71721-66-9

Basic information

• Product Name: 2-(Hydroxyimino)malonamide
• Synonyms: 2-(Hydroxyimino)malonamide
• CAS NO: 71721-66-9
• Molecular Formula: C₃H₅N₃O₃
• Molecular Weight: 131.0901
• Mol File: 71721-66-9.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 406.3°Cat760mmHg
• Flash Point: 199.6°C
• Appearance: /
• Density: 1.85g/cm³
• Vapor Pressure: 2.69E-08mmHg at 25°C
• Refractive Index: 1.65
• CAS DataBase Reference: 2-(Hydroxyimino)malonamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Hydroxyimino)malonamide(71721-66-9)
• EPA Substance Registry System: 2-(Hydroxyimino)malonamide(71721-66-9)

Safety Data

• Hazardous Substances Data: 71721-66-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C3H5N3O3/c4-2(7)1(6-9)3(5)8/h9H,(H2,4,7)(H2,5,8)

Upstream product

• 73003-80-2 2,2-dibromomalonamide 
• 69645-51-8 2-nitromalonamide 
• 6829-41-0 diethyl oximinomalonate 
• 7732-18-5 water 
• 108-13-4 malonodiamide 
• 42937-74-6 dimethyl 2-(hydroxyimino)malonate 

Downstream Products

• 74-90-8 hydrogen cyanide 
• 129709-04-2 C₂₆H₃₁N₃O₁₂S₂ 

Relevant articles and documents

Nitrite ionic liquids (IL-ONO and [bmim]NO2) as effective nitrosonium sources for the synthesis of α-oximinoketones under mild heterogeneous conditions

Ketones and β-diketones were nitrosated and converted to their corresponding α-oximinoketones using task-specific ionic liquids, 1-(4-nitritobutyl)-3-methylimidazolium chloride, IL-ONO, and 1-butyl-3-methylimidazolium nitrite at room temperature. The results from two ionic liquids are comparable and showed that these IL's are effective nitrosonium sources for the preparation of oximinoketones. The protocol is rapid, the yields are excellent, and the method is simple. Copyright