7119-93-9Relevant articles and documents
Synthesis method of nitramide
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Paragraph 0028-0036; 0055-0063, (2019/02/04)
The invention relates to a synthesis method of nitramide. The method comprises the step of enabling an aniline reaction substrate and a nitrating reagent to be subjected to a reaction in a solvent at20-60 DEG C for 2-8 hours to obtain the nitramide, where
AN ALTERNATE METHOD FOR THE SYNTHESIS OF SECONDARY NITRAMINES
Daszkiewicz, Z.,Domanski, A.,Kyziol, J. B.
, p. 337 - 342 (2007/10/02)
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SUBSTITUENT EFFECT TREATMENT OF INTERACTIONS BETWEEN CONTIGUOUS FUNCTIONALITIES. IV. RESTRAINT TO PHENYL-NITROGEN CONJUGATIVE INTERACTION IN N-FUNCTIONALIZED N-METHYLANILINES
Bradamante, Silvia,Colombo, Silvana,Pagani, Giorgio A.,Roelens, Stefano
, p. 357 - 364 (2007/10/02)
13C shifts at the para position in PhN(Me)X for 17 different substituents X serve as monitors for investigating, in correlative analysis, the nature and the extent of interactions occurring between the substituent X and the N-Me cavity.For the majority of substituent, X, partitioning of the nitrogen electron pair between the phenyl and the substituent is partially hampered because of the non-zero twist angle between the planes containing the phenyl ring and the Me-N-X fragment.As a consequence, relative to PhNHX, the interactions between the cavity and the substituents are increased in intensity, especially their mesomeric component, and, at the same time, para-13C shifts are displaced toward lower field.Evidence is also provided that possible H-bonding by the NH cavity of PhNHX with dimethyl sulphoxide does not appreciably influence the substituent electron demand determined previously.