74032-27-2

Basic information

• Product Name: 1-((E)-2-Methylsulfanyl-1-phenyl-vinyl)-piperidine
• CAS NO: 74032-27-2
• Molecular Weight: 233.378
• Mol File: 74032-27-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-((E)-2-Methylsulfanyl-1-phenyl-vinyl)-piperidine(CAS DataBase Reference)
• NIST Chemistry Reference: 1-((E)-2-Methylsulfanyl-1-phenyl-vinyl)-piperidine(74032-27-2)
• EPA Substance Registry System: 1-((E)-2-Methylsulfanyl-1-phenyl-vinyl)-piperidine(74032-27-2)

Safety Data

• Hazardous Substances Data: 74032-27-2(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 776-75-0 N-benzoylpiperidine 
• 29765-03-5 LiCH(SCH₃)(Si(CH₃)3) 
• 10428-57-6 trimethyl[(methylthio)methyl]silane 

Relevant articles and documents

Reaction of 1-Lithio-1-arylthio(or alkylthio)methyltrimethylsilane with Acid Derivatives. A Novel Synthesis of Functionalized Vinyl Sulfides

Reactions of 1-lithio-1-phenylthiomethyl- (1a) and 1-lithio-1-methylthiomethyltrimethylsilane (1b) with amides, an ester, acid anhydrides, a urea, and a carbonate are described which provide useful routes to functionalized vinyl sulfides.The reaction of 1 with amides gave β-functionalized vinyl sulfides, 1-dialkylamino-2-phenylthio (or methylthio)ethylenes, in 40-95percent yields and the reaction could be extended to the sulfonyl derivatives of 1 to afford 1-dialkylamino-2-phenylsulfonyl(or methylsulfonyl)ethylenes.Although ethyl benzoate and some acid anhydrides were not good substrates for this reaction, tetramethylurea and diethyl carbonate gave α-functionalized vinyl sulfides, 1-amidovinyl- and 1-(ethoxycarbonyl)vinyl sulfides, in moderate yields when treated with 1a followed by addition of benzaldehyde.