68572-87-2

Basic information

• Product Name: 9-Phenanthracenylboronic acid
• Synonyms: PHENANTHREN-9-YLBORONIC ACID;PHENANTHRENE-9-BORONIC ACID;RARECHEM AH PB 0056;BORONIC ACID, 9-PHENANTHRENYL-;9-PHENANTHRENEBORONIC ACID;9-Phenanthreneboronic acid (contains varying amounts of anhydride);Phenanthreneboronicacid;Phenanthrene-9-boronic acid 98%
• CAS NO: 68572-87-2
• Molecular Formula: C₁₄H₁₁BO₂
• Molecular Weight: 222.05
• EINECS: 1592732-453-0
• Product Categories: Boron Compounds;blocks;BoronicAcids;Electronic Chemicals;B (Classes of Boron Compounds);Boronic Acids;Aromatics;Boron Derivatives;Fluorescent Labels & Indicators
• Mol File: 68572-87-2.mol
• Article Data: 17

Chemical Properties

• Melting Point: 165-170 °C
• Boiling Point: 479.505 °C at 760 mmHg
• Flash Point: 243.796 °C
• Appearance: /
• Density: 1.268 g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.71
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility: Soluble in DMSO.
• PKA: 8.53±0.30(Predicted)
• CAS DataBase Reference: 9-Phenanthracenylboronic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Phenanthracenylboronic acid(68572-87-2)
• EPA Substance Registry System: 9-Phenanthracenylboronic acid(68572-87-2)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 22-24/25-26
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 68572-87-2(Hazardous Substances Data)

Usage

Chemical Properties

White solid

Uses

Different sources of media describe the Uses of 68572-87-2 differently. You can refer to the following data:
1. 9-Phenanthreneboronic Acid is used as an fluorescent analytical reagent in sensing systems for glucose-specific detection.
2. 9-Phenanthracenylboronic acid is used as an fluorescent analytical reagent in sensing systems for glucose-specific detection and in suzuki reaction.
3. suzuki reaction

InChI:InChI=1/C14H11BO2/c16-15(17)14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9,16-17H

Upstream product

• 5419-55-6 Triisopropyl borate 
• 573-17-1 9-bromophenanthrene 
• 688-74-4 boric acid tributyl ester 
• 121-43-7 Trimethyl borate 
• 7732-18-5 water 

Downstream Products

• 1013933-56-6 2-(9-phenanthryl)phenylacetone 
• 1094602-68-2 1,2,4-tris-(9'-phenanthryl)benzene 
• 1217313-31-9 methyl (Z)-2-(tert-butoxycarbonylamino)-3-(phenanthracen-9-yl)but-2-enoate 
• 1217313-32-0 methyl (E)-2-(tert-butoxycarbonylamino)-3-(phenanthracen-9-yl)but-2-enoate 
• 1217313-43-3 methyl (Z)-2-(tert-butoxycarbonylamino)-3,3-bis(phenanthracen-9-yl)acrylate 
• 1217313-34-2 methyl (E)-2-(tert-butoxycarbonylamino)-3-(phenanthracen-9-yl)-3-phenylacrylate 
• 1217313-33-1 methyl (Z)-2-(tert-butoxycarbonylamino)-3-(phenanthracen-9-yl)-3-phenylacrylate 
• 1271724-76-5 C₃₁H₂₅N₃ 
• 1312023-66-7 9-(2,2,2-trifluoroethyl)phenanthrene 
• 1437383-67-9 1,2-bis(3-(phenanthren-9-yl)phenyl)ethane 
• 23827-06-7 9-(pyridine-2-yl) phenanthrene 
• 1581695-33-1 2-(phenanthren-9-yl)pyrimidine 
• 1581695-38-6 10-(pyrimidin-2-yl)phenanthrene-9-carbonitrile 

Relevant articles and documents

Preparation method of dibenzo [g,p] condensed naphthalene compound

The invention relates to the field, of organic synthesis, and particularly relates to a preparation method [g,p] of a dibenzo. condensed naphthalene compound 1, and the preparation method, of the compound of Formula: comprises 7 reacting the compound of Formula, in the presence of an inorganic Lewis acid and an oxidizing agent to obtain a compound 1 of Formula. The present invention provides a method for preparing a dibenzo [g,p] fused bicyclic naphthalene compound according to the present invention by using an inorganic Lewis acid and an oxidizing agent to, prepare a compound of, the, present invention having a high overall, conversion rate, and, a high efficiency . industrial production operation .

Phosphorescence host material and application thereof in organic electroluminescence devices

The invention relates to an organic compound; the organic compound is as shown in a formula (1), and the formula (1) is described in the description, wherein the dotted circle represents a benzene ring structure, and indole derivative groups positioned at the two sides of the benzene ring structure are fused into indolocarbazole derivatives by means of the benzene ring structure; X1-X8 is CR or N;one of Ar1 and Ar2 is selected from pi-absence electron-type aromatic groups of C3-C30; R is selected from hydrogen, aliphatic hydrocarbon groups of C1-C4, aryl groups of C6-C30 and heteroaryl groupsof C3-C30; when multiple Rs exist, all the Rs can be the same or different; m and n are respectively integers within a range of 1-4; p is 1 or 2; L1 and L2 are respectively and independently selectedfrom a single bond, arylene groups of C6-C12 or hetero-arylene groups of C3-C12; when substituents exist in the groups, the substituents are respectively and independently selected from halogen, alkyl or cycloalkyl groups of C1-C10, alkenyl or cycloalkenyl groups of C2-C6, alkoxy or thioalkoxy groups of C1-C6, monocyclic aryl or fused ring aryl groups of C6-C30, monocyclic heteroaryl or fused ring heteroaryl groups of C3-C30, or a combined structure of the groups.

aromatic compound having fused cyclic substituent in aromatic ring and organic light-emitting diode including the same

The present invention relates to a compound having a cyclic substituent fused with a cyclic ring and an organic light emitting diode including the same, and more particularly, to a compound for an organic light emitting diode represented by chemical formula A and an organic light emitting diode including the same. In chemical formula A, X is a substituent having structural formula X, Y is a substituent of structural formula Y1, n is an integer from 1 to 4, and structural formulas X and Y1 are the same as described in detailed description of the present invention.