70712-85-5Relevant articles and documents
Method for synthesizing alkyne through catalytic asymmetric cross coupling (by machine translation)
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Paragraph 0205-0212; 0234-0236, (2020/01/12)
The invention belongs to the field of, asymmetric synthesis, and discloses a method for catalyzing asymmetric cross- coupling to synthesize: an alkyne, and the L method comprises, the following steps, of A: preparing B a cuprous, salt and C a: ligand; preparing a catalyst; adding a base; reacting the compound with the compound with the compound; and reacting the compound with the compound. Of these, one of them, X is selected from the group consisting of, R halogens. 1 Optionally substituted heteroarylsulfonylcyanamide groups selected from the, group consisting, of optionally substituted, phenyl groups In-flight vehicle, R6 Trialkyl silyl groups or alkyl radicals, R2 Cycloalkyl radicals optionally substituted with an, optionally substituted alkyl, (CH radical2 )n R4 Multi,layer chain, n=0-10,R saw blade4 A group selected, from, the group consisting of phenyl, alkenyl, aralkynyls, noonyloxy,and, noonylsulfonylsulfonylsulfonylsulfonylsulfonylsulfonylsulfonylsulfonylsulfonylsulphonylsulphonylsulphonylsulphonylsulphonylsulphonylsulphonylsulphonylsulphonylsulphonylphenyl disiloxy-radicals. R3 A ligand, selected from hydrogen or any of the functional groups, is selected from the group consisting of, hydrogen and any L other functional group. The method, R disclosed by the, A invention has the, advantages of good catalytic, R ’ effect, wide application range. and high catalytic efficiency, and the, method disclosed by the, invention has the. advantages of good catalytic effect, wide application range and high catalytic efficiency. (by machine translation)
Solvolysis of 1-aryl-1-tert-butylmethyl bromides. Hammett-type correlation analysis and revised YBnBr scale
Liu, Kwang-Ting
, p. 789 - 796 (2007/10/03)
The solvolysis of a series of l-aryl-1-tert-butylmethyl bromides (la~lg) in a variety of solvents were carried out. Linear relationships were observed from Hammett-type analysis of logarithm of rate constants using single-parameter Brown-Okamoto equation
Barriers to Internal Rotation in Neopentylbenzenes Substituted on the Benzyl Group. A 13C NMR Band Shape Study
Andersson, Sven,Drakenberg, Torbjoern
, p. 730 - 744 (2007/10/02)
Two series of neopentylbenzenes with one or two substituents on the benzyl group have been synthesized.In one series the substituents were H, F, Cl, Br, I, OCH3, OCOCH3, OSi(CH3)3, CH3 and CH2CH3, and in the other OH and R R = H, CH3, CH2CH3, (CH2)3CH3,