68525-40-6

Basic information

• Product Name: C₁₁H₁₅
• Synonyms: C₁₁H₁₅
• CAS NO: 68525-40-6
• Molecular Weight: 147.24
• Mol File: 68525-40-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₁H₁₅(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₁H₁₅(68525-40-6)
• EPA Substance Registry System: C₁₁H₁₅(68525-40-6)

Safety Data

• Hazardous Substances Data: 68525-40-6(Hazardous Substances Data)

Upstream product

• 70712-85-5 1-phenyl-2,2-dimethyl-1-propyl bromide 
• 107557-73-3 meso-Bis(2,2-dimethyl-1-phenylpropyl)diazen 
• 100-17-4 4-methoxynitrobenzene anion radical 
• 92-24-0 2,3-benzanthracene radical anion 
• 119-61-9 benzophenone radical anion 
• 1499-10-1 9,10-diphenylanthracene anion radical 
• 103-33-3 azobenzene anion radical 
• 84-65-1 9,10-anthraquinone radical anion 
• 1009-61-6 1,4-diacetylbenzene anion radical 

Relevant articles and documents

The Nucleophilicity of Superoxide towards Different Alkyl Halides Estimated from Kinetic Measurements

Values of the rate constant ksub are measured for the substitution reaction between superoxide O2 anion-radical and the alkyl halides butyl chloride, 2-butyl chloride, benzyl chloride, ethyl bromide, butyl bromide, 2-butyl bromide, neopentyl bromide, benzyl bromide, (1-bromo-2,2-dimethylpropyl)benzene and 1-iodoadamantane.These rate constants are compared with the expected rate constant kET for the electron transfer reaction between the same alkyl halides and an aromatic anion radical A anion-radical with the same standard oxidation potential as O2 anion-radical.The ksub/kET ratios show that the mechanism of the substitution reaction amy shift from SN2-like to ET-like on changes in the steric hindrance and the acceptor ability of the alkyl halide.The influence on ksub/kET of the difference in self-exchange reorganization energy λ(0) between O2 anion-radical/O2 and A anion-radical/A is discussed.