72358-83-9

Basic information

• Product Name: Benzenesulfonamide, N,N-bis[2-(2-hydroxyethoxy)ethyl]-4-methyl-
• Synonyms: N,N-bis<2-(2-hydroxyethoxy)ethyl>-4-methylbenzenesulfonamide;Benzenesulfonamide,N,N-bis[2-(2-hydroxyethoxy)ethyl]-4-methyl;N,N-bis[2-(2-hydroxyethoxy)ethyl]-p-toluenesulfonamide
• CAS NO: 72358-83-9
• Molecular Formula: C15H25NO6S
• Molecular Weight: 347.433
• Mol File: 72358-83-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N,N-bis[2-(2-hydroxyethoxy)ethyl]-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N,N-bis[2-(2-hydroxyethoxy)ethyl]-4-methyl-(72358-83-9)
• EPA Substance Registry System: Benzenesulfonamide, N,N-bis[2-(2-hydroxyethoxy)ethyl]-4-methyl-(72358-83-9)

Safety Data

• Hazardous Substances Data: 72358-83-9(Hazardous Substances Data)

Upstream product

• 70-55-3 toluene-4-sulfonamide 
• 118591-58-5 5-tosyloxy-3-oxapentanol 
• 628-89-7 2-(2-Chloroethoxy)ethanol 
• 80639-60-7 4-Methyl-N,N-bis-{2-[2-(tetrahydro-pyran-2-yloxy)-ethoxy]-ethyl}-benzenesulfonamide 
• 65338-95-6 1-(tetrahydropyranyloxy)-2-<(p-tolylsulfonyl)oxy>ethane 
• 7146-67-0 N-tosyldiethanolamine 

Downstream Products

• 115538-87-9 8,27-Bis-(toluene-4-sulfonyl)-2,5,11,14,21,24,30,33-octaoxa-8,27-diaza-tricyclo[32.4.0.0^15,20]octatriaconta-1⁽³⁸⁾,15,17,19,34,36-hexaene 
• 118187-52-3 8,27-Bis-(4-methoxy-benzyl)-2,5,11,14,21,24,30,33-octaoxa-8,27-diaza-tricyclo[32.4.0.0^15,20]octatriaconta-1⁽³⁸⁾,15,17,19,34,36-hexaene 
• 118187-51-2 8,27-Dibenzyl-2,5,11,14,21,24,30,33-octaoxa-8,27-diaza-tricyclo[32.4.0.0^15,20]octatriaconta-1⁽³⁸⁾,15,17,19,34,36-hexaene 
• 118221-67-3 N,N-Bis-{2-[2-(2-benzyloxy-phenoxy)-ethoxy]-ethyl}-4-methyl-benzenesulfonamide 
• 118187-56-7 N,N-Bis-{2-[2-(2-hydroxy-phenoxy)-ethoxy]-ethyl}-4-methyl-benzenesulfonamide 
• 115942-17-1 12-benzyl-7,17,22,27-tetraoxa-1,4,10,14-tetraazatricyclo<12.5.5.5^4,10>nonacosane 
• 115942-18-2 4,16-di-p-toluenesulfonyl-10,22-dibenzyl-1,7,13,19-tetraoxa-4,10,16,22-tetraazacyclotetracosane 
• 96563-17-6 4,4'-(2-hexadecyl-1,3-propanediyl)bis<10-<(4-methylphenyl)sulfonyl>-1,7-dioxa-4,10-diazacyclododecane> 
• 96563-18-7 4,4'-(2-benzyl-1,3-propanediyl)bis<10-<(4-methylphenyl)sulfonyl>-1,7-dioxa-4,10-diazacyclododecane> 
• 96563-20-1 4,4'-(2-benzyl-1,3-propanediyl)bis(1,7-dioxa-4,10-diazacyclododecane) 
• 96563-14-3 4-carbethoxy-10-<(4-methylphenyl)sulfonyl>-1,7-dioxa-4,10-diazacyclododecane 
• 96563-15-4 4-[(4-methylphenyl)sulfonyl]-1,7-dioxa-4,10-diazacyclododecane 
• 143065-61-6 10,25-ditosyl-4,7,13,16,22,28-hexaoxa-1,10,19,25-tetraazabicyclo<17.11.2>dotriacontane 
• 143065-62-7 8,21-ditosyl-4,12,18,24-tetraoxa-1,8,15,21-tetraazabicyclo<13.11.2>octacosane 

Relevant articles and documents

Synthesis and metal ion complexation studies of proton-ionizable calix[4]azacrown ethers in the 1,3-alternate conformation

A series of novel N-chromogenic calix[4]arene azacrown ethers were synthesized as selective extractants of potassium ion. 1,3-Alternate calix[4]arene azacrown ethers were prepared by reacting 25,27-dipropyloxy- 26,28-bis(5-chloro-3-oxapentyloxy) calix[4]arenes with p-toluenesulfonamide in the presence of potassium carbonate. The coupling reaction of calix[4]arene azacrown ether with 2-hydroxy-5-nitrobenzyl bromide in the presence of triethylamine in THF gave the chromogenic calix[4]arene azacrown ether in moderate yield. These compounds show high potassium selectivity over other metal ions as shown by two-phase extraction, bulk liquid membrane, and 1H NMR studies on a ligand-metal complex. It is assumed that the OH of the chromogenic group attached on nitrogen can assist the complexation by encapsulation of the metal.

Synthesis of Chiral Diaza-18-crown-6 Derivatives from Optically Active Diethanolamines

Homotopic 1,10-diaza-18-crown-6 derivatives with two, four, and six chiral centers have been prepared in optically active form from diethanolamines via a cyclization reaction with tosylates 39 and 48.The requisite optically active diethanolamines were prepared from chiral cyanohydrins and chiral ethanolamines by a one-pot Grignard-transimination-reduction or a one-pot reduction-transimination-reduction procedure.Yields were strongly affected by the size of the substituents α to the nitrogen atom.The stereoselectivity of the diethanolamine synthesis was found to depend on the configuration of the ethanolamine used.

Diazadibenzo-30-crown-10 derivatives as receptors for diquat

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