Downstream Products

• 10219-70-2 (13R)-hydroxylinoleic acid methyl ester 
• 125010-85-7 (9Z,11E,13S)-13-N-p-toluenesulfonylamino octadecadienoic acid 
• 172995-09-4 18<(tert-butyldiphenylsilyl)oxy>-9(Z)-octadecenoic acid 
• 172995-10-7 18<(tert-butyldiphenylsilyl)oxy>-9(Z)-octadecenamide 
• 460077-85-4 (11S,9Z)-12-[(tert-butyldimethylsilyl)oxy]-11-[(tert-butyldiphenylsilyl)oxy]dodec-9-enoic acid methyl ester 
• 460077-87-6 (11S,9Z,12Z,15Z)-11-[(tert-butyldiphenylsilyl)oxy]octadeca-9,12,15-trienoic acid methyl ester 
• 460077-86-5 (11S,9Z)-11-[(tert-butyldiphenylsilyl)oxy]-12-hydroxydodec-9-enoic acid methyl ester 
• 460077-75-2 (Z)-(S)-11-(tert-Butyl-diphenyl-silanyloxy)-12-oxo-dodec-9-enoic acid methyl ester 
• 460077-81-0 (11R,9Z,12Z,15Z)-11-[(tert-butyldiphenylsilyl)oxy]octadeca-9,12,15-trienoic acid methyl ester 
• 172995-08-3 methyl 18<(tert-butyldiphenylsilyl)oxy>-9(Z)-octadecenoate 
• 13481-97-5 dimethyl (Z)-octadec-9-ene-1,18-dioate 
• 24753-49-9 Dimethyl (E)-octadec-9-enedioate 
• 125010-84-6 methyl-13(S)-N-p-toluenesulfonylamino-9(Z),11(E)-octadecadienoate 
• 98524-17-5 methyl 13(S)-(benzoyloxy)octadeca-9(Z),11(E)-dienoate 

Relevant articles and documents

A study of 1,5-hydrogen shift and cyclization reactions of an alkali isomerized methyl linolenoate

Heating a mixture formed by alkali isomerization of methyl linolenoate (1) produces a complex mixture with the bicyclic hexahydroindenoic esters 4β-(7-methoxycarbonylheptyl)-5α-methyl-2,3,3aα,4,5, 7aαhexahydroindene (CL5) and 4β-ethyl-5α-(6-methoxycarbonylhexyl)-2,3,3aα,4,5, 7aα-hexahydroindene (CL6) as main components. Similar isomerization reactions of three synthetic model compounds, methyl 9Z,13E,15Z-octadecatrienoate (2), 9Z,14E,16E-octadecatrienoate (4) and 9Z,11E,15Z-octadecatrienoate (5) corroborated the results obtained with alkali isomerized methyl linolenoate.

IDEBENONE COMPOUNDS

The present application provides idebenone derivatives or analogues useful for treating a disease or disorder in a subject in need thereof. Pharmaceutical compositions comprising the compounds and methods of treating the disease or disorder are also provided.

Studies related to in vivo C-H activation: Synthesis and influence of 8,8- and 11,11-dimethyl oleic and 11,11-dimethyl linoleic acids on Δ12- desaturation of C. sorokiniana

The synthesis of three acids was achieved using the Wittig reaction in order to study their in vivo influence on the Δ12-desaturase of Chlorella sorokiniana. It was shown that the introduction of two methyls near the double bond prevent the desaturation of these exogenous acids while they seem to be accurately incorporated. This functionality could be of interest for the design of new thiaoleic acids as probes of the different oxidation processes.