70960-88-2

Basic information

• Product Name: Silane, trimethyl (4-phenyl-1,3-butadienyl)-, (E,E)-
• CAS NO: 70960-88-2
• Molecular Weight: 202.371
• Mol File: 70960-88-2.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl (4-phenyl-1,3-butadienyl)-, (E,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl (4-phenyl-1,3-butadienyl)-, (E,E)-(70960-88-2)
• EPA Substance Registry System: Silane, trimethyl (4-phenyl-1,3-butadienyl)-, (E,E)-(70960-88-2)

Safety Data

• Hazardous Substances Data: 70960-88-2(Hazardous Substances Data)

Upstream product

• 6783-05-7 trans-2-phenylvinylboronic acid 
• 754-05-2 ethenyltrimethylsilane 
• 14371-10-9 (E)-3-phenylpropenal 
• 2612-42-2 (dibromomethyl)trimethylsilane 
• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 
• 22430-47-3 (1E,3E)-1,4-bis(trimethylsilyl)-1,3-butadiene 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 75-77-4 chloro-trimethyl-silane 
• 1067-87-4 Diethyl allylphosphonate 
• 100-52-7 benzaldehyde 
• 100-42-5 styrene 
• 17891-78-0 2,2,6,6-tetramethyl-2,6-disila-3-heptene 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 106-95-6 allyl bromide 

Downstream Products

• 1190597-81-9 C₁₄H₁₆O₃ 
• 16939-57-4 (E)-buta-1,3-dienylbenzene 
• 75391-05-8 (4E,6E)-7-phenylhepta-4,6-dien-3-one 
• 4173-44-8 (E,E)-6-phenyl-3,5-hexadien-2-one 
• 29179-25-7 cinnamylideneacetophenone 
• 155455-29-1 (6Z,8E)-6-bromo-5-phenyl-9-(trimethylsilyl)-4-oxanona-1,6,8-triene 
• 188802-38-2 ((1E,3E)-4-bromobuta-1,3-dienyl)benzene 
• 19222-50-5 1,8-diphenyl-1,3,5,7-octatetraene 
• 67229-92-9 (((1E,3E)-4-phenylbuta-1,3-dien-1-yl)sulfonyl)benzene 
• 13466-40-5 (2E, 4E)-5-phenylpenta-2,4-dienal 

Relevant articles and documents

Aza-peterson olefinations: Rapid synthesis of (E)-alkenes

An aza-Peterson olefination methodology to access 1,3-dienes and stilbene derivatives from the corresponding allyl- or benzyltrimethylsilane is described. Silanes can be deprotonated using Schlosser's base and added to N -phenyl imines or ketones to directly give the desired products in high yields.

Ruthenium-Catalyzed Silylation of 1,3-Butadienes with Vinylsilanes

A novel method for the synthesis of 1-silyl-substituted 1,3-butadienes, based on [RuHCl(CO)(PCy3)2]-catalyzed silylative coupling of terminal (E)-1,3-dienes with vinylsilanes, is reported. The reaction provides a facile and straightf

Heck coupling with nonactivated alkenyl tosylates and phosphates: Examples of effective 1,2-migrations of the alkenyl palladium(II) intermediates

(Chemical Equation Presented) What the Heck! A catalytic system composed of a Pd complex with a basic, hindered alkyl phosphine ligand is capable of promoting Heck coupling of nonactivated vinyl tosylates and phosphates with electron-deficient olefins. An unexpected 1,2-migration of the alkenyl Pd II intermediates (see Scheme) leads to the isomerized Heck coupling product.