71092-65-4Relevant articles and documents
Thermolysis of the benzene anion radical 18-crown-6 complex
Stevenson, Cheryl D.,Morgan, Grant
, p. 7694 - 7697 (1998)
The C-O and G-H bonds of 18-crown-6 are activated when 18-crown-6 is complexed with the potassium salt of the benzene anion radical. Evacuated glass bulbs containing the solid anion radical salt of potassium 18-crown-6 benzene anion radical were plunged into a bath at 320 C, resulting in mini-explosions and generating a series of compounds including dioxane, 2-methyl1,3-dioxolane, divinyl ether, hydrogen, methane, and 15-crown-5. Deuterium labeling studies proved that all of these compounds originated from the 18-crown-6. Further, these labeling studies were an aid in discerning the mechanism of the decomposition. Benzene, 1,4-cyclohexadiene, and cyclohexene were also generated. The last two originated from the reaction of the anion radical of benzene with hydrogen.
A Pseudotetrahedral Terminal Oxoiron(IV) Complex: Mechanistic Promiscuity in C?H Bond Oxidation Reactions
Warm, Katrin,Paskin, Alice,Kuhlmann, Uwe,Bill, Eckhard,Swart, Marcel,Haumann, Michael,Dau, Holger,Hildebrandt, Peter,Ray, Kallol
, p. 6752 - 6756 (2021)
S=2 oxoiron(IV) species act as reactive intermediates in the catalytic cycle of nonheme iron oxygenases. The few available synthetic S=2 FeIV=O complexes known to date are often limited to trigonal bipyramidal and very rarely to octahedral geom
Concerted and nonconcerted pathways for thermal conversions of deuterium-labeled cyclohexenes to butadienes and ethylenes
Lewis, David K.,Brandt, Benjamin,Crockford, Lisa,Glenar, David A.,Rauscher, Grant,Rodriguez, Julio,Baldwin, John E.
, p. 11728 - 11734 (2007/10/02)
The retro Diels-Alder reactions of cyclohexene-3,3,6,6-d4 and the 4,5-cis isomers of cyclohexene-1,2,3,4,5,6-d6 have been followed using single-pulse shock tube kinetic and tunable diode laser infrared spectroscopic techniques. At te
