69905-74-4Relevant articles and documents
Transition metal complexes comprising carbene ligands serving as emitters for organic light-emitting diodes (OLED's)
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Page/Page column 34; 35; 36, (2020/03/14)
Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≥1; o is the number of ligands K, where o can be 0 or ≥1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.
ELECTROLUMINESCENT IMIDAZO-QUINOXALINE CARBENE METAL COMPLEXES
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Page/Page column 211; 212, (2016/04/04)
Metal carbene complexes comprising at least one imidazo-quinoxaline ligand, organic electronic devices, especially OLEDs (Organic Light- Emitting Diodes) which comprise such complexes, a light-emitting layer comprising at least one inventive metal carbene complex, an apparatus selected from the group consisting of illuminating elements, stationary visual display units and mobile visual display units comprising such an OLED, the use of such a metal carbene complex for electrophotographic photoreceptors, photoelectric converters, organic solar cells (organic photovoltaics), switching elements, organic light emitting field effect transistors (OLEFETs), image sensors, dye lasers and electroluminescent devices and a process for preparing such metal carbene complexes.
Facial and practical synthesis of benzimidazole-based N-heterocyclic carbenes
Wang, Han,Xia, Yuyu,Lv, Shang,Xu, Jingli,Sun, Zhihua
supporting information, p. 2124 - 2127 (2013/05/08)
An efficient synthesis of benzimidazole-based N-heterocyclic carbenes has been developed. The key step in this synthetic methodology was a one-pot protocol for the synthesis of N,N′-diarylaryldiamines starting from aryldiamine and aryl halides.