70672-86-5

Basic information

• Product Name: (1-METHOXY-3-METHYL-BUT-3-ENYL)-BENZENE
• Synonyms: (1-METHOXY-3-METHYL-BUT-3-ENYL)-BENZENE
• CAS NO: 70672-86-5
• Molecular Formula: C₁₂H₁₆O
• Molecular Weight: 176.25484
• Mol File: 70672-86-5.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (1-METHOXY-3-METHYL-BUT-3-ENYL)-BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: (1-METHOXY-3-METHYL-BUT-3-ENYL)-BENZENE(70672-86-5)
• EPA Substance Registry System: (1-METHOXY-3-METHYL-BUT-3-ENYL)-BENZENE(70672-86-5)

Safety Data

• Hazardous Substances Data: 70672-86-5(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 22, p. 745, 1981 DOI: 10.1016/0040-4039(81)80140-2

Upstream product

• 18292-38-1 2-methallyltrimethylsilane 
• 100-52-7 benzaldehyde 
• 149-73-5 trimethyl orthoformate 
• 135569-04-9 <<<(3-methyl-1-phenyl-3-butenyl)oxy>methyl>seleno>benzene 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 1458-98-6 2-methyl-3-bromo-1-propene 

Relevant articles and documents

Bismuth compounds in organic synthesis. A one-pot synthesis of homoallyl ethers and homoallyl acetates from aldehydes catalyzed by bismuth triflate

(Chemical Equation Presented) Three one-pot methods for the conversion of aldehydes to homoallyl ethers catalyzed by Bi(OTf)3? xH 2O (1 x 4) have been developed. The one-pot synthesis of homoallyl ethers can be achieved either by

Fluessiges Schwefeldioxid als Lewis-acides Solvens fuer die Alkylierung und Alkoxyalkylierung von Allylsilanen

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Homogeneous Catalysis. Use of the Catalyst for the Sakurai Reaction of Allylic Silanes with Orthoesters, Acetals, Ketals and Carbonyl Compounds.

The effectiveness of the catalyst for the Sakurai reaction has been explored for a variety of allylic silanes reacting with orthoesters, acetals, ketals, aldehydes and ketones. Key Words: Sakurai reaction, titanium based catalyst.